Name, Date, Hr/Per_____________________________________________________________________________ MATTER & THE PERIODIC TABLE – UNIT 2 – INSTRUCTIONAL PACKET #1 UNIT 2 Vocabulary: Create notecards or a key-term foldable for Chapter 15 Vocabulary. Due __________________ Lecture 2-1: Properties of Matter Matter: - Definition Properties of Matter: - Physical Properties - Physical Changes - Chemical Properties - Chemical Changes o Signs of a chemical change Composition of Matter: Phases of Matter: Type of Volume Matter Solid Shape Particle Movement Energy / Temp. Other Notes: Liquid Gas Plasma 1 Phase Changes: (warming up) - Melting - Vaporization - Sublimation Phase Change Diagram: (Draw and label the diagram below) Phase Changes: (cooling down) - Condensation - Freezing Homework: Physical vs. Chemical Change w/s In a physical change, the original substance still exists, it has only changed in form. Energy changes usually do not accompany physical changes, except in phase changes and when substances dissolve, In a chemical change, a new substance is produced. Energy changes always accompany chemical changes. Chemical changes are always accompanied by physical Classify the following as examples of a physical change [P], a chemical change [C] or both kinds of change [P / C]. 1. _________ Sodium hydroxide dissolves in water 6. _________ Iron rusts 2. _________ Hydrochloric acid reacts with sodium 7. _________ Ice melts hydroxide to produce a salt, water and heat. 8. _________ Acid on limestone produces 3. _________ A pellet of sodium is sliced in two carbon dioxide gas 4. _________ Water is heated and changed to steam 9. _________ Milk sours 5. _________ Potassium chlorate decomposes to 10. _________ Wood rots potassium chloride and oxygen gas States of Matter – Crossword w/s [crossword follows on next page] DOWN 1. The three forms of matter (liquid, solid, and gas). (3 words – not specific; general overall term) 14. In ____, atoms move the fastest. 3. The change in a state of matter from a solid to a liquid. 15. Water changes from a liquid state to a solid-state at ____ degrees Celsius. 5. The gas state of water. (2 words) 16. The particles in ____ move back and forth in place. 8. Matter in a gas state will ____ out to fill its container 19. The particles in liquids ____ past each other. 9. The change in a state of matter from a gas to a liquid. 20. A solid always take up the same amount of this. 11. If you add heat to matter, the atoms that make up the matter will begin to move ____. 21. A state of matter that has no fixed shape and no fixed volume. 2 ACROSS 1. If you subtract heat from matter, the atoms that make up the matter will begin to move ____. 12. The change in a state of matter from a liquid to a solid. 2. The temperature at which a given substance will change from a liquid into a gas. (2 words) 13. The change in a state of matter from a liquid to a gas. 4. The particles in a solid state move around ___ point. 17. The pull on the surface of liquids that allow liquids to form drops when they fall. (2 words) 6. The number of states of matter. 18. The basic building blocks of matter. 7. You can change the state of matter by either adding or subtracting ____. 22. The temperature at which a given substance will change from a solid into a liquid. (2 words) 10. A state of matter that has no fixed shape but that has a definite volume. 23. A state of matter that has a definite shape and a definite volume. 11. Particles in a gas are ____ apart than the particles in a liquid. 24. Gases ____ to fill whatever space is available to them. 3 Lecture 2-2: Composition of Matter Composition: - Pure Substance - Mixture Pure Substance: - Elements - Compounds Practice: Mixture: - Homogeneous o Solvent Types of Solutions: - Alloy - Amalgam - Aqueous Solution Heterogeneous o examples Solution (aka: Homogeneous Mixture): - Solute - - Example - Soluble - Insoluble - Concentrated - Dilute - Temperature Making a Solution: - “Surround and Separate” Speeding up the Solution Process: - Agitation - o Surface Area Exception for Gas Solubility: - Definition Saturation of Solute: - Unsaturated - Saturated o Supersaturated - Solubility Curve (graph) - Example Saturation Point Heterogeneous Mixture: - Definition 4 - Types of Heterogeneous Mixtures: - Suspensions - Colloids o Tyndall Effect Homework: Substances vs. Mixtures w/s A substance is matter for which a chemical formula can be written. Elements and compounds are substances. Mixtures can be in any proportion, and the parts are not chemically bonded. Classify the following as to whether it is a substance or a mixture by writing “S” or “M” in the space provided. 