AP Chemistry Unit 9 Vocabulary: Atomic Structure & Periodic Properties You are responsible for knowing the meaning and applications of each of the following terms. You can receive extra credit by creating numbered flashcards, one for each word (the word is on one side and the definition is on the other). 1. Dalton’s Atomic Theory 2. Electronic Structure 3. Wavelength 4. Frequency 5. Plank’s Constant 6. Atomic Spectrum 7. Orbitals 8. Bohr’s Model 9. Wave Mechanical Model 10. Ground State 11. Excited State 12. de Broglie’s Matter Wave Theory 13. Momentum 14. Heisenberg’s Uncertainty Principle 15. Pauli Exclusion Principle 16. Magnetic Quantum Number 17. Principle Quantum Number (Electron Shell) 18. Angular Momentum Quantum Number (Subshell) 19. Spin Quantum Number 20. Electron Configuration 21. Valence Electrons 22. Core Electrons 23. Hund’s Rule 24. Aufbau Principle 25. Main Group Elements 26. Transition Elements 27. Lanthanide (Rare Earth) Elements 28. Actinide Elements 29. Alkali Metals 30. Alkaline Earth Metals 31. Halogens 32. Noble (Inert) Gases 33. Metalloids 34. Allotrope 35. Atomic Radius 36. Ionization Energy 37. Electron Affinity 38. Electronegativity 39. Metallic Character What you need to know for Unit 9: Unit 9 relates to Chapters 6 & 7 in your textbook. Describe the electromagnetic spectrum Describe the relationship between frequency and wavelength and calculate both Describe the relationship between energy and wavelength of light and be able to order the light based on both Describe the dual nature of light Describe diffraction Explain how line spectra of the elements relate to the idea of quantized energy states of electrons in atoms Describe the quantum mechanical model of the atom including the Schrodinger equation and wave functions Understand Heisenberg’s Uncertainty Principle and how it limits how precisely we can specify the position and momentum of subatomic particles such as electrons Describe orbital shape and energies of an atom Describe quantum numbers and how they relate to orbitals Describe electron spin and the Pauli Exclusion Principle Draw an orbital diagram Write electron configurations and use the periodic table to write abbreviated electron configurations Write electron configurations of ions Describe the problems of the Schrödinger equation with polyeletronic ions Describe the periodic table and the Aufbau Principle Describe Hund’s Rule and electron configuration Describe periodic trends such as atomic radii, ionization energy, electron affinity, electronegativity, reactivity, oxidation numbers, and ionic radii and how each are related to chemical reactivity and physical properties Understand how radii change as atoms become ions Understand how the ionization energy changes as we remove excessive electrons and recognize that it jumps as when removing a core electron Name and describe properties of main group elements (alkali metals, alkaline earth metals, transition metals, halogens, and noble gases) There is also a list of important people who contributed to the Modern Atomic Theory. You will need to know what each one did. John Dalton: Atomic Theory Michal Faraday: electric current can cause chemical reactions Sir William Crookes: cathode ray tube J.J. Thomson: used cathode ray tube to discover electrons and their mass; also created the plum pudding model of the atom Robert Millikan: oil drop experiment to find charge of electrons Ernest Rutherford: gold foil experiment to find that atoms had a small, positive, densely packed nucleus and that atoms are mostly empty space; also discovered the proton James Chadwick: discovered the neutron Johann Balmer: used hydrogen to find that light wavelength related to numbers Johannes Rydberg: created equation to make Blamer’s concept apply to all elements Niels Bohr: created “solar system model” of atoms where electrons go around nucleus in different orbitals Max Planck: light is contained in particles called photons Louis de Broglie: if light travels in waves then electrons (matter) can travel in waves Erwin Schrödinger: created wave-mechanