Ideal and not-so-Ideal Gases Thermometry Celsius Scale

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Ideal and not-so-Ideal Gases

Boyle (UK)-1662 & Mariotte (FR)-1676

Ideal Gas Law: P V = RT

Amontons-1702

Absolute Zero—

Temperature at which

Pressure goes to zero at fixed Volume

Amontons

Also proposed Theory of

Friction

Thermometry

11/8/2011

• Daniel Gabriel Fahrenheit

(1686-1736)

• German physicist

• invented alcohol thermometer (1709)

• Hg thermometer in (1714)

• Introduced temperature scale Fahrenheit Scale-in

1724 .

Celsius Scale-1742

• On Fahrenheit scale, two very significant things for humans happened at two very insignificant points. The temperature at which water freezes is at 32 degrees and the temperature at which water boils is at 212.

• Why did Mr. F. do this?

• Why not, Celsius thought, simplify things a bit and call the freezing point zero and the boiling point

100.

Anders Celsius

Johann Lambert-1779

• In 1779 Joseph Lambert proposed a definition for absolute zero on the temperature scale that was based on the straightline relationship between the temperature and pressure of a gas.

What is the difference between this and what Amontons conjectured in 1702?

William Thomson Kelvin-1848

KELVIN, Lord (William Thomson)

(1824 - 1907)

• Proposed an absolute scale of temperature in

1848.

• The absolute scale that he proposed was based on his studies of the theory of heat, in particular the theory proposed by Sadi

Carnot

It was Thomson's studies in thermodynamics though which led him to propose his absolute scale of temperature in 1848.

Kelvin is an absolute scale in that temperatures below 0K (absolute zero) do not exist anywhere in the universe. Equivalent to -273.15° Celsius or -

459.67° Fahrenheit, 0K is the temperature at which molecular energy is a minimum i.e. all molecular motion would cease.

He developed it by 'extrapolating' backwards on volume-temperature and pressure-temperature graphs. He discovered that the temperature axis was cut at -273°C. Kelvin was also aided in the developing of his scale by a 'carnot engine'. Kelvin defined his thermodynamic scale so that a Kelvin was exactly the same as one degree Celsius.

1

Rankine, William (1820-1872)

• Invented an absolute temperature based on the interval of one degree

Fahrenheit termed the

Rankine temperature scale.

• 1850 – “ Mechanical Action of

Heat.” –formulated heat theory.

1852

11/8/2011

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