1. _____ sodium 8. _____ cake batter 15. _____ eggs 2. _____ water 9. _____ air 16. _____ blood 3. _____ soil 10. _____ soup 17. _____ table salt 4. _____ coffee 11. _____ iron 18. _____ nail polish 5. _____ oxygen 12. _____ salt water 19. _____ milk 6. _____ alcohol 13. _____ ice cream 20. _____ cola 7. _____ carbon dioxide 14. _____ nitrogen Homogeneous vs. Heterogeneous Matter w/s Classify the following substances and mixtures as either homogeneous [HO] or heterogeneous [HE] 1. ______ flat soda pop 6. ______ aluminum foil 11. ______ alcohol 2. ______ cherry vanilla ice cream 7. ______ black coffee 12. ______ iron 3. ______ salad dressing 8. ______ sugar water 13. ______ beach sand 4. ______ sugar 9. ______ city air 14. ______ pure air 5. ______ soil 10. ______ paint 15. ______ spaghetti sauce Solutions, Colloids, and Suspensions w/s Label the following mixtures as a solution, colloid, or suspension. Give an example of each. 1. has large particles which settle out upon standing a. kind of mixture ________________________________ b. example: _____________________________________ 2. has medium sized particles which settle out upon standing; scatters light a. kind of mixture ________________________________ b. example: _____________________________________ 3. has very small particles which do not settle out upon standing a. kind of mixture ________________________________ b. example: _____________________________________ 5 Separation of Mixtures w/s Taking advantage of various physical and chemical properties, how would you separate the following mixtures into their components? 1. Sand and water ____________________________________________________________________________ _________________________________________________________________________________________ 2. Sugar and water ___________________________________________________________________________ _________________________________________________________________________________________ 3. Oil and water _____________________________________________________________________________ _________________________________________________________________________________________ 4. Sand and gravel ________________________________________________________ ___________________ _________________________________________________________________________________________ 5. A mixture of heptane (boiling point 98°C) and heptanol (boiling point 176°C) __________________________ _________________________________________________________________________________________ 6. A mixture of iodine solid and sodium chloride (Hint: Iodine is not soluble in water) _____________________ _________________________________________________________________________________________ 7. A mixture of lead and aluminum pellets ________________________________________________________ _________________________________________________________________________________________ 8. A mixture of salt and iron filings ______________________________________________________________ _________________________________________________________________________________________ A Solubility Curves w/s Answer the following questions based on Solubility graph A 1. Why do the temperatures on the graph only go from 0º C to 100º C ? 2. Which substance is most soluble at 60º C ? 3. Which two substances have the same solubility at 80º C ? 4.Which substance’s solubility changes the most from 0º C to 100º C ? 5.Which substance’s solubility changes the least from 0º C to 100º C ? 6. What is the solubility of potassium nitrate at 90º C ? 6 7. At what temperature does potassium iodide have a solubility of 150 g/ 100 cm3 water ? Continue answering the following questions based on Solubility graph A from the previous page. 8. You have a solution of sodium nitrate containing 140 g at 65º C. Is the solution saturated, unsaturated, or supersaturated ? 9. You have a solution of potassium chlorate containing 4 g at 65º C. How many additional grams of solute must be added to it, to make the solution saturated ? 10. A solution of potassium iodide at 70º C contains 200 g of dissolved solute in 100 cm3 water. The solution is allowed to cool. At what new temperature would crystals begin to start forming ? 11. What is the general trend that you see on the graph? Use the IV and DV in your answer. Answer the following questions based on Solubility graph B 1. At which temperature do KBr and KNO3 have the same solubility? 2. At which temperature do NaCl and KNO3 have the same solubility? 3. At which temperature do NaClO3 and KNO3 have the same solubility? 4. At 60oC, how much KNO3 can 100 g of water hold? 5. At 80oC, how much NaCl can 100 g of water hold? 6. At 0oC, how much KBr can 100 g of water hold? 7. A solution of NaCl contains 50g at 70 º C. Is the solution saturated, unsaturated, or supersaturated ? 8. A solution of KBr contains 100g at 95 º C. Is the solution saturated, unsaturated, or supersaturated ? 9. Which compound's solubility changes very little with temperature? 10. Which compound's solubility changes the most with temperature? 11. Which compound has the greatest solubility at 60oC? 12. Which compound has the least solubility at 20o C? 7 Element, Compound, Solution, or Heterogeneous Mixture? w/s Identify each as an element [E], a compound [C], a solution [S], or a heterogeneous mixture [HM]. 1. _____ Sand 11. _____ Salad Dressing 20. _____ Calcium Nitrate 2. _____ Salt 12. _____ Salt Water 21. _____ Kool-Aid ® 3. _____ Pure Water 13. _____ Raisin Bran 22. _____ Sugar water 4. _____ Soil 14. _____ Silver 23. _____ Chocolate milk 5. _____ Soda 15. _____ Lithium Carbonate 24. _____ Salt water 6. _____ Pure Air 16. _____ Apple Pie 25. _____ Coffee with milk 7. _____ Carbon Dioxide 17. _____ Iced Tea (with powder, well mixed) 26. _____ Cup of tea with tea leaves floating in it 18. _____ Potassium 27. _____ Salt 19. _____ Soda 28. _____ Chocolate chip cookies 8. _____ Gold 9. _____ Bronze 10. _____ Oxygen Reading a Phase Diagram w/s Examine the phase diagram below, then answer the questions which follow. 