Quarterly 1 Review Trupia ____1. Which subatomic particles have a mass of approximately 1 atomic mass unit each? (1) proton and electron (2) proton and neutron (3) neutron and positron (4) electron and positron ____6. All atoms of a given element must contain the same number of (1) protons (2) neutrons (3) electrons plus neutrons (4) protons plus neutrons ____2. In Rutherford's gold foil experiments, some alpha particles were deflected from their original paths but most passed through the foil with no deflection. Which statement about gold atoms is supported by these experimental observations? (1) Gold atoms consist mostly of empty space. (2) Gold atoms are similar to alpha particles. (3) Alpha particles and gold nuclei have opposite charges. (4) Alpha particles are more dense than gold atoms. ____7. What is the nuclear charge of an atom with a mass of 23 and an atomic number of 11? (1) 11+ (3) 23+ (2) 12+ (4) 34+ ____8. What is the nuclear charge of an iron atom (Fe)? (1) +26 (3) +56 (2) +30 (4) +82 ____9. What is the charge of the nucleus in an atom of oxygen-17? (1) 0 (3) +8 (2) –2 (4) +17 ____3. Experiments performed to reveal the structure of atoms led scientists to conclude that ____10. What is the atomic number of an element an atom's that has six protons and eight neutrons? (1) positive charge is evenly distributed (1) 6 (3) 8 throughout its volume (2) 2 (4) 14 (2) negative charge is mainly concentrated in its nucleus ____11. What is the atomic number of an element (3) mass is evenly distributed throughout its whose atoms each contain 47 protons, 60 volume neutrons, and 47 electrons? (4) volume is mainly unoccupied (1) 13 (3) 60 (2) 47 (4) 107 ____4. Which of the following particles has the smallest mass? ____12. Compared to a proton, an electron has (1) neutron (3) proton (1) a greater quantity of charge and the same (2) electron (4) hydrogen atom sign (2) a greater quantity of charge and the opposite ____5. Which subatomic particle has a negative sign charge? (3) the same quantity of charge and the same (1) proton (3) neutron sign (2) electron (4) positron (4) the same quantity of charge and the opposite sign Quarterly 1 Review Trupia ____13. The total mass of the protons in an atom of gold-198 is approximately (1) 79 atomic mass units (2) 119 atomic mass units (3) 198 atomic mass units (4) 277 atomic mass units ____20. All the isotopes of a given atom have (1) the same mass number and the same atomic number (2) the same mass number but different atomic numbers (3) different mass numbers but the same atomic number (4) different mass numbers and different atomic ____14. An atom of fluorine has a mass of 19 atomic numbers mass units. The total number of protons and neutrons in its nucleus is ____21. The atomic mass of an element is the (1) 9 (3) 19 weighted average of the (2) 10 (4) 28 (1) number of protons in the isotopes of that ____15. The atomic mass of an atom is measured in element atomic mass units. This unit is based on (2) number of neutrons in the isotopes of that (3) 16O (1) 1H element (4) 12C (2) 14N (3) atomic numbers of the naturally occurring isotopes of that element ____16. An atomic mass unit is defined as exactly (4) atomic masses of the naturally occurring 11 (1) 12 the mass of a 12C atom isotopes of that element 11 the mass of a 14N atom (2) 14 11 (3) 16 the mass of a 16O atom ____22. Which atom contains exactly 15 protons? 11 19 (1) phosphorus-32 (3) oxygen-15 (4) 19 the mass of a F atom (2) sulfur-32 (4) nitrogen-15 ____17. Which two particles make up most of the ____23. Isotopes of an element must have different mass of a hydrogen-2 atom? (1) electron and neutron (3) proton and neutron (1) atomic numbers (2) electron and proton (4) proton and positron (2) mass numbers (3) numbers of protons ____18. What is the total number of neutrons in the (4) numbers of electrons nucleus of a neutral atom that has 19 electrons and a mass number of 39? 