Electron, Proton, and Neutron Table – + Electron Proton Neutron Occurence Charge Mass (g) Relative Mass found outside of nucleus -1 9.109 × 10-28 1 found in all nuclei +1 1.673 × 10-24 1,836 found in almost all nuclei (exception: most H nuclei) 0 1.675 × 10-24 1,839 Radioactive Decay Alpha decay Beta decay Nucleus ejects a helium-4 nucleus Nucleus converts a neutron to a proton and electron, ejecting the electron. - Protons Neutrons Atomic number Mass number Decrease by 2 Decrease by 2 Decrease by 2 Decrease by 4 Protons Neutrons Atomic number Mass number Increase by 1 Decrease by 1 Increase by 1 Stays the same Gamma decay Nucleus emits gamma radiation and lowers its energy. Gamma ray Protons Neutrons Atomic number Mass number Stays the same Stays the same Stays the same Stays the same Size and Structure of an Atom – Atom Diameter = 10-10 m + + – + Proton Neutron – Electron + + Nucleus Diameter = 10-15 m Units of Elementary Charge } Electric charge only appears in multiples of the elementary charge, e. + – + + – – + +e – -e + +2e – -2e + +3e – -3e + + ++2.5e – – -.5e } Allowed in normal matter Impossible in normal matter Bohr’s Model of the Atom Ground state Excited state Ground state – – – Energy absorbed Energy (light) released Electron Energy Levels Number of possible electrons Energy levels (first four) 4th level 18 3rd level 8 2nd level 8 1st level 2 Atom Orbitals The p-orbitals The s-orbitals Up Back Left Right Up Back Left Front Right Down Front Down Violet Blue - violet Blue - green Hydrogen Red spectrum high 7 6 5 4 3 Light 2 low Light energy 1 Energy levels Energy Diagram of Spectral Lines and Energy Energy Levels in the Periodic Table Groups in the Periodic Table Periodic Table of Elements 18 He 1 H 1 2 Li 2 Be 13 B 14 C 15 N 16 O 17 F lithium beryllium boron carbon nitrogen oxygen fluorine neon Na Mg Al S Cl Ar chlorine argon Br Kr bromine krypton I Xe iodine xenon Po At Rn hydrogen 3 11 sodium K 19 potassium 5 4 12 3 Ca Sc 20 21 scandium calcium Y Rb Sr 37 rubidium 38 strontium 39 yttrium Cs Ba 55 barium Fr Ra francium radium 5 V 22 23 6 Cr 7 8 9 Mn Fe Co 25 24 vanadium chromium manganese titanium Zr Nb Mo Tc 40 41 zirconium niobium Hf Ta hafnium tantalum 72 56 cesium 87 4 Ti magnesium 73 44 W Re Os molybdenum technetium ruthenium 74 tungsten 75 rhenium 76 osmium La Ce lanthanum cerium Ac Th actinium thorium 57 89 58 90 Pr 59 seaborgium bohrium 61 Pa 91 U 92 protactinium uranium neptunium 94 32 33 34 copper 29 30 zinc 48 gallium In 49 palladium Ir Pt Au Hg Tl iridium platinum 78 silver 79 gold cadmium 80 mercury Mt Uun Uuu Uub 110 111 63 64 europium gadolinium 65 terbium Np Pu Am Cm Bk 93 31 nickel 28 112 hassium meitnerium ununnilium unununium ununbium praseodymium neodymium promethium samarium 16 rhodium 108 109 62 15 11 12 aluminum silicon phosphorus silicon Cu Zn Ga Ge As Se Nd Pm Sm Eu Gd Tb 60 14 47 77 95 plutonium americium P 13 46 45 Si 8 10 Ni Ru Rh Pd Ag Cd 43 Rf Db Sg Bh Hs rutherfordium dubnium cobalt iron 42 104 105 106 107 88 27 26 7 6 96 curium 97 indium 81 thallium 113 germanium arsenic Sn Sb 51 50 tin antimony Pb Bi 83 82 lead Uuq 114 ununquadium Dy Ho Er dysprosium holmium erbium Te 52 tellurium 84 85 36 54 86 radon 115 116 117 118 Tm Yb Lu thulium lutetium Es Fm Md No berkelium californium einsteinium fermium 53 18 astatine Cf 100 35 10 polonium 67 99 17 Ne bismuth 66 98 68 selenium 9 helium 69 101 70 ytterbium 102 71 Lr 103 mendelvium nobelium lawrencium Reading the Periodic Table Periodic Table of the Element s 1 H 1 Main Group Elements