1. If you were to have a bottle containing compound X in your closet, what phase would it most likely be in? @ sea level, pressure = 1 atm 2. What is the triple point of compound X (At what temperature and pressure will all three phases coexist)? 3. If you have a bottle of compound X at a pressure of 3 atm and temperature of 1000 C, then raise the temperature to 4000 C, what phase transition(s) would occur? 4. If you have a bottle of compound X at a pressure of 4 atm and temperature of 1000 C, then raise the temperature to 8000 C, what phase transition(s) would occur? 5. Why can’t compound X be brought to a boil at a temperature of 2000 C? 7. At 5000 C and at 2 atm, in what state is the substance? ________ 8. At 4500 C and at 4 atm, in what state is the 6. Is it possible for humans to drink compound X? Why or why not? 8 substance? ________ 9. At 7500 C and 6 atm, in what state is the substance? ________ Lecture 2-3: Atoms Atom: - Definition - Composed of Subatomic Particles: - Protons - Electrons - Quarks? - Neutrons Elements: - Definition - Atomic Number - Chemical Symbol - Atomic Mass Nucleon Practice [see graphic above – label the image and write # of subatomic particles]: Writing Elements: - Steps Counting Particles: - Protons = - Neutrons = - Electrons = If electrons differ: - Ion If neutrons differ: - Isotope - Example - Example If protons differ: Allotrope: - Definition Electron Dot Models: Practice drawing electron dot models: Homework: 9 Elements to Memorize List the chemical symbol for each element and memorize them 10 per night. You will be quizzed on them in these sets of ten – SPELLING COUNTS. After you have been quizzed a few times, you will have a large quiz with 25-30 of these 45 elements. This large quiz will contain one or more bonus elements ______1. Hydrogen ______16. Titanium ______31. Silicon ______2. Iodine ______17. Calcium ______32. Gold ______3. Lithium ______18. Manganese ______33. Tin ______4. Helium ______19. Strontium ______34. Zinc ______5. Sodium ______20. Iron ______35. Lead ______6. Neon ______21. Barium ______36. Mercury ______7. Potassium ______22. Cobalt ______37. Nitrogen ______8. Argon ______23. Radium ______38. Uranium ______9. Cesium ______24. Nickel ______39. Phosphorous ______10. Krypton ______25. Boron ______40. Plutonium ______11. Francium ______26. Platinum ______41. Oxygen ______12. Xenon ______27. Aluminum ______42. Sulfur ______13. Beryllium ______28. Copper ______43. Fluorine ______14. Radon ______29. Carbon ______44. Chlorine ______15. Magnesium ______30. Silver ______45. Bromine Elements and their Symbols w/s Write the symbols for the following elements. 1. ______ oxygen 6. ______ carbon 11. ______ magnesium 16. ______ silver 2. ______ hydrogen 7. ______ helium 12. ______ manganese 17. ______ lead 3. ______ chlorine 8. ______ nitrogen 13. ______ neon 18. ______ iron 4. ______ sodium 9. ______ copper 14. ______ bromine 19. ______ calcium 5. ______ fluorine 10. ______ sulfur 15. ______ phosphorus 20. ______ potassium Write the name of the element that corresponds to each of the following symbols 21. ____________ Cu 26. ____________ Pb 31. ____________ Ca 36. ____________ Sn 22. ____________ K 27. ____________ Fe 32. ____________ Ag 37. ____________ H 23. ____________ C 28. ____________ Na 33. ____________ P 38. ____________ F 24. ____________ Au 29. ____________ S 34. ____________ O 39. ____________ Ni 25. ____________ Zn 30. ____________ Al 35. ____________ I 40. ____________ Hg Number of Atoms in a Formula w/s Determine the number of atoms in the following chemical elements. 1. ______ NaCl 6. ______ Ba(OH)2 11. ______ Cu(NO3)2 16. ______ Fe2O3 2. ______ H2SO4 7. ______ NH4Br 12. ______ KMnO4 17. ______ NaC2H3O2 3. ______ KNO3 8. ______ Ca(PO4)2 13. ______ H2O2 18. ______ Mg(C2H3O2)2 4. ______ CaCl2 9. ______ Al2(SO4)3 14. ______ H3PO4 19. ______ Hg2Cl2 5. ______ C2H6 10. ______ Mg(NO3)2 15. ______(NH4)3PO4 20. ______ K2SO3 Parts of an Atom w/s An atom is made up of protons and neutrons which are in the nucleus, and electrons which are in the electron cloud surrounding the atom. The atomic number equals the number of protons. The electrons in a neutral atom equal the number of protons. The mass number equals the sum of the protons and neutrons. The charge indicates the number of electrons that have been lost or gained. A positive charge indicates the number of electrons (which are negatively charged) lost. A negative charge indicates the number of electrons gained. Complete the following chart. Element / Ion 24 12 39 19 23 11 19 9 27 13 1 1 24 Mg K Na+1 F-1 Al+3 H Mg+2 Ag S-2 2 1 35 H Cl- Atomic Number Mass Number Charge # of Protons # of Neutrons # of Electrons Be+2 11 Parts of the Atom w/s Using the Periodic Table of the Elements, determine the number of protons, neutrons, and electrons in each of the following atoms. Draw a model of the atom showing the electrons in the proper energy levels. Model: _____ protons 1 1 H _____ neutrons _____ electrons Model: _____ protons 12 6 C _____ neutrons _____ electrons Model: _____ protons 23 11 Na _____ neutrons _____ electrons Model: _____ protons 21 15 P _____ neutrons _____ electrons Model: _____ protons 16 8 O _____ neutrons _____ electrons 12 Valence Clues w/s Atomic Structure – Create the appropriate Bohr model. Use the PT to fill in the info for each element given. Element: Boron Number of Valence Electrons: _______ Group Number: _______ Oxidation Number: _______ Period Number: _______ Circle One: metal, non-metal, metalloid, noble gas, halogen Element: Silicon Number of Valence Electrons: _______ Group Number: _______ Oxidation Number: _______ Period Number: _______ Circle One: metal, non-metal, metalloid, noble gas, halogen Element: Nitrogen Number of Valence Electrons: _______ Group Number: _______ Oxidation Number: _______ Period Number: _______ Circle One: metal, non-metal, metalloid, noble gas, halogen Element: Carbon Number of Valence Electrons: _______ Group Number: _______ Oxidation Number: _______ Period Number: _______ Circle One: metal, non-metal, metalloid, noble gas, halogen Element: Hydrogen Number of Valence Electrons: _______ Group Number: _______ Oxidation Number: _______ Period Number: _______ Circle One: metal, non-metal, metalloid, noble gas, halogen 13 Element: Neon Number of Valence Electrons: _______ Group Number: _______ Oxidation Number: _______ Period Number: _______ Circle One: metal, non-metal, metalloid, noble gas, halogen Element: Fluorine Number of Valence Electrons: _______ Group Number: _______ Oxidation Number: _______ Period Number: _______ Circle One: metal, non-metal, metalloid, noble gas, halogen Element: Oxygen Number of Valence Electrons: _______ Group Number: _______ Oxidation Number: _______ Period Number: _______ Circle One: metal, non-metal, metalloid, noble gas, halogen Element: Calcium Number of Valence Electrons: _______ Group Number: _______ Oxidation Number: _______ Period Number: _______ Circle One: metal, non-metal, metalloid, noble gas, halogen Element: Helium Number of Valence Electrons: _______ Group Number: _______ Oxidation Number: _______ Period Number: _______ Circle One: metal, non-metal, metalloid, noble gas, halogen 14 Bohr Model Practice w/s For each element, write the total number of electrons on the line. Then color the correct number of electrons for each orbit. Remember, fill the orbit closest to the nucleus first, but never exceed the number each orbit can hold. This number is _______ for the first shell and _______ for the shells that come afterward. Check the Periodic Table to find out how many electrons each element actually has. To indicate the number of protons & neutrons in the nucleus, draw a line extending from the center pointing to your labels. 15 Now, draw your own Bohr model diagrams for the elements listed below. Lithium (Li) _________ Sulfur (S) _________ Neon (Ne) _________ Bohr Models w/s Check the periodic table to find out how many of each type of subatomic particle each element below has. Small circles in the images will represent possible electron locations. For each element [as modeled in lecture]: a. write the atomic number on the line provided c. draw electron clouds with: b. draw and label the nucleus of the atom i. blue inner electrons & red valence electrons Sodium (Na) _________ 16 Phosphorous (P) ________ Aluminum (Al) ________ Carbon (C) _______ Silicon (Si) ________ Oxygen (O) ________ Chlorine (Cl) ________ Argon (Ar) ____ Lecture 2-4: Electron Configuration Background Info: - Groups - Orbitals: - Lewis Dot Quantum Numbers: - First - Periods - - Bohr Model Second - Third Example(s) Homework: Electron Configurations - Tutorial An electron configuration is a method of indicating the arrangement of electrons about a nucleus. A typical electron configuration consists of numbers, letters, and superscripts with the following format: 1. A number indicates the energy level [“the quantum number”] 2. A letter indicates the type of orbital; s, p, d, f. [we will not use f] a. “s” orbitals can hold up to 2 electrons b. “p” orbitals can hold up to 6 electrons c. “d” orbitals can hold up to 10 electrons d. Orbitals fill in this order: 1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d, 5p…and so on. i. “d” orbitals are filled after the “s” orbital of the next energy level 1. you can clearly see this on the periodic table!! ii. You will not be asked for anything further than this on an exam. 3. A superscript indicates the number of electrons in the orbital. Example: ls2 means that there are two electrons in the “s” orbital of the first energy level. The element is helium. The periodic table can help us figure out what these configurations are. To the left are the “s” orbitals. The “p” orbitals are shown on the right, and the “d” orbitals are in the center. The periodic table has been labeled with the correct period numbers on the far left and on the far right for you. You already know that the group number helps indicate the number of valence electrons and the charge/oxidation number; the period number tells you which energy level/shell those electrons belong to. The area of the periodic table which corresponds to elements in the “d” level [the transition metals] belong to one energy level less than the period that it is in. This has been noted for you on the chart to the right. Example: Chlorine – Chlorine is in group 17. Chlorine has 17 electrons [which is totally a coincidence, not related