Atmospheric Moisture and Precipitation Principles of Physical Geography Atmospheric Moisture and Precipitation Aims To understand the relationship between temperature and humidity To define evapotranspiration To understand the concept of stability in the atmosphere To understand why it rains To understand convection Objectives • • • • • • • • • GY To identify the utilization of energy during the various phase change processes of water. To describe the saturation process and how the amount of atmospheric water vapour at saturation depends upon temperature. To understand the processes of evaporation and transpiration To explain how the water vapour content of air is quantified and define the following moisture parameters: dewpoint temperature, wet bulb temperature, vapour pressure, mixing ratio, relative humidity To explain the temperature dependency of relative humidity. To define dry and wet adiabatic temperature changes. To explain the concept of stability and its application to the atmosphere To explain absolute stability and absolute and conditional instability of an air column To explain convection, orographic lifting, frontal wedging and convergence Atmospheric Moisture and Precipitation Outline Introduction • • • • Moisture and atmospheric stability Air water vapour content Relevance of moisture for the hydrologic cycle Importance for local surface weather and climate, role in tropical storms Water’s changes of state • • • • Evaporation, condensation Transpiration, evapotranspiration Energy supply for evapotranspiration Latent heat Humidity • • • • Vapour pressure Saturation Mixing ratio and absolute humidity Dewpoint Relative humidity • • Relative humidity Changing water content and temperature Adiabatic temperature changes • • • Ideal Gas Law Dry adiabatic rate Wet adiabatic rate Lifting processes and precipitation • • • • Orographic lifting Convective lifting Frontal wedging Convergence Convection GY Atmospheric Moisture and Precipitation Main topics Interactions of water vapour with atmospheric stability Evapotranspiration Relationship between temperature and humidity Concept of stability in the atmosphere Lifting and precipitation Convection Outline Introduction • • • • Moisture and atmospheric stability Air water vapour content Relevance of moisture for the hydrologic cycle Importance for local weather and climate, role in tropical storms Water’s changes of state • Evaporation, condensation, transpiration, evapotranspiration • Energy supply for evapotranspiration • Latent heat Humidity • • • • Dewpoint Saturation Mixing ratio and absolute humidity Vapour pressure Relative humidity • Relative humidity • Changing water content and temperature Adiabatic temperature changes • Ideal Gas Law • Dry adiabatic rate • Wet adiabatic rate Lifting processes and precipitation Convection GY Atmospheric Moisture and Precipitation Bullets Introduction • • • • • • • • • • • Moisture <-> atmospheric stability? What is stability anyway? Water vapour - only small fraction of the atmosphere 0<v<5% ! Takes energy to evaporate water - as water vapour condensates, what happens with the heat being released in the atmosphere? Why care? Very important: precipitation, groundwater recharge, cooling, moisturizing Latent/sensible heat -> cooling of surface Released energy - used to drive other processes? Warm some areas? One way how the energy from the sun drives the processes one earth and allows for warming the higher latitudes Example for moisture/stability/energy content: tropical convection and Hurricanes Thus: for several reasons important to understand the water cycle and to measure water vapour content of air, that is air moisture, humidity Importance of energy transformations and temperature measurements Water’s changes of state • • • • • • • • • • • Evaporation - requires energy - latent heat of vaporization, calorie Change of state During evaporation some fast molecules escape to the air Transpiration: water loss from plants Evapotranspiration: sum of evaporation and transpiration Evaporation is a cooling process since energy is used to evaporate the water and not to heat the water or the air. Heat/energy used for evaporation is now contained in the water vapour Latent/sensible heat -> forest/open Latent heat is released again during condensation Melting, requires energy, too, the latent heat of fusion, released again during freezing Frost protection by sprinkling water onto fruit crops: heat content of water, latent heat of fusion is released as the water freezes -> as long as there is liquid water on the fruit, their temperature will not fall below 0oC as the freezing water releases heat Humidity • • • • • • • • Humidity - general term for the amount of water vapour in the air Water vapour pressure - partial pressure of the water vapour in the atmosphere Saturation of air with