14 ____24. The nuclides 14 6 C and 7 N are similar in that (1) 19 (3) 39 they both have the same (2) 20 (4) 58 (1) mass number (3) number of neutrons ____19. Which isotopic notation represents an atom of carbon-14? (3) 614C (1) 68C 8 (4) 14 (2) 6C 6 C (2) atomic number (4) nuclear charge ____25. Which electron configuration represents an atom in an excited state? (1) 2–7 (3) 2–8–1 (2) 2–6–2 (4) 2–8–8–2 ____26. Which is the configuration of an atom in the ground state? (1) 2-8-2 (3) 2-7-2 (2) 2-8-3 (4) 2-7-3 Quarterly 1 Review Trupia ____27. The principal quantum number of the outermost electron of an atom in the ground state is n = 3. What is the total number of occupied principal energy levels contained in this atom? (1) 1 (3) 3 (2) 2 (4) 4 ____28. What causes the emission of radiant energy that produces characteristic spectral lines? (1) neutron absorption by the nucleus (2) gamma ray emission from the nucleus (3) movement of electrons to higher energy levels (4) return of electrons to lower energy levels ____29. Which electron configuration represents an atom in an excited state? (1) 2-2 (3) 2-8 (2) 2-2-1 (4) 2-8-1 ____30. Which electron configuration represents an atom of aluminum in an excited state? (1) 2-7-4 (3) 2-8-3 (2) 2-7-7 (4) 2-8-6 ____31. In an atom that has an electron configuration of 1s22s22p3, what is the total number of electrons in its sublevel of highest energy? (1) 1 (3) 3 (2) 2 (4) 4 ____32. An atom of phosphorus is in the ground state. The total number of orbitals that contain only one electron is (1) 5 (3) 3 (2) 2 (4) 4 ____33. What is the maximum number of electrons in an orbital of any atom? (1) 1 (3) 6 (2) 2 (4) 10 ____34. Which of the following electron configurations represents the element with the smallest covalent radius? (3) 1s22s22p4 (1) 1s22s22p2 2 2 3 (2) 1s 2s 2p (4) 1s22s22p5 ____35. What is the total number of occupied sublevels in the third principal energy level of a zinc atom in the ground state? (1) 1 (3) 3 (2) 2 (4) 4 ____36. Which electron configuration represents a neutral atom of nitrogen in an excited state? (3) 1s22s12p4 (1) 1s22s22p3 (2) 1s22s22p4 (4) 1s22s12p5 Quarterly 1 Review Trupia 37. In the early 1900s, evidence was discovered that atoms were not “hard spheres.” It was shown that atoms themselves had an internal structure. One experiment involved gold metal foil. a Complete the simple model for an atom of gold-197 by placing the correct numbers in the two blanks. b In the gold-foil experiment, alpha particles were directed toward the foil. Most of the alpha particles passed directly through the foil with no effect. This result did not agree with the “hard spheres model” for the atom. What conclusion about the internal structure of the atom did this evidence show? c In the same experiment, some of the alpha particles returned toward the source. What does this evidence indicate about the charge of the atom’s nucleus? Quarterly 1 Review Trupia 38. Base your answer to the following question on the following information. In a laboratory, a glass tube is filled with hydrogen gas at a very low pressure. When a scientist applies a high voltage between metal electrodes in the tube, light is emitted. The scientist analyzes the light with a spectroscope and observes four distinct spectral lines. The table below gives the color, frequency, and energy for each of the four spectral lines. The unit for frequency is hertz, Hz. A spectral line in the infrared region of the spectrum of hydrogen has a frequency of 2.3 × 1014 hertz. Using your graph, estimate the energy associated with this spectral line. Quarterly 1 Review Trupia 39. Base your answer to the following question on the data table below, which shows three isotopes of neon. Based on natural abundances, the average atomic mass of neon is closest to which whole number? ____40. Which statement identifies the element arsenic? (1) Arsenic has an atomic number of 33. (2) Arsenic has a melting point of 84 K. (3) An atom of arsenic in the ground state has eight valence electrons. (4) An atom of arsenic in the ground state has a radius of 146 pm. ____45. Which element is a member of the halogen family? (1) K (3) I (2) B (4) S ____46. Which substance can not be decomposed by a chemical change? (1) Ne (3) HF (4) H2O (2) N2O ____41. Which of the following elements in Period 3 ____47. Which element has no known stable isotope? has the greatest metallic character? (1) Hg (3) Se (1) Ar (3) Mg (2) Po (4) Zn (2) Si (4) S ____42. Which element is an alkali metal? (1) hydrogen (3) sodium (2) calcium (4) zinc ____48. Which element is a noble gas? (1) krypton (3) antimony (2) chlorine (4) manganese ____43. An atom of an element contains 20 protons, ____49. Which substance is the best conductor of electricity? 20 neutrons, and 20 electrons. This element is in (1) nitrogen (3) sulfur Group (2) neon (4) silver (1) 1 (3) 4 (2) 2 (4) 18 ____50. Which substance can not be decomposed by ordinary chemical means? ____44. Which element in Period 3 exists as (1) methane (3) ethanol diatomic molecules at STP? (2) mercury (4) ammonia (1) argon (3) aluminum (2) chlorine (4) sodium ____51. At standard pressure, which element has a melting point higher than standard temperature? (3) Fe (1) F2 (2) Br2 (4) Hg Quarterly 1 Review Trupia ____52. If the electron configuration of an atom of ____58. Which of the following ions has the smallest radius? element X is 2-6, the electron dot symbol for the (3) K+ (1) F– element is – (2) Cl (4) Ca2+ (1) (3) ____59. In the ground state, each atom of an element has two valence electrons. This element has a lower first ionization energy than calcium. Where is this element located on the Periodic (2) (4) Table? (1) Group 1, Period 4 (3) Group 2, Period 3 (2) Group 2, Period 5 (4) Group 3, Period4 ____53. Which element has a total of 5 valence electrons present in the fifth energy level (shell)? ____60. Which element forms an ion that is larger (1) Sb (3) I than its atom? (2) Bi (4) Br (1) aluminum (3) magnesium (2) chlorine (4) sodium ____54. Lithium and potassium have similar chemical properties because the atoms of both ____61. As the elements in Period 2 of the Periodic elements have the same Table are considered in succession from left to (1) mass number right, there is a decrease in atomic radius with (2) atomic number increasing atomic number. This may best be (3) number of electron shells explained by the fact that the (4) number of valence electrons (1) number of protons increases, and the number ____55. What is the net charge of an ion that consists of 10 electrons, 11 protons, and 12 neutrons? (1) 1+ (3) 1– (2) 2+ (4) 2– of shells of electrons remains the same (2) number of protons increases, and the number of shells of electrons increases (3) number of protons decreases, and the number of shells of electrons remains the same (4) number of protons decreases, and the number of shells of electrons increases ____56. Which chemical substances contain atoms in which electrons from the two outermost principal energy levels may be involved in a chemical reaction? ____62. As the atoms in Period 3 of the Periodic (1) halogens (3) alkaline earths Table are considered from left to right, the (2) alkali metals (4) transition elements atoms generally show (1) an increase in radius and an increase in ____57. Which elements form ions that are usually ionization energy colored in solid compounds and in solution? (2) an increase in radius and a decrease (1) alkali metals ionization energy (2) alkaline earth metals (3) a decrease in radius and an increase in (3) transition elements ionization energy (4) halogen elements (4) a decrease in radius and a decrease in ionization energy Quarterly 1 Review Trupia ____63. In Period 2 of the Periodic Table, which Group contains the element with the highest first ionization energy? (1) alkali metals (2) alkaline earth metals (3) halogens (4) noble gases 64. Base your answer to the following question on the information below The table below lists physical and chemical properties of six elements at standard pressure that correspond to known elements on the Periodic Table. The elements are identified by the code letters, D, E, G, J, L, and Q. Identify, by code letter, the element that is a noble gas in the “Properties of Six Elements at Standard Pressure” table. 65. As a neutral sulfur atom gains two electrons, what happens to the radius of the atom? Quarterly 1 Review Trupia 66. Base your answer to the following question on the information below. A safe level of fluoride ions is added to many public drinking water supplies. Fluoride ions have been found to help prevent tooth decay. Another common source of fluoride ions is toothpaste. One of the fluoride compounds used in toothpaste is tin (II) fluoride. A town located downstream from a chemical plant was concerned about fluoride ions from the plant leaking into its drinking water. According to the Environmental Protection Agency, the fluoride ion concentration in drinking water cannot exceed 4 ppm. The town hired a chemist to analyze its water. The chemist determined that a 175-gram sample of the town’s water contains 0.000 250 grams of fluoride ions. How many parts per million of fluoride ions are present in the analyzed sample? Is the town’s drinking water safe to drink? Support your decision using information in the passage and your calculated fluoride level. 67. Base your answer to the following question on the data table provided. On the same grid, plot the data from the data table. Circle and connect the points. 68. Describe one chemical property of Group 1 metals that results from the atoms of each metal having only one valence electron. 