to group number…]. Chlorine is in period 3. Following the rules of filling electron levels… Chlorine has: a. 2 electrons in the 1s level [full] = 1s2 d. 2 electrons in the 3s level [full] = 3s2 b. 2 electrons in the 2s level [full] = 2s2 e. 5 electrons in the 3p level [not full] = 3p5 6 c. 6 electrons in the 2p level [full] = 2p Check it out – it matches the electron configuration!! Trace this across the periodic table left to right. When you get to the end of a period, go to the next period starting at the right…etc. You cross: a. 2 elements in the “s” block of the period 1 c. 6 elements in the “p” block of the period 2 b. 2 elements in the “s” block of the period 2 d. 2 elements in the “s” block of period 3 17 e. …and Chlorine is the 5th element in the “p” block of period 3 Now, you try – write the full electron configuration of the following elements. Helium______________________________________________________________ Neon______________________________________________________________ Sodium______________________________________________________________ Zinc______________________________________________________________ Sulfur______________________________________________________________ Palladium_____________________________________________________________ Electron Configurations w/s PART A: Longhand Electron Configuration – Use the patterns within the periodic table to write longhand electron configurations for the following atoms. 1. Symbol: __Mg__ # of electrons: ______ Long-Hand Electron Configuration: 2. Symbol: __P__ # of electrons: ______ Long-Hand Electron Configuration: 3. Symbol: __V__ # of electrons: ______ Long-Hand Electron Configuration: 4. Symbol: __Ge__ # of electrons: ______ Long-Hand Electron Configuration: 5. Symbol: __Kr__ # of electrons: ______ Long-Hand Electron Configuration: 6. Symbol: __O__ # of electrons: ______ Long-Hand Electron Configuration: PART B: Shorthand Electron Configurations – Use the patterns within the periodic table to write longhand electron configurations for the following atoms. 18 7. Symbol: __Ca__ # of electrons: ______ Short-Hand Electron Configuration: 8. Symbol: __Pb__ # of electrons: ______ Short -Hand Electron Configuration: 9. Symbol: __F__ # of electrons: ______ Short -Hand Electron Configuration: 10. Symbol: __O__ # of electrons: ______ Short -Hand Electron Configuration: __________ 11. Symbol: __S__ # of electrons: ______ Short -Hand Electron Configuration: __________ 12. Symbol: __Al__ # of electrons: ______ Short -Hand Electron Configuration: __________ 13. Symbol: __Cs__ # of electrons: ______ Short -Hand Electron Configuration: __________ 14. Symbol: __Sb__ # of electrons: ______ Short -Hand Electron Configuration: __________ Valence Electrons & the Periodic Table w/s Group = vertical columns; begins with H/Li, Be, skips transition metals, continues with B-He/Ne; Period = horizontal rows [not needed for this w/s] Using the information above and a periodic table, complete the tables below with the requested information. Number of… Chemical Symbol Chemical Name Atomic # e-s _____ Li nos _____ p+s _____ nos _____ p+s _____ nos _____ p+s _____ nos _____ group # _____ valence e-s _____ oxidation # _____ e-s _____ Ne p+s _____ group # _____ valence e-s _____ oxidation # _____ e-s _____ F nos _____ group # _____ valence e-s _____ oxidation # _____ e-s _____ O p+s _____ group # _____ valence e-s _____ oxidation # _____ e-s _____ N nos _____ group # _____ valence e-s _____ oxidation # _____ e-s _____ C p+s _____ group # _____ valence e-s _____ oxidation # _____ e-s _____ B nos _____ group # _____ valence e-s _____ oxidation # _____ e-s _____ Be p+s _____ p+s _____ nos _____ group # _____ valence e-s _____ oxidation # _____ What do you notice about: 1. …the number of valence e-s as you go across the periodic table? 2. …the number of valence e-s compared to the group number? 19 Predict how many valence electrons each would have: Ba ______, Br ______, Xe ______, At ______ Electron Configuration Practice w/s In the space below, write the unabbreviated [long-hand] electron configurations of the following elements: 1. sodium _________________________________________________________________________________ 2. iron __________________________________________________________________________________ 3. bromine ______________________________________________________________________________ 4. barium _____________________________________________________________________________ In the space below, write the abbreviated [short-hand] electron configurations of the following elements: 5. cobalt _______ 6. silver _______ 7. tellurium _______ 8. radium _______ Determine what elements are denoted by the following electron configurations: 9. 1s2 2s2 2p6 3s2 3p4 ____________________ 11. 1s2 2s2 2p6 3s2 3p6 4s2 __________________________ 10. 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s1 _______________ 12. 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p1 ___________________ Determine which of the following electron configurations are valid, and which are invalid. 13. 1s2 2s2 2p6 3s2 3p6 4s2 4d10 4p5 _______________ 15. 1s2 2s2 2p9 3s2 3p6 4s2 ____________________ 14. 1s2 2s2 2p6 3s3 3d5 ____________________ 16. 