Guide to Calculating Chemical Quantities The Mole: A mole of any compound contains 6.02X 1023 particles; Avogardo’s Number 1 mol = 6.02 X 1023 The subscripts in a formula indicate the number of moles of each element in one mole of the compound Guide to Calculating the Atoms or Molecules of a Substance: (1 step problem) STEP 1: Determine the given number of moles STEP2: Write a plan to convert moles to atoms or molecules STEP 3: Use Avogardo’s number to write the conversion factors STEP 4: Set up the problem to convert given moles to atoms or molecules Example: Use Avogardo’s number to calculate the following: The number of Ca atoms in 3.00 mol of Ca Given = 3.00 mol Ca Unknown: atoms of Ca Conversion Factor: 6.02 X 1023 1 mol 3.00 mol Ca 6.02 X 1023 atoms = 1.81 X 1024 atoms 1 mole Molar Mass: The molar mass of an element is numerically equal to its atomic mass in grams The molar mass (g/mol) of a compound is determined by multiplying the molar mass of each element by its subscript in the formula and adding the results together Guide to Calculating Molar Mass STEP 1: Obtain the molar mass of each element (the atomic mass from the periodic table) STEP 2: Multiply each molar mass by the number of moles (the subscript) in the formula STEP 3: Calculate the molar mass by adding the masses of the elements together Example: What is the molar mass of silver nitrate, AgNO3? Ag= 107.9 N= 14.007 O= 16 1 mol Ag X 107.9 g/mol Ag = 107.9 g Ag 1 mol N X 14.007g/mol N = 14.007g N 3 mol O X 16g/mol = 48 g O Molar Mass of AgNO3 = (107.9 g + 14.007 g + 48 g) = 169.907 g Calculations Using Molar Mass The molar mass is useful as a conversion factor to change a given quantity in moles to grams or vice versa The 2 conversion factors for the molar mass of NaOH (molar mass = 40.01 g/mol) have the following forms: 40.01 g NaOH OR 1 mol NaOH 1 mol NaOH 40.01 g/mol NaOH Guide to Calculating the Moles of a substance from grams given or vice versa: (1 step problem) STEP 1: Identify the given; either moles or grams STEP 2: Step up your T-chart STEP 3: Determine the molar mass and write the correct conversion factor STEP 4: Set up the problem to convert given moles to grams; or vice versa Example: What is the mass in grams of 0.254 mol of Na2CO3? Given: 0.254 mol Na2CO3 0.254 mol Na2CO3 = Molar mass of Na2CO3 = [2(23.0 g Na) + 1(12.011 g C) + 3(16.0 g O)] = 106.011 g Na2CO3 0.254 mol Na2CO3 106.011 g Na2CO3 = 26.9 g Na2CO3 1 mol Na2CO3 Guide to Converting Grams to Particles: (2 step problem) STEP 1: Identify the given and the unknown STEP 2: Find the molar mass of the given compound STEP 3: Set up the problem to convert grams to moles STEP 4: Add the second conversion factor to the T-chart to convert from moles to particles (atoms or molecules) Example: How many molecules of sodium carbonate are in 26.92 grams of Na2CO3? Given: 26.92 g Na2CO3 Unknown: molecules of Na2CO3 Molar Mass of Na2CO3 = 106.011 g Na2CO3 26.92 g Na2CO3 1 mol Na2CO3 106.011 g Na2CO3 26.92 g Na2CO3 1 mol Na2CO3 6.02 X 1023 molec. Na2CO3 = 1.529 X 1023 molec. Na2CO3 106.011 g Na2CO3 1 mol Na2CO3 Percent Composition: Percent Composition is the percent by mass of each element in a compound Guide to Calculating Percent Composition STEP 1: Determine the total mass of EACH element in molar mass of a formula STEP 2: Determine the total molar mass of the ENTIRE compound STEP 3: Divide the total mass of EACH element by the molar mass of the entire compound and multiply by 100 Example: What is the percent of Na in NaOH? Molar Mass: Na= 1 x 23 g= 23 g Na O= 1 x 16 g= 16 g O H= 1 x 1.008 g = 1.008 g H Molar Mass of NaOH= 40.008 g NaOH 23 g Na x 100 % = 57.49 % Na in NaOH 40.008 g NaOH