Li 2 Be lithium beryllium hydrogen 3 Transition Elements 4 11 K 19 potassium 12 3 Ca Sc 20 21 scandium calcium Y Rb Sr 37 rubidium 38 strontium 39 yttrium Cs Ba 55 barium Fr Ra francium radium 5 V 22 23 Metals 6 Cr 40 41 niobium Hf Ta hafnium tantalum 73 La Ce lanthanum cerium Ac Th actinium thorium 57 89 58 90 Pr 59 44 W Re Os 75 rhenium 76 osmium seaborgium bohrium 91 28 29 92 protactinium uranium fluorine neon S Cl Ar chlorine argon Br Kr selenium bromine krypton Te I Xe iodine xenon Po At Rn Si P 13 14 15 16 61 31 32 33 34 neptunium zinc 48 94 In 49 47 Ir Pt Au Hg Tl iridium platinum 77 78 silver 79 gold cadmium 80 mercury Mt Uun Uuu Uub 110 111 112 hassium meitnerium ununnilium unununium ununbium 62 gallium 46 63 64 europium gadolinium 65 terbium Np Pu Am Cm Bk 93 30 palladium 45 Nd Pm Sm Eu Gd Tb U oxygen rhodium 108 109 praseodymium neodymium promethium samarium Pa nitrogen Al Ru Rh Pd Ag Cd 43 60 carbon 8 copper Rf Db Sg Bh Hs rutherfordium dubnium boron 7 6 nickel 104 105 106 107 88 17 F cobalt iron 42 tungsten 16 O 5 27 26 molybdenum technetium ruthenium 74 15 N 11 12 aluminum silicon phosphorus silicon Cu Zn Ga Ge As Se Zr Nb Mo Tc zirconium 14 C 10 Ni 25 24 95 plutonium americium 96 curium 97 indium 81 thallium 113 germanium arsenic Sn Sb 51 50 tin antimony Pb Bi 83 82 lead Uuq 114 ununquadium Dy Ho Er dysprosium holmium erbium 84 35 53 85 10 18 36 54 86 astatine radon 115 116 117 118 Tm Yb Lu thulium lutetium Es Fm Md No berkelium californium einsteinium fermium 17 Ne polonium Cf 100 9 helium bismuth 67 99 68 52 tellurium 66 98 2 13 B 7 8 9 Mn Fe Co vanadium chromium manganese titanium 72 56 cesium 87 4 Ti magnesium Metalloids COLUMNS = GROUPS ROWS = PERIODS Na Mg sodium Non metals 18 He 69 101 70 ytterbium 102 71 Lr 103 mendelvium nobelium lawrencium Chemical Formulas and Structure Diagrams Structural diagram H O H C H O O Na H C C C C C C O H H H C C H H H H C H H C O H H H Sodium bicarbonate (baking soda) NaHCO3 Benzene Ethane C6H6 C2H6 Chemical formula Acetic acid (in vinegar) HC2H3O2 H Chlorine and Sodium Bonds Periodic Table and Reactivity Lewis Dot Diagrams Neon 8 valence electrons Ne Boron 3 valence electrons B Flourine F Beryllium Be Oxygen O Lithium Li 7 valence electrons 6 valence electrons Nitrogen N Carbon C 5 valence electrons 4 valence electrons 2 valence electrons 1 valence electrons Hydrogen 1 valence electrons H Methane H C H molecule (CH4) H H Example of Oxidation Numbers Adding to Zero Cl Cl C Cl Cl CCl4 Carbon tetrachloride C Cl Cl Cl Cl 4+ 1- 1- 1- 1- =0 The total of the oxidation numbers for each atom in the molecule must be zero. Periodic Table and Electron Acceptors and Donors Predicting a Chemical Formula Iron and oxygen combine to form a compound. Iron (Fe) has an oxidation number of 3+. Oxygen (O) has an oxidation number of 2-. Predict the chemical formula of this compound. 1. Looking for: Chemical formula 2. Given: oxidation numbers Fe 3+ and O 2- 3. Relationships: The oxidation numbers for all the atoms in a compound must add up to zero. 4. Solution: Three oxygen atoms contribute the total oxidation number of 6-. It takes only two iron atoms to get a total oxidation number of 6+. Therefore, the chemical formula is Fe2O3. Your turn... a. Predict the chemical formula of the compound containing beryllium (2+) and fluorine (1-). Answer: BeF2 Valence Electrons and Bonding Chlorine 17 electrons Inner electrons 7 1 6 2 5 Bond Valence electrons 3 4 Chlorine has 7 valence electrons Sodium 1 valence electron Chlorine 7 valence electrons