1s2 2s2 2p6 3s2 3p4 ____________________ Explain what is wrong with the following electron configurations: 17. 1s2 2s2 2p6 3s2 3p6 4s2 4d10 4p6 ___________________________________________________________________ 18. 1s2 2s2 2p6 3s3 3d5 _____________________________________________________________________________ Use the following clues to identify the element. Show any figuring in the space below. 19. This element has a 3p sublevel that contains 3 electrons. 20. This element has a 4s sublevel with 2 electrons for its outermost electrons. 21. This element has 1 electron in its 3d sublevel. 22. This element has 5 electrons in its 5p sublevel 23. This element has a completely filled 3p sublevel for its outermost electrons. 24. This element has 2 electrons in its 6p sublevel. Lecture 2-5: Periodic Table Periodic Table: - Describes… Properties: - Chemical Properties 20 - Consists of - Valence Electrons Charge: - Octet Rule - Cation - Anion Mendeleev’s Contributions: - First Periodic Table - Undiscovered Elements Periodic Table: - Columns called - - Rows called - - Groups Oxidation #: - Definition - Practice Group 1: - Name - Characteristics Group 2: - Name - Characteristics Groups 3-12: - Name - Characteristics - Lanthanides & Actinides Metals Non-Metals Location Appearance “Shape-Ability” Conductivity Physical State Charge Metalloids: - Properties - Location Group 17: - Name - Characteristics Group 18: - Semi-conductors 21 - Name Electronegativity: - High - - Characteristics Low Reactivity: - Definition - - Increases - Decreases Metals - Non-Metals Atomic Radius: - Properties Homework: Color the Trends in the Periodic Table w/s Color according to trends listed; record colors by coloring in terms provided on table. Metals Non-Metals Metalloids Zig-Zag Divider [red] [blue] [purple] [make line darker] @ Standard Pressure & Temperature: Solid Liquid Gas [red] [blue] [white] 22 Non-Metals Alkali Metals Alkaline Earth Metals Metalloids Halogens [blue] [red] [green] [purple] [yellow] Transition Metals Noble Gases Lanthanides Actinides [brown] [white] [light orange] [orange] Draw arrows representing the trend(s) in Electronegativity. Draw arrows representing the trend(s) in Atomic Radius [size]. 23 An Elemental Tale: The Gold Dust Kid w/s The Kid mounted his trusty steed, old [B] ___________. His shooting [Fe] ____________ strapped to his side, he headed out for the bright [Ne] ____________ lights of Toronto, aiming to rob the mid-day stage. There was sure to be a load of precious [U] ______________ aboard, and probably [K] ____________, too. Inhaling a deep breath of [O] ____________ he coughed on the [S] ____________ from the nearby mills. Since the [Hg] ______________ was climbing, he quenched his thirst with some H2O, tasting the [Cl] ____________ all big cities like Brockville had. As he headed north his bones ached from [Ca] _____________deposits built up over the years of riding the [Zn] _________ trail. Overhead a [He] __________-filled balloon floated in the breeze; the sun beat down like burning [P] _______________. Soon he spotted the stage, guarded only by a sheriff with a [Sn] ____________ badge. "Halt," he yelled. "or I'll fill you full of [Pb] ____________." The sheriff drew his gun, but alas, was too slow. The Kid's gun, blazing like flaming [Mg] ______________ did the [Cu] ____________ in. Anyone who drew on the Kid should know his life wasn't worth a plugged [Ni] ______________. A [Pt] ____________ blonde riding beside the [Al] ______________-framed coach rode for her life when the Kid pulled out some [N] ____________ compounds, preparing to blow the safe to atoms. Suddenly, a shout rang out, "Hi Ho [Ag] ___________ and a masked man on a white horse raced across the [Si] ____________ sands like [Na] ______________ skittering on H2O. A [H] ______________ bomb would not have stopped the lawman; the Kid had met his doom. The rest of his life was to be spent behind [Co] ___________ steel bars, a warning to all who flirt with danger. Your first detention may be the initial step in a [C] ____________ copy life of the saga of the [Au] ____________ dust Kid. ~Author unknown Protons, Neutrons & Electrons Practice w/s Adapted from a worksheet from ChemFiesta.com Directions: Using a periodic table and your knowledge, fill in the missing chart information below. o + (same as #p ) Atomic Symbol Atomic Number (Mass - #n ) (same as At #) (same as #e ) (Mass - #p ) (same as #p ) (#p +# n ) Protons Neutrons Electrons Atomic Mass B + + 6 11 23 31 39 39 29 89 35 43 98 Pb 207 103 89 Mo 70 227 54 81 24 + 204 o 100 157 No 259 Make Your Own Periodic Table w/s For chemistry help, visit www.chemfiesta.com © 2009 All Rights Reserved You’ve heard how the periodic table was invented and had a chance to make one in class. Now that you’re a pro at classifying elements, you get a chance to make your very own periodic table using real elements. If you do this correctly, your classification scheme should be the same as the actual periodic table. Unfortunately, you’re not going to be given the names of the elements or a complete list of their properties. Using partial information (such as scientists had in the old days), see if you can arrange these real elements into their proper periods and families. One hint: These elements should be arranged into a grid that’s three boxes tall by four