water vapour <-> after some time an equilibrium between evaporation and condensation over a water surface in closed container Saturation vapour pressure - pressure exerted by air saturated with water Saturation water vapour pressure is temperature dependent as at higher temperatures more water evaporates <-> more molecules have higher energy Absolute humidity - mass of water vapour in a given volume of air Mixing ratio - mass of water vapour in a unit mass of dry air Difficult to determine Relative humidity • GY Relative humidity - ratio of the air’s actual water vapour content compared with the amount of water vapour required for saturation at the same temperature Atmospheric Moisture and Precipitation • • • • • • • • Temperature dependent -> can be changed by changing water content or by changing temperature Increases in water vapour content lead to increases to relative humidity (at the same temperature) until condensation occurs - at saturation. Increases in temperature decrease relative humidity because at higher temperatures air can hold more water Decreases in temperature increase relative humidity because at higher temperatures air can hold less water - at some temperature condensation might occur removing water from the air and relative humidity remains at 100% 1. diurnal cycle due to temperature cycle, 2. air movement horizontally or, 3. vertically Relative humidity <-> mixing ratio Dew point: temperature at which a parcel of air would be saturated Human discomfort: sweating dissipates heat by evaporation of perspiration (latent heat of vaporization!) - not efficient if surrounding air is very moist and can thus not take up easily more moisture -> heat stress -> eventually fatal due to failing protein functions. Very dangerous in enclosed spaces - cars! Adiabatic temperature changes • • • • • • • • • • • Ideal gas law Dry adiabatic changes: when air is allowed to expand it cools, when it is compressed it warms - no heat is added nor subtracted If air is lifted: dry adiabatic rate: 10oC per 1000m Applies only to vertically moving unsaturated air If air cools sufficiently condensation will occur and release heat, thus slowing the rate of cooling Wet adiabatic rate Wet adiabatic rate depends on the amount of moisture in the air: 5oC for air with high to 9oC for air with low moisture content Wet adiabatic rate applies above the level, where condensation occurs, the lifting condensation level -> rain Cooling is faster at the dry rate than at the wet rate Importance of moisture and temperature measurements to estimate lifting and thus precipitation and energy release Linkage of air movement and energy exchange Lifting processes and precipitation • • • • • Lifting processes are important as they can force air up to a level where the temperate is below it’s dew point and thus producing clouds and rain Convective lifting Orographic lifting: air forced upward by air flow over elevated terrain ->rain shadow deserts Frontal wedging: air forced upward by air flow over denser air; often warmer over colder air. Convergence Links • • GY http://ww2010.atmos.uiuc.edu/(Gh)/guides/mtr/cld/home.rxml http://cwx.prenhall.com/bookbind/pubbooks/aguado2/chapter4/deluxe.html Atmospheric Moisture and Precipitation Water’s changes of state Heat energy absorbed Sublimation Most important for climate: •Energy transfer •Air density Melting Ice Freezing Deposition Evaporation •Circulation Liquid Condensation •Precipitation Vapour •Transpiration Heat energy released Source: Ahrens, C.D., 1994. Meteorology Today GYk •Air stability Atmospheric Moisture and Precipitation Spraying with water used for frost protection Freezing releases the energy used for melting As long as the water releases enough heat while it freezes the fruit will not be damaged (held at 0oC) Source: Lutgens, F.K. and E.J. Tarbuck, 1998. The Atmosphere GYk Atmospheric Moisture and Precipitation Air density and water vapour concentration Wet air is less dense than dry air • • • • There is a lot of empty space between gas molecules They neither attract nor repel each other much Distances between molecules are not affected by the type of gas The number of molecules in container at same temperature and pressure independent of the type of gas. Same temperature, T, and pressure, P! (T, P do change distance between molecules! And thus the density) The molecular weights of O2 (red), N2 heavier lighter (blue) and H2O are about 32, 28, and 18, respectively. Substituting a water molecule for either an oxygen or a nitrogen molecule, will decrease the total mass of air in a volume and thus the density of the wet air is less than the density of dry air. GYk Atmospheric Moisture and Precipitation Water’s changes of state Effects: • Change energy content or temperature of air (latent heat) • Change density (and so the weight!) of air Impacts