Quiz: Geo 406 Lecture 25 –Metabasites & Metapelites Announcements Goals for today Understand facies, zones Facies & Mineralogy Blueschist Above ~0.6 GPa (6 kbar) Below ~500°C Mineralogy: glaucophane lawsonite ±jadeite ±epidote ±aragonite Multiple reactions: Prh Lws Act Glc Ab Jd + Qz {see Keynote) At what pressure is Jadeite stable? At what pressure is Jadeite + Quartz stable? Tectonics of blueschist metamorphism: Accretionary prisms accumulate by scraping at the toe underplating at the base (blueschists must form this way) Eclogite High P, High T Above 1.2 GPa, 500°C Mineralogy: Garnet (Pyrope-rich = Mg) Omphacite (Na-Cpx) ± quartz ± glaucophane Isograds vs. GIS Reaction on ground vs. line of constant grade Metapelites Protolith [ASK] Shale Location: where does this form? distal part of continental shelf/slope Mineralogy clays (e.g., kaolinite) fine white micas (e.g., sericite) chlorite fine-grained quartz other stuff (fsp, oxides, carbonates, etc.) Chemistry high Al2O3, K2O low CaO generally KFMASH: K2O, FeO, MgO, Al2O3, SiO2, H2O Diagrams: AKF AFM Barrovian Facies Series: Chlorite zone What facies is this? Biotite zone first Bt: Chl + Kf = Bt + Ms for what rock compositions will this occur? More typical Bt-in reaction is continuous: Ms1+Chl1 = Ms2+Chl2+Bio Mineralogy: chl+Bt+Ms+Qtz±Ctd What if you had an unusually Fe-rich protolith? Would have grt at this point Garnet zone What is the reaction? Cld + Bt = Grt + Chl Does this make grt in the full range of typical pelites? No (just like Bt), only for Fe-rich Staurolite zone What is the reaction? Cld + Ky = St + Chl For what types of compositions does this produce Sta? Al-rich? What are all the assemblages you might observe in the sta zone, given the full range of typical pelite chemistry? Chl+Bt Chl + Bt + Grt Chl Chl + Cld Chl + Cld + Sta Chl + Sta + Ky (!) Chl + Ky Next Sta Rxn: loss of Cld [What is that reaction?] Cld = Sta + Grt + Chl Puts Sta into Fe-rich high-Al pelites Third Sta Rxn [What is it?] Grt + Chl = Sta + Bt Puts Sta into low-Al pelites But what happened between second and third? Continuous reaction added Sta to Fe-poor, high-Al pelites See T-XMf diagram Note no kyanite anymore Kyanite zone What is the reaction? St + Chl = Ky + Bt Puts Ky into Mg-rich pelites Note that Chl is still stable in some low-Al pelites, but disappears mid-Ky zone weird that Cld is lost before Chl is! Sillimanite zone Reaction? St = Sil + Grt + Bt Second Sill Reaction? Ms + Qz = Sil + Kf