boxes wide, with no blank spaces. [ie, the one below] In no particular order: Element 1: Solid, metal, does not corrode in air, density = 1.85 g/mL. Element 2: Yellow gas, highly dangerous to handle, toxic in low doses. Element 3: White, shiny, metallic solid, reacts slightly in air, density = 1.55 g/mL. Element 4: Colorless gas, stable in air, forms very few chemical compounds. Element 5: White, shiny metallic solid, unreactive, good electrical conductor, ductile, density = 10.5 g/mL. Element 6: Orange-red metallic solid, ductile, density = 8.9 g/mL. Element 7: White metallic solid, reacts easily in air, density = 3.5 g/mL. Element 8: Colorless gas, unreactive with any element. Element 9: Red nonmetallic liquid, irritates skin and lungs. Element 10: Colorless gas, denser than air, forms no chemical compounds. Element 11: Radioactive metalloid, very little known about its properties. Element 12: Yellow metallic solid, extremely malleable, unreactive with most chemicals, density = 19.3 g/mL. Good luck! 25 Trends in the Periodic Table – Graphing w/s Graph paper is 32 x 32 1. Draw a line in the middle of a piece of graph paper, separating the page into top and bottom [DONE FOR YOU]. On the top, plot a graph of ionization energy (y-axis) vs. atomic number (x-axis). On the bottom plot a separate graph of atomic radius vs. atomic number. For each graph, connect successive dots with straight lines. Also, ensure that identical atomic numbers are plotted on the same vertical position on the sheet (i.e. atomic number 1 in the top graph should be on the same line as atomic number 1 in the bottom graph – your X axis is the same). 2. Examine your graph of ionization energy (IE) vs. atomic number. a. Which elements are found at the main peaks on your graph (there should be 3)? What do these elements have in common? b. Which elements are found at the main valleys on your graph (there should be 3)? What do these elements have in common? 3. Examine your graph of atomic radius verses atomic number. a. Which elements are found at the peaks on your graph? What do these elements have in common? b. Which elements are found at the valleys on your graph? What do these elements have in common? 26 4. How are atomic radii and ionization energy related (i.e. as atomic radius increases, what happens to the ionization energy)? 5. Generally, as you go from left to right across a period on the periodic table, what happens to… a. atomic radius? b. ionization energy? 6. Generally, as you go down a group in the periodic table, what happens to atomic radius and IE? 7. When Na forms an ion it loses its outer electron to become Na+. Draw Bohr diagrams for Na and Na+. a. What element does Na+ resemble (with respect to its electron arrangement)? b. In general, which group’s electron configuration do the alkali metals resemble when they form ions (i.e. lose an outer electron)? 8. Why does radius increase as you go down a group (hint: think of Bohr diagrams)? 9. Why would an increase in radius make it easier to lose an outer electron (i.e. give a lower ionization energy)? 10. What happens to the number of protons in the nucleus as you go across a period? Use this to explain the trends in atomic radius and ionization energy across a period. 11. There is one group that is usually ignored because it does not follow the trends in the periodic table. Which group is usually ignored? 12. Define electron affinity. In which corner of the periodic table is it highest? Explain why this is so. 13. Define Electronegativity. Where on the periodic table is it highest? Explain why this is the case. Periodic Table Assignment w/s [crossword follows on next page] ACROSS 1. Synthetic elements with atomic numbers greater than 93 5. This law states that the properties of elements repeat as a function of their atomic number 7. Silicon is in this period 8. Elements were originally placed in order of atomic __, now they are in order of atomic __. 9. The group that consists of very nonreactive gases 10. Number of elements known in 1800 13. Element 101 was named in his honor 17. The periodic table is normally drawn with 18 columns. A more accurate representation has ___ columns 19. Most nonmetals are in this state 20. Nonmetal that is a liquid at SATP 21. The general name given to a column in the periodic table 22. According to figure 6, when aluminum combines with oxygen, three oxygen atoms combine with this many aluminum atoms DOWN 2. Elements that most closely follow the 12. Iodine belongs to this group periodic law 14. The first alkali metal 3. The first scientist to organize elements 15. This element was assigned a relative atomic based on repeating patterns mass of one because it is the lightest element 4. The modern name for eka-silicon 16. The state of matter represented by (aq) 6. Most elements are ___, since they fall to the 18. Silicon is in this group left of the "staircase line" 20. The staircase that separates metals and 11. The general name given to a row (left-to-right) nonmetals begins below this element in the periodic table 27 T R A N S U R A N I C D E O P B R E E R S E E I N T N A R T E W E N T Y O N E I V E I V A On the periodic table on the following page… 1. Place a large G in boxes that house elements that are gases at SATP, and a large L in boxes that contain elements that are liquids. The rest of the elements are solids; do not write anything in these boxes. 2. Darken the “staircase line” that divides metals from non-metals 28 3. Metalloids (i.e. semi-conductors) are elements that have properties midway between metals and non-metals. The metalloids are: B, Si, Ge, As, Sb, Te, Po, At. Identify the metalloids by drawing diagonal lines in these boxes. 4. Notice that each group (column) in the periodic table is identified at the top with a number and/or letter. There are two conventions used in the textbook. Label the groups that end in A (e.g. IA, IIA, IIIA, etc). 5. Frame and color the following groups (note: H is not an IA metal): Alkali metals, alkaline earth metals, halogens, noble gasses, transition metals, the inner transition elements (made up of lanthanides and actinides). 6. Create a legend for your periodic table. Legend: Fun Reviewing the Periodic Table w/s 1 Size of an atom. MOATIC RUDIAS 2 Atomic # = # of these. RNTOPSO 3 Rows in the periodic table. DORIPE 4 A chemical symbol represents an ___. LETNEEM 5 Exist in the nucleus of an atom. NENSOTRU 6 An element is made of one of these. TOAM 7 A diatomic nonmetal which forms a green gas. CLRNHOIE 8 Similar to oxidation number. HEGACR 9 Most are cations. TEMLA 10 Metals in group 1. LIAKAL 44 19 8 14 7 21 25 37 35 42 22 32 28 36 46 49 11 Most elements exist as ___ at room temperature. DOSLIS 12 Any element in group 18. NELBO ASG 13 Elements which donate electrons if ionically bonded. TIOPESIV CASNTIO 41 54 2 27 26 33 43 29 14 Protons + neutrons = this. CIMTAO SAMS 15 The outer shell of electrons. 16 17 20 CAVNEEL LEHSL 12 Every valence shell [except the first] strives TOCET LURE to have 8 electrons. Each element has IATOCM BURENM its own of this. 6 34 18 Columns on the periodic table. PROUG RO LAMFIY 19 Metals in group 2. KELLANAI TEARH 20 Elements which accept electrons if ionically bonded. NEGVIATE NOINA 21 A proton + a neutron = this. 22 Similar to charge. 23 39 48 5 24 NOATIOXID Groups 3-12. 17 NAISONTITR 53 29 25 Surround the nucleus of an atom. CENTEOLRS 26 The most electronegative element. ULFIENOR 27 Contains properties of both a metal and a non-metal. MOETADLIL Creator of our modernday periodic table. Increases as you move across CLEIENAVT [L-R] on the GOEYRITT periodic table. Exist as liquids MOREBNI at room DAN temperature. CYRUREM 31 51 NEELUCNO LNTENMOA 30 15 40 Most are anions. 29 10 52 24 28 23 50 11 16 30 1 VEMLENEDE 3 18 45 38 47 4 Use the numbers given in your unscrambled answers to solve the puzzle below. J 1 2 3 4 5 6 7 8 9 10 11 12 13 ? 24 30 25 26 , 27 28 29 15 16 , 30 . 14 31 4 32 33 J 17 18 19 20 21 22 W 34 35 !! 36 , 23 37 38 39 40 41 . 42 43 12 44 45 46 47 48 49 50 51 52 53 54 Periodic Table Practice Test adapted from talsc.com - The Active Learning Science Classroom 1. In your own words, sum up the periodic law. 2. In the Periodic Table, rows are known as ____________________. 3. In the Periodic Table, columns are known as ____________________. 4. Group 1 is referred to as ____________________. 5. Group 2 is referred to as ____________________. 6. Groups 3 through 12 are known as ____________________. 7. Group 17 is known as ____________________. 8. Group 18 is known as ____________________. 9. There are two major families in the periodic table. What are they? 10. How did Mosley arrange his periodic table? 11. How did Mendeleev arrange his periodic table? 12. Explain the difference in ionization energy for sodium and magnesium. 13. True or false. Non-metals are an excellent conductor of electricity. 14. Argon is in group 18. Does group 18 have a high reactivity rate or a low reactivity rate? Why? 15. As you move down Group 1, does reactivity increase or decrease? Why? 16. As you move down group 17, does reactivity increase or decrease? Why? 17. Lithium is a shiny metal. When cut, it dulls quickly. It also reacts violently with water. Name another element that would possibly show the same characteristics. 18. This group of elements are harder, stronger than group 1. They also have a higher melting point. Which group are they? 19. This group of elements means “salt-former.” They are very reactive. They have an s2p5 electron configuration. Which group are they? 20. Circle the element with the higher ionization energy. a. Sodium vs. Magnesium b. Oxygen vs. Fluorine c. Iodine vs. Bromine d. Lithium vs. Sodium 21. Which has the larger…? Nitrogen vs. Oxygen a. Ionization Energy b. Atomic Radius 22. Which has the larger…? Magnesium vs. Calcium a. Ionization Energy b. Atomic Radius c. Electronegativity c. Electronegativity 31 State the Trend. Trend Down Trend Across 23. Ionization Energy 24. Atomic Radius 25. Electronegativity 26. In 2-3 sentences, state why the downwards trend of atomic radius occurs that way. 27. In 2-3 sentences, state why the across trend of ionization energy occurs that way. 28. In 2-3 sentences, state why the across trend of melting point occurs that way. Identify the following elements. 32 29. ________________ Period 4, Group 12 32. ________________ Calcium is in this row. 30. ________________ Filled with the 2p5 electron. 33. ________________ Nitrogen is in this column. 31. ________________ 9th e- in the 4d sub-level. 34. ________________ Chlorine is in this group.