Washington-Lee HS 2013-2014 AP Chemistry Syllabus Ms Stacy Brasfield, Instructor --------------------------------------------------------------------------------------- Room 4005 (703)228-6200 Stacy.Brasfield AT apsva DOT us Course Objectives AP Chemistry is a college level course designed to develop an in-depth understanding of the major areas of chemistry. The course components are based on the curriculum guides provided by the College Board. The course includes the following general content areas: Structure of Matter (Atomic theory and atomic structure. Chemical Bonding) States of Matter (Gases, liquids and solids. Solutions.) Reactions (Reaction Types, Stoichiometry, Equilibrium, Kinetics, Thermodynamics, Nuclear.) Descriptive Chemistry (Relationships in the periodic table, Qualitative Analysis) Laboratory The course emphasizes chemical calculations and the mathematic formulation of principles, including the application of significant figures, precision of measured values, the use of logarithmic and exponential relationships, and critical analysis of the reasonableness of results. Examples of types of calculation problems are Percentage composition Empirical & Molecular formulas from experimental data Molar masses from gas density, freezing point & boiling point measurements Gas Laws, including the ideal gas law, Dalton’s law & Graham’s law Stoichiometric relations using the concept of the mole; titration calculations Mole fractions, molar and molal solution concentrations Faraday’s law of electrolysis Equilibrium constants and their applications, including simultaneous equilibria Standard electrode potentials and their use; Nernst equation Thermodynamic & thermochemical calculations Kinetics calculations The course is a laboratory course. In the laboratory, students will develop and practice laboratory techniques, such as measurement, distillation, filtration, titration, and making solutions. engage in designing experiments, choosing and isolating variables and developing procedures. practice collecting and organizing qualitative and quantitative data, develop skills in data manipulation and analysis including graphing, analysis of uncertainty and reliability, and error analysis develop higher-level communication and collaboration skills by working with other students in the laboratory and through the writing of laboratory reports practice proper laboratory safety and waste handling procedures have a “hands-on” experience to discover chemical principles learn to communicate clearly with laboratory reports. All lab reports are saved in a lab portfolio. Additional Note: The AP Chemistry test consists of two parts, worth 50% each. Part One consists entirely of multiple choice questions and calculations that are performed without a calculator. Part Two consists entirely of free response questions. Calculator use is permitted with a portion of Part Two. To help students score well on this test, test taking strategies, including mental math strategies are emphasized and reinforced throughout this course. Prerequisites Successful completion of Intensified Chemistry or permission of the instructor must precede this course. Requirements This course is a double course – 2 consecutive classes which meet every school day for 90 minutes. Students receive 2 credits upon successful completion of the course. The course includes a laboratory component comparable to college-level chemistry laboratories. The equivalent of one double period per week is spent engaged in laboratory work. Each student will complete a laboratory portfolio of lab reports. Students are required to prepare adequately for laboratory work for the safety of themselves and others. Students who practice unsafe laboratory practices will not be permitted to continue working in the laboratory. Students are required to take the AP Chemistry exam that is administered in May. According to APS policy, students who fail to take the official exam will lose the GPA quality point for the course. Students are required to do an independent project. Seniors who are part of Senior Experience may be exempted from this requirement. Teaching Strategies/Conceptual Approaches 1) Promote a yearning for learning. 2) 3) 4) To tap into a student’s natural curiosity, the instructor poses timely questions. The questions “whet the students’ appetite” for learning by linking new ideas to prior learning. They bring to light misconceptions, and they encourage students to develop critical thinking skills by taking intellectual leaps into uncharted learning territory. Develop reasoning skills. Since students remember things that they find meaningful, great emphasis is placed on learning for meaning. Labs and class work activities use higher-level questioning to help students make sense of chemical concepts through use of particle level explanations. Encourage and support intellectual risk taking. By working together collaboratively in small groups, students can test out their ideas in a supportive, emotionally safe climate Practice, practice, practice with problems from the AP Chemistry Released Tests These practice sessions take place both during class and after class. Students practice answering free response questions on Unit Assignments, and they practice answering multiple choice questions on the online Practice