on temperature, pressure and circulation Sources of water vapour? GY Atmospheric Moisture and Precipitation Evapotranspiration Transpiration: loss of water vapour from plants by evaporation through stomata Transpiration Evaporation from leaf surface Evaporation from water surface Soil evaporation Evapotranspiration is the sum of all evaporation and transpiration • water flux from earth’s surface to the atmosphere • driving the upward water transport in plants GYk Atmospheric Moisture and Precipitation Humidity Humidity - general term for the amount of water vapour in the air • Absolute humidity - mass of water vapour in a given volume of air • Mixing ratio - mass of water vapour in a unit mass of dry air • Relative humidity • Water vapour pressure Saturation of air with water vapour <-> Over water surface in closed container an equilibrium between evaporation and condensation will form Dew Point Temperature (Dew Point) Temperature at which air would be saturated (dew formation would start) Gk Atmospheric Moisture and Precipitation Very strongly temperature dependent T [oC] H2O vapor [g/kg] 5 3.5 10 7 20 14 Source: Lutgens, F.K. and E.J. Tarbuck, 1998. The Atmosphere Water vapor (g/kg) Saturation water vapour content of air Temperature (oC) Crucial relationship for understanding the power of convection, e.g. in thunderstorms, in particular in the tropics -> hurricans GY Atmospheric Moisture and Precipitation Relative humidity Ratio of the air’s actual water vapour content relative to the amount of water vapour at saturation at the same temperature Varies with: • the amount of water vapour in the air • temperature, as temperature changes saturation water vapour content GYk Atmospheric Moisture and Precipitation Relative humidity at constant temperature Source: Lutgens, F.K. and E.J. Tarbuck, 1998. The Atmosphere GY Atmospheric Moisture and Precipitation Relative humidity at different temperatures Dew point! Source: Lutgens, F.K. and E.J. Tarbuck, 1998. The Atmosphere Gk Atmospheric Moisture and Precipitation GY1 Atmospheric Moisture and Precipitation Water vapour pressure • Water vapour pressure - partial pressure exerted by the water vapour in the atmosphere Pressure? GY Atmospheric Moisture and Precipitation The Ideal Gas Law Relationship between pressure, volume and temperature Air molecules Density Mass per volume [kg/m3] Amount of matter per volume <-> heavy/light in low atmosphere high density further up lower density G Air density Air pressure Low High Atmospheric Moisture and Precipitation Pressure the lower in the atmosphere, the more air above, the larger the weight of air above, the larger the air pressure GYk Atmospheric Moisture and Precipitation The Ideal Gas Law pV -------- = K T GY1 p - pressure V - volume T - temperature K - a constant Atmospheric Moisture and Precipitation Water vapor pressure and saturation • Water vapour pressure partial pressure exerted by the water vapour in the atmosphere • Saturation vapour pressure - pressure exerted by air saturated with water 20oC Pressure gauge H2O vapour Dry air 20oC • Saturation water vapour pressure is temperature Saturated dependent as at higher temperatures more water evaporates <-> more molecules Evaporation and condensation have higher energy occurring at the same rate GY 20oC Moist air 30oC Atmospheric Moisture and Precipitation Lifting processes and precipitation condensation level (b) Orographic lifting (a) Convective lifting Warm air Cold air (c) Fontral wedging GY1003 - Principles of Physical Geography, Lecture 14, Jörg Kaduk Converging winds (d) Convergence Converging winds Atmospheric Moisture and Precipitation Convective lifting & cloud formation • Air at surface becomes less dense (Warming from surface (Ideal Gas Law)) or increasing water vapour content) • If air is less dense than air above, air tends to rise (instability) • Air rises • Air expands due to decreasing pressure (Ideal Gas Law) • Air cools (Ideal Gas Law) - Cooling rate (no condensation): Dry adiabatic lapse rate • Air can rise further - depending on surroundings • Condensation might occur due to cooling, if dew point was reached • Condensation releases heat • air warms, expands, density drops, air rises, cools, further water vapour condenses,... Cooling rate with condensation: Wet adiabatic lapse rate GY1k Atmospheric Moisture and Precipitation Summary • Changes of state of water vapour interact with many processes • Wet air less dense than dry air • Evapotranspiration - total water flux from surface to atmosphere • Drives plant water uptake, source for all precipitation • Saturation water vapour content depends strongly on temperature • Ideal gas law relating temperature, pressure and volume • Atmospheric stability modified through reducing the density of near surface air due to warming or increasing water vapour concentration GY