Intro. Petrology EPSC 212, Lab. 2, Francis 2014 Lab 2: Crystal Growth and Igneous Textures The identification and classification of an igneous rock is typically a two fold process that requires the determination of the type of cooling unit that the rock sample was taken from in the field and an estimation of its mineralogical and chemical composition. The identification of the cooling unit is best done on the basis of structures and textures in the field and we will look at this aspect in more detail in the next lab. The first order question you must decide for any igneous rock is whether it is a volcanic or plutonic rock. After the field context of the rock sample, this is best answered on the basis of textures in hand specimen and thin section. Volcanic (extrusive) rocks cool quickly and crystallize rapidly on the surface and are thus typically relatively fine-grained and have compositions that approximate that of the liquids from which they formed. Volcanic rocks are commonly phenocrystic, however, containing some larger euhedral crystals that formed at slower cooling rates before eruption. They also commonly contain vesicles or amygdules (filled vesicles) formed by exsolving volatiles, and may exhibit reddening and/or brecciation along flow boundaries if they are subaerial. The presence of pillow structures with glassy margins is indicative of sub-aqueous eruption. Plutonic (intrusive) rocks crystallize more slowly below the Earth’s surface and are typically coarser-grained and more equi-granular than volcanic rocks. Their grain-size is indicative of both the rate of cooling, and therefore the depth of crystallization, and the viscosity of the magma, which is a function of composition and water content. Plutonic rocks are commonly in part cumulate, that is their compositions reflect the mechanical accumulation of crystals rather than a frozen liquid. Some plutonic rocks are almost completely cumulate in nature, while others reflect a mixture of accumulated crystals and frozen interstitial liquid. 1 Intro. Petrology EPSC 212, Lab. 2, Francis 2014 2 Intro. Petrology EPSC 212, Lab. 2, Francis 2014 3 Intro. Petrology EPSC 212, Lab. 2, Francis 2014 Station A – Mafic Volcanics – Pillow lavas: These rocks are specimens of the margins of pillow lavas that erupted into water. They cooled very rapidly and 'quenched in' a virtual snapshot of the magmas as they erupted. They are ideal samples with which to determine the phenocryst assemblage of the magma at the time of eruption. Specimens AS-7a & WG-3 are very old (~1.9 Ga), and their primary mineralogy has been replaced by greenschist facies metamorphic minerals, which is responsible for their green colour. The primary pillow rim texture, however are still well preserved. 4 Intro. Petrology EPSC 212, Lab. 2, Francis 2014 Stations B1 and B2 – Mafic Volcanics - Lava Flows The 2 sets of 4 rocks at stations B1 and B2 are samples taken across single lava flows: B1 - the darker set was taken across an alkaline olivine basalt flow from the Canadian cordillera that is 4 metres in thickness. Samples A, B, C, D B2 - the lighter set was taken across a tholeiitic olivine basalt flow from Baffin Island that is 5 metres in thickness. Samples Pd-48, PD-41, PD-46, PD-45, and AK-42. The samples from each flow have approximately the same chemical composition, and mineralogy, but differ texturally because of their different cooling histories. For each sample set, determine the location of each of the samples in their respective flows by examining their textures in hand specimen. Describe the variation in the textures of the minerals and vesicles across the same flow and briefly rationalize this variation in terms of the cooling history of the lava flow. Station C: Mafic to Intermediate Volcanics - Lava Flows The samples at this station are random pieces of lava flows with mafic to intermediate compositions. Examine each specimen to determine what part of the lava flow it represents, using the criteria developed in Section B. Identify any phenocrysts in each specimen, and qualitatively estimate where the specimen lies in the mafic to intermediate compositional spectrum. 5 Intro. Petrology EPSC 212, Lab. 2, Francis 2014 Station D1: Felsic Volcanics – Lava Flows Felsic volcanic rocks commonly have the lightest coloured matrices, if they are holocrystalline. However, silica-rich magmas will often quench to a glass that is dark in colour and similar in appearance to basaltic glass, unless examined through a thin chip, in which case basaltic glass has a darker brown colour. It is unusual, however, for an entire sample of basalt to be glassy because it is harder to quench silica-poor mafic magmas. In addition, glassy felsic lavas frequently exhibit spherulites, small spherical bodies composed of radiating felsic crystals that are though to have grown by the devitrification of glass. spherulites Extremely fine-grained varieties of felsic lavas will also be relatively dark in colour and easily confused with more mafic lavas in the field. The presence of concoidal fracture in a extremely finegrained dark matrix that cannot be scratched with a knife is typically diagnostic of a felsic composition. No matter how dark the fresh surface, the weathering surface of felsic rocks will typically be light coloured compared to that of mafic to intermediate rocks. obsidian 6 Intro. Petrology EPSC 212, Lab. 2, Francis 2014 Felsic volcanic flows are commonly flow banded. Flow banding is defined by alternating layers of glass and finely crystalline material, sometimes coalescing spherulites, which define the slip planes along which the viscous felsic magma flowed. The crystalline layers are thought to be those along which volatile bubbles have concentrated during lamellar flow. These volatiles aided the crystallisation of the magma in these layers, which tend to be lighter coloured than the darker layers that are depleted in such bubbles and quenched to glass. This banding is frequently preserved even when the felsic volcanic rock has been completely recrystallized. This type of banding is not observed in mafic to intermediate volcanic rocks. Furthermore, the margins of felsic flows are always fragmented, and their brecciated margins constitute a larger proportion (thicker) of the flow than in the case of mafic aa flows. Ropy or pahoehoe tops are not observed in felsic lavas. Flow-banded rhyolite Although glassy and crypto-crystalline felsic volcanic rocks are relatively dark in colour, most old felsic lavas have recrystallized, and thus are light in colour reflecting the fact that their compositions are rich in felsic minerals (E8733, E8969, 2.7 Ga). 