tests. Students explain how to solve problems in class and the teacher explains how the problems are graded on the AP Test. 5) 6) 7) Write to learn and learn to write. Writing lab reports and responses to questions requires that students organize and make sense of their ideas. As they put their thoughts on paper they learn how to complete the thought, and they recognize weaknesses in their thinking. To promote better written work, time is built into the schedule for lab groups to meet again to peer edit their papers before the submission deadline. Students can share ideas, but all lab work must be an original composition. Students can learn from their mistakes. They are given two weeks after each test to make test corrections. To “correct” an answer, students must explain in writing why the correct answer is the correct answer. There must be enough detail that it would make sense to a fellow student. Hands-on learning is the most memorable. Labs convey and cement the chemical principles presented in lectures and demonstrations. They make visual the language of chemistry. Different labs are assigned for different reasons; some are summative, some formative. The purpose and requirements of each laboratory are summarized on the lab assignment handout. Some lab reports are “complete lab reports”; others require fewer sections. Students maintain a lab portfolio of their completed lab reports. AP Chemistry Resources Text: Ebbing & Gammon, General Chemistry, 9th Ed., 2009, Houghton Mifflin Co., NY Online Classroom: Online practice assignments, additional copies of class handouts, weekly class calendars and student grades are posted at http://apsva.blackboard.com Study Guide: Neuss, Geoff. Chemistry for the IB Diploma. Oxford Press, 2007 Labs are taken from several sources. Often they are modified to make them open-ended investigation. Several labs are student-designed. Class Policies Course Supplies: Students need a scientific calculator, a binder for class notes and assignments, pens and pencils and a dedicated lab book. The lab book can be a composition book, a sturdy spiral graph paper notebook or a separate lab binder. Attendance: Good attendance is critically important. If a student must be absent, they are responsible for all work missed. Students can stay informed of assignments either by checking the class calendar or by calling/emailing the teacher at school. Since most work is assigned well in advance, missed work is due immediately upon return from the absence, within reason. Students should be ready to take a missed test or make up a missed lab on the day that they return to school whenever possible. In extreme cases, other arrangements can be negotiated with the instructor. The student must keep in mind that the course is cumulative, and it moves quickly, so it is not in their best interest to let the work pile up. If the absence is unexcused, the missed assignment should be made up, but it may not count for credit. Late work: Students will be given ample time to do assigned work so they can do excellent, thoughtful work. Assignments are scheduled well in advance of the due date. That being said, the work is more meaningful for students if it is completed in a timely fashion in context with the unit, so the due dates are assigned for the maximum learning benefit of the student. o Lab reports that are turned in late will be graded with a late grade penalty until the final deadline, after which the lab report will receive no points. Unit Assignments are take-home, open-note quizzes with free response questions. The purpose of the Unit Assignment is to give the students meaningful experience with free response questions, which is 50% of the AP Chemistry exam. The Unit Assignments are evaluated during class time for maximum feedback potential, so there will be no points awarded to students who turn in these assignments after they are evaluated in class. o Blackboard Practice tests have a hard deadline since they must be completed the night prior to the unit test. No points are awarded for Bb Practice Tests completed after the corresponding test. o Test corrections must be completed within 10 school days of the date that the tests are returned to the class. Test corrections work must be supervised by a science teacher. Collaboration vs. Cheating: Students are encouraged to work together in this class. Copying work, however, is not permitted. When students collaborate on laboratories, class work and homework, they are expected to record their work in their own words and design their own method for recording, organizing and displaying data even when working with others in a group. It is a violation of the honor code to use resources without giving proper credit, to pass off another’s work as one’s own work or to give or to receive help on a test. All honor code violations will be processed according to the W-L regulations as set forth in the handbook. I am available for extra help during General’s Period, and both lunches on W days. Ms Fretts has a lunch lab for all science students on L days, both lunches. o Grading Policy: Student grades reflect student achievement and not student behavior. Quarterly grades are calculated through the accumulation of summative and formative assessments, specifically laboratory work, Unit Assignments, Blackboard practice tests, quizzes, tests, exams (midterm, and mock exams), class participation and homework. Quarter grades are computed using a point system. Tests are 100 points, labs and Unit Assignments vary from 10 to 50 points, Blackboard practice tests vary from 10 to 30 points. According to APS policy, homework will not exceed 15% of any quarter grade. The percentage of the total points determines the letter grade, according to the chart below. Quarterly grades will round up to the nearest 1%. Quarterly tests and mid-terms are calculated into the quarter grade. The Final Exam will count for a maximum of 20%, and the balance of the final grade for the year is equally divided across the four quarterly grades. Students who take the AP Exam, as required by APS policy, will be exempt from the W-L AP Chemistry Final Exam, and their final grade for the year will be an average of the four quarter grades. The College Board determines the AP Chemistry grade, based on the AP Chemistry test results alone. GRADING SCALE Letter Grade A B+ B C+ C D+ D E Percentages Quality Points AP & IB Quality Points 90,91,92,93,94,95,96,97,98, 99, 100 87, 88, 89 80, 81, 82, 83, 84, 85, 86 77, 78, 79 70, 71, 72, 73, 74, 75, 76 67, 68, 69 60, 61, 62, 63, 64, 65, 66 0 – 59 4.0 3.5 3.0 2.5 2.0 1.5 1.0 0.0 5.0 4.5 4.0 3.5 3.0 2.5 2.0 0.0 Units of Study and Major Assignments: Summer Assignment: A review of high school chemistry As this is a second year course, students should have a sound previous knowledge of Molar relationships Gas laws Electronic structure Properties of solutions History of Atomic Theory Nuclear chemistry Periodicity Laboratory practices and experimental design Bonding and Intermolecular Forces Molecular geometry This course will take full advantage of this previous knowledge, because although these topics will be covered again in detail, we will go over them quickly. Unit 1: Chemistry Fundamentals: Review of 1st Year Chemistry (con’t) & Experimental Design Lab safety, significant figures and measurement uncertainty, dimensional analysis, separation/ purification techniques, experimental design and data analysis. Writing formulas, computing oxidation states, nomenclature Major Assignments: Unit Assignment Unit 1 Test (Ch 1 & 2) Labs #1 - 5 Unit 2: Stoichiometry & Reaction Types The mole, molar mass, molecular and empirical formulas, molar volume of gases, reaction types, Stoichiometry of reactions, percent composition, limiting reactants, percent yield and solution stoichiometry Major Assignments: Unit Assignment Labs 6 - 7 Unit 2 Test (Ch 3 & 4) Unit 3: Behavior of Gases and Electronic Structure & the Periodic Table Laws of Ideal Gases: Boyle’s Law, Charles’s Law, Guy-Lussac’s Law, Ideal Gas Law, Combined Gas Law, Dalton’s Law of Partial Pressures, Kinetic Molecular Theory of Gases: Interpretation of gas laws on the basis of this theory, Avogadro’s hypothesis and the mole concept, Molar Volume at STP, Dependence of kinetic energy of molecules on Kelvin Temperature, Deviations from ideal gas laws. The history of atomic theory including Laws of Definite Composition and Multiple Proportion and Conservation of Mass, Dalton’s theory, Rutherford’s Gold Foil experiment, the CR Tube experiments, and the current model of the atom. Major Assignments: Unit Assignment Labs 8 – 11 Unit 3 Test (Ch 5, 7 & 8) Unit 4: Calorimetry and Thermodynamics: Enthalpy, Entropy and Free Energy Specific heat, calorimetry determinations, enthalpy of reactions, Hess’s law, heats of formation, bond energies and heats of reactions, work, endothermic and exothermic reactions, entropy, Laws of Thermodynamics, and Gibb’s Free Energy Major Assignments: Unit Assignment Lab 12 Unit 4 Test (Ch 6 & 18) The Chemistry of Coastal Ecology: Environmental Water Quality factors and a Stream Study Field Trip to local stream site (Lab 13) Unit 5: Chemical Kinetics, Qualitative Analysis and Chemical Equilibrium Reaction kinetics, rate law expressions, order of reactions, reaction mechanisms, rate constant, reaction half-life, activation energy, catalysts, reaction intermediates and activated complexes. Law of Mass Action, equilibrium expressions, calculations of K and equilibrium concentrations from initial conditions, LeChatelier’s principle and how the equilibrium shifts with changes in temperature, pressure and concentration. Major Assignments: Unit Assignment Labs 14 – 17 Unit 5 Test (Ch 12 - 14) Midterm Exam Unit 6: Acids and Bases and Aqueous Equilibria (Buffers, Ion Solubility) pH, Ka and Kb expressions, titration, ionization, Kw, indicators, equivalence points, buffers, Henderson-Hasselbach equation, Arrhenius, Bronsted-Lowry and Lewis definitions/theories, structural aspects of ionization, salt hydrolysis, the pH of salts and Kspexpressions. Major Assignments: Unit Assignment Labs 18-20 Unit 6 Test (Ch 15 & 16) Unit 7: Oxidation-Reduction Reactions, Electrochemistry, Nuclear Reactions and Nuclear Energy Oxidation and reduction, half cells and equations, galvanic and electrolytic cells, standard reduction potentials, Nernst equation, Faraday’s law, writing and balancing redox equations. Nuclear equations, half-life calculations, fission and fusion, nuclear energy and reactors, types of nuclear decay, zone of stability and mass defect. Societal issues of fuels and energies. Major Assignments: Labs 21 – 23 Electrochemistry Quiz Unit 7 Test (Ch 19 & 20) Unit 8: Bonding & Intermolecular Forces, Molecular Geometry, and Complex Ions Lewis structures, ionic bonding, covalent bonding, polarity, exceptions to octet rule, resonance, VSEPR theory, molecular geometries, hybridization, molecular orbitals, diploe-dipole interactions, dispersion forces, hydrogen bonding, network solids, complex ion formation Major Assignments: Labs 24-27 Unit Assignment Unit 8 Test (Ch 9-12, 17) Unit 9: Organic Chemistry Hydrocarbons, physical properties and reactions, nomenclature, general formulas, functional groups. Major Assignments: Unit Assignment Labs 28 & 29 Unit 9 Test (Ch 23) Unit 10: Solutions (Colligative Properties, Redox Titration, Beer’s Law) and Descriptive Chemistry Electrolytes and nonelectrolytes, molarity vs. Molality, mole fraction, colligative properties, Raoult’s law, Henry’s law, freezing point depression & boiling point elevation, osmotic pressure, vapor pressure, changes of state and phase diagrams Major Assignments: Labs 29 – 32 Unit Assignment (Ch 12 & 22) Course Review Mock Exam/Final Exam AP Exam Independent Project Laboratory Activities The Instructor provides this schedule as a guideline, but it is not written in stone. Other laboratories may be substituted, and timing may change due to availability of resources and field trip opportunities, and the needs and interests of the class. Month Laboratory Investigation Title & Purpose August 1. Investigating Solutions To design an experiment involving solution properties 2-5 Resolution of Mixtures To practice several laboratory techniques of separating mixtures: Distillation, Filtration & Recrystallization, Paper Chromatography, and Column (Liquid) Chromatography 6 Precipitation Reactions and Solubility Rules To discover solubility rules and write net ionic equations for the reactions that take place 7 Gravimetric Analysis of a Carbonate To perform an analytical gravimetric determination of a carbonate. To use mass and mole relationships in a chemical reaction. 8 Boyle’s Law To empirically deduce Boyle’s law 9The Molar Volume of a Gas To quantitatively determine the molar volume of a gas at STP using the empirical data Sept Oct Approx. Lab Time (hours) 2 6 2 3 1 2.5 Nov TBD Dec Jan Feb Mar Apr 10 Emission Spectrometry A hands-on experience with simple spectroscopes and line spectra 11 Flame Tests To learn and apply the basic principles of emission spectroscopy 12 Enthalpy of Solution To determine the enthalpy change associated with 3 reactions and to empirically verify Hess’s Law 13 Coastal Ecology To investigate the environmental health of a rural aquatic ecosystem using colorimetric & spectrophotometric analysis. 14 Reaction Rates To determine the order and rate law of the iodine clock reaction with respect to the iodate ion concentration. 15 From Reactions to Equations The descriptive chemistry of 3 gases: Production reactions & Verification of identity with splint tests 16 Qualitative Analysis of Anions Wet chemistry analysis techniques of an unknown ion 17 LeChatelier's Principle A hands-on experience with shifting equilibrium systems to validate LeChatelier’s Principle 18 pH of Salts To predict and verify the acid-base properties of salts 19 Acid-Base Titration The titration with primary standard to standardize a NaOH solution and then use it to quantitatively determine the molar mass of an unknown solid acid or the percent composition of an unknown acid solution 20 Determination of Ka for an unknown weak acid To use titration to produce a buffer solution and to determine the equilibrium constant, Ka, of an unknown acid 21 Activity Series To determine an electrochemical series of metals and nonmetals and write the net ionic equations for the reactions 22 Corrosion of Iron To qualitatively investigate the corrosion of iron and cathodic protection 23 Nuclear Decay Kinetics To investigate the mathematical patterns of the first order kinetics of nuclear decay 24 Models of Covalent Molecules A hands-on inquiry experience with molecular bonding, geometries and polarity 25 Hydrocarbons Activity An inquiry experience with the patterns of alkanes, alkenes and alkynes 26 Polymer Synthesis The synthesis and analysis of an organic polymer 27 Complex Ions Lab The synthesis and analysis of coordination compounds of copper 28 Beer-Lambert Law 1 1 2 10 3 1.5 3 1.5 1 4 2 2 2 1.5 1.5 2 1 2.5 1.5 May TBD Using spectrophotometric techniques to investigate the concentration of an unknown solution 29A Sequence of Copper Reactions A 5-step series of reactions involving the compounds of copper that demonstrates the characteristics of transition metal compounds. 30 Freezing Point Depression: Ice Cream Possible Field Trips A tour of the Secret Service forensics lab at the DC Headquarters and/or A visit to a local stream site and/or A tour of the Smithsonian Museum of Natural History’s Gems, Minerals and Rocks Exhibit and/or A tour of the National Museum of Medical History 2.5 1 *All laboratories are student run. Detach and return to Ms Brasfield I have received and read the 2013-2014 AP Chemistry class syllabus. __________________________ Student printed name ______________________________ Student signature _________ Date __________________________ Parent printed name ______________________________ Parent signature __________ Date