69. Base your answer to the following question on the information below. Potassium ions are essential to human health. The movement of dissolved potassium ions, K + (aq), in and out of a nerve cell allows that cell to transmit an electrical impulse. What is the total number of electrons in a potassium ion? Quarterly 1 Review Trupia ____70. The percent by mass of nitrogen in NH 4NO3 (formula mass = 80) is approximately (1) 18% (3) 32% (2) 23% (4) 35% ____71. A sample of a substance containing only magnesium and chlorine was tested in the laboratory and was found to be composed of 74.5% chlorine by mass. If the total mass of the sample was 190.2 grams, what was the mass of the magnesium? (1) 24.3 g (3) 70.9 g (2) 48.5 g (4) 142 g ____72. Base your answer to the following question on the table below shows the data collected during the heating of a 5.0 gram sample of a hydrated salt. ____74. The percent by mass of water in BaCl2 • 2H 2O (formula mass = 243) is equal to (1) (3) (2) (4) ____75. What is the percent by mass of oxygen in magnesium oxide, MgO? (1) 20% (3) 50% (2) 40% (4) 60% ____76. A 60. gram sample of LiCl • H2O is heated in an open crucible until all of the water has been driven off. What is the total mass of LiCl remaining in the crucible? (1) 18 g (3) 42 g (2) 24 g (4) 60 g ____77. What is the total mass of 2.0 moles of H 2(g)? (1) 1.0 g (3) 3.0 g (2) 2.0 g (4) 4.0 g After 60. minutes, how many grams of water appear to remain in the salt? (1) 0.00 (3) 1.9 (2) 2.0 (4) 0.90 ____73. What is the percent by mass of hydrogen in CH3COOH (formula mass = 60.)? (1) 1.7% (3) 6.7% (2) 5.0% (4) 7.1% ____78. What is the mass in grams of 2.0 moles of NO2? (1) 92 (3) 46 (2) 60. (4) 30. ____79. The gram molecular mass of CO2 is the same as the gram molecular mass of (1) CO (3) C2H6 (2) SO2 (4) C3H8 ____80. What is the total mass of oxygen in 1.00 mole of Al2(CrO4)3? (1) 192 g (3) 64.0 g (2) 112 g (4) 48.0 g ____81. Which quantity is equivalent to 39 grams of LiF? (1) 1.0 mole (3) 0.50 mole (2) 2.0 moles (4) 1.5 moles Quarterly 1 Review Trupia ____82. The number of moles of molecules in a 12.0gram sample of Cl2 is (1) (2) (3) (4) ____83. What is the mass in grams of 1.00 mole of O 2 gas? (1) 11.2 (3) 22.4 (2) 16.0 (4) 32.0 84. Fluorine is a Group 17 element. Fluorine is the most electronegative and reactive of all elements. It is a pale yellow, corrosive gas, which reacts with practically all organic and inorganic substances. a Draw the Lewis electron-dot structure for an atom of fluorine. b What is the definition (or your interpretation} of the term "electronegativity". c Explain why the electronegativity of elements in Group 17 decreases as you go down within that group. 85. A knowledge of the ionization energies of elements can be very useful in predicting the activity and type of reaction an element will have. a What does the ionization energy quantitatively measure about an atom? b Why do ionization energies decrease from the top to the bottom of a group on the periodic table of elements? c Why do ionization energies increase from left to right across any period? 86. Chorine is a member of the halogen (saltforming) group of elements. It is a greenishyellow gas, combining directly with nearly all elements. In nature it is found in the combined state only, chiefly with sodium as common salt (NaCl), carnallite, and sylvite. a Draw the electron-dot diagram of an atom of chlorine. b From the passage above give one physical property and one chemical property of chlorine? Quarterly 1 Review Trupia 87. One electron is removed from both an Na atom and a K atom, producing two ions. Using principles of atomic structure, explain why the Na ion is much smaller than the K ion. Discuss both ions in your answer. 88. The following procedures are carried out during a laboratory activity to determine the mass in grams of CuSO 4 in a hydrated sample of CuSO4 • 5H2O. Step 1 Determine the mass in grams of the crucible and CuSO4•5 H2O. Step 2 Determine the mass in grams of the crucible and CuSO4 Step 3 Determine the mass in grams of CuSO4 • 5 H2O. Step 4 Determine the mass in grams of the empty crucible. Step 5 Determine the mass in grams of CuSO4 Arrange the steps above in the order that the student should use to determine the mass of CuSO4 in the sample. _______, _______, _______, _______, ________ 89. A student heats a 243 gram sample of BaCl2 • 2H2O hydrated crystals? a What was the percentage by mass of water in the hydrated crystals?[Show all work] b If all the water was driven out of the crystal, what would be the expected weight of the BaCl2 sample remaining?