7 Intro. Petrology EPSC 212, Lab. 2, Francis 2014 Station D2: Felsic Fragmental Volcanics – Pyroclastic rocks The majority of felsic volcanic rocks are not lava flows, but pyroclastic rocks produced by the accumulation of clasts or fragments produced in an explosive volcanic eruption. Felsic magmas commonly erupt explosively because their Si-rich compositions make them so viscous that exsolving volatiles can not escape. Because of the combination of high melt viscosity and high gas contents, the majority of felsic magmas erupt as pyroclastic deposits than rather than effusive lava flows. Mafic magmas can also produce fragmental volcanic rocks during explosive eruptions, but typically erupt as more effusive lava flows. Some petrologists view pyroclastic rocks as sedimentary rather than igneous rocks. This station contains a wide variety of fragmental volcanic rocks. The classification of fragmental rocks requires the consideration of a number of features: grain size, matrix versus clast support, degree of sorting, presence of layering or grading, monomictic versus polymictic character, signs of aerial or hot emplacement. Examine each specimen in terms of these features and classify them according to the first figure in this lab. 8 Intro. Petrology EPSC 212, Lab. 2, Francis 2014 Air-fall tuffs are deposited relatively cold and may or may not be layered. Water-lain tuffs are more typically layered and exhibit better sorting than air fall tuffs. Air fall tuffs are commonly reworked by wind and water, showing structures such as fine-scale cross-bedding. Such rocks are technically sedimentary, rather than volcanic, and they are sometimes referred to as epiclastic as opposed to pyroclastic rocks. If you don’t know which a rock is, it is safer to use the term fragmental volcanic or volcanoclastic rock can be used – a clastic rock made up of fragments of volcanic rock and/or broken crystals. Some of the samples in this section are welded tuffs or ignimbrites. They are tuffs that have between deposited by pyroclastic flows. They are characteristically poorly sorted and lack well defined layering, although they commonly exhibit grading. In some cases, they are hot enough that the fragments are plastic and welded together after emplacement. Signs of hot deposition include flattened pumice or glass fragments known as fiamme, columnar joints, alteration rims around larger fragments, and the presence of a hard glassy matrix. Strongly welded rocks are typically physically hard to break and when they do, fiamme they tend to break across fragments. Many ash flow tuffs are not welded, however, and are recognized on the basis of lack of layering and/or poor sorting. In some cases, the interior of ash flows are welded, while the margins are not, or ash flows are welded near their source, but not welded far from their source. Pyroclastic Surge deposits are distinguished from pyroclastic flow deposits by the presence of well developed planar or wavy layering and low-angle, large-scale dune cross bedding. They are typically thinner than pyroclastic flows deposits. 9 Intro. Petrology EPSC 212, Lab. 2, Francis 2014 Station E: Felsic Intrusive Rocks Intrusive felsic dykes can range from aplites, characterized by a fine-grain sugary texture thought to represent rapid crystallization due to the loss of volatiles, to very coarsegrained pegmatites that crystallize slowly from volatile rich melts. High-level felsic dykes are commonly porphyritic, characterized by euhedral quartz and/or feldpsar phenocrysts in a very fine-grained felsic matrix (QFP). More deepseated felsic intrusive rocks tend to be more coarse-grained and equigranular. Depending on crystallization conditions, quartz and feldspars can develop a variety of intergrowths. Graphic texture is an intergrowth of K-feldspar with cuneiform or patchy quartz, formed by selective nucleation of quartz along the feldspar crystal edges and corners. The K-feldspar in coarse-grained deep-seated felsic plutons commonly exhibit perthitic exsolution lamellae of albite and K-spar due to slow cooling that has enabled the feldspar to re-equilibrate at relatively low temperatures. . Station F: Mafic Plutonic Rocks This station contains examples of mafic plutonic rocks. They range from high-level (near surface) porphyritic dykes, whose grain-size is virtually indistinguishable from mafic volcanic rocks in the interiors of flows (seen at station B and C) to coarser-grained cumulate rocks formed in large deep-seated intrusions. High-level mafic dykes are dark in colour and commonly lack vesicles, but may be difficult to distinguish from mafic lavas. The presence of finer grained chilled margins against their host rock is diagnostic. Deeper-seated cumulate rocks are typically coarser-grained and rarely porphyritic. They may sometimes be recognized in outcrop by the presence of mineral layering, or the alignment of large tabular crystals such as plagioclase. In some cases they are characterized by a restricted mineralogy, for example cumulates of olivine are called dunites, cumulates of plagioclase are termed anorthosites. Another characteristic feature of cumulate rocks is the presence of oikocrysts, large crystals of pyroxene or plagioclase enclosing smaller equant crystals of earlier formed olivine (chadocrysts). These oikocrysts are thought to crystallize from the interstitial liquid trapped between mechanically accumulated crystals. Examine the mafic intrusive rocks at station F, comparing them to the mafic volcanic rocks that you have seen at station B, and C. Identify all the minerals you can and look for features indicative of cumulate rocks, such as layering or oikocrysts. 10