[Show all work] 90. The table below shows the data collected during the heating of a 10.0-gram sample of a hydrated salt. a What is the percent by mass of water in the original sample? b Why is it important in this experiment to heat the salt until the mass of salt remains constant? Quarterly 1 Review Trupia 91. In a laboratory experiment, a student determined the mass of the product, CaCl2(s), to be 45.5 grams. a Calculate the gram formula mass of CaCl2(s). Round atomic masses from the Periodic Table to the nearest tenth. [ Show all work. Indicate the correct answer in proper significant figures and include an appropriate unit.] b Calculate the number of moles of CaCl2(s) produced. [Show all work. Indicate the correct answer in proper significant figures.] 92. In a laboratory experiment, a student determined the mass of the product, KClO3(s), to be 45.7 grams. a. Calculate the gram formula mass of KClO3(s). Round atomic masses from the Periodic Table to the nearest tenth. [Show all work. Indicate the correct answer in proper significant figures and include an appropriate unit.] b. Calculate the number of moles of KClO3(s) produced. [Show all work. Indicate the correct answer in proper significant figures.] 93. Base your answers to the following questions on the information below. Sodium is an essential ingredient in the human diet. The Federal Food and Drug Administration recommends that the average adult daily requirement for sodum is 2.4 grams. Sodium is ingested through consuming plant and animal tissues, but another good source is table salt, sodium chloride. a) Write the chemical formula of sodium chloride. b) What is the gram-formula mass of a mole of sodium chloride? c) How many moles of table salt, sodium chloride would need to be comsumed in order to ingest the 2.4 grams? [Show all work] Quarterly 1 Review Answer Key [New Exam] 1. 2 26. 1 41. 3 2. 1 27. 3 42. 3 3. 4 28. 4 43. 2 4. 2 29. 2 44. 2 5. 2 30. 1 45. 3 6. 1 31. 3 46. 1 7. 1 32. 3 47. 2 8. 1 33. 2 48. 1 9. 3 34. 4 49. 4 – increases; – The ion is larger then the atom. 66. The water has a fluoride level of 1.43 ppm, which is below the maximum contaminant level for fluoride, so it is safe to drink; F– below 4 ppm, safe, below max level; Safe: 1.43 ppm < 4 ppm 67. 10. 1 35. 3 50. 2 11. 2 36. 1 51. 3 12. 4 52. 4 13. 1 53. 1 14. 3 54. 4 15. 4 55. 1 16. 1 56. 4 17. 3 57. 3 18. 2 58. 1 68. Examples: -form 1+ ions -react vigorously with water -easily lose one electron -form ionic bonds with nonmetals form halides with the general formula MX 19. 4 59. 2 69. 18 20. 3 60. 2 70. 4 21. 4 37. a) 118 neutrons, 79 electrons. b) Acceptable responses include, but are not limited to, these examples: – The atom’s internal structure is mostly empty space or – mostly empty space c) Acceptable responses include, but are not limited to, these examples: – The nucleus of the gold atoms have a positive charge. or – Both the nucleus of the gold atoms and the alpha particles have the same charge. or – positive charge 61. 1 71. 2 22. 1 72. 1 23. 2 73. 3 24. 1 74. 2 25. 2 75. 2 3 38. 1.5 ] 10–19 J ± 0.1 ] 10–19 62. J 63. 4 39. 20 64. D or He 40. 1 65. Examples: – gets bigger; Quarterly 1 Review Answer Key [New Exam] 76. 3 77. 4 78. 1 79. 4 80. 1 81. 4 b. Examples: Physical – Chlorine is greenishyellow. – Chlorine is a gas. Chemical – a Halogen; – very reactive; combines with sodium 87. Examples: –K1+ has three energy levels, while Na1+ has 83. 4 only two energy levels. –Na+ has its valence 84. electrons drawn closer to the nucleus than K+ b) Electronegativity because the effect of the is the relative measure of nucleus is greater for Na+. how strongly the nucleus of an atom will attract 88. 4,1,3,2,5 electrons from another atom. c) As you go 89. a) 36/ (137 + 71 + 36) × down the period the 100 = 15% b) 207 grams nuclear charge gets shielded by layers of more90. a) 20.% b) To insure electrons and as the atom that all of the water has gets larger, the distance been driven out of the salt. to the nuclear charge gets greater. 91. a) 40.1 + 2(35.5) = 101 82. 2 grams b) 45.5g x 1.00 85. a) The ionization energy mole/101g = .450 mole is the amount of energy needed to remove the 92. a) 39.1 + 35.5 + 3(16.0) most loosely bound = 122.6 g b) 45.7g x electron from an atom. 1.00 mole/122.6g = .373 b) The electrons are mole farther away in the lower periods so there is less 93. a) NaCl b) 57.5 grams pull from the nucleus. c) 0.042 Also, there is shielding from the electrons that are closer to the nucleus. c) Electrons are held tighter to an atom because of the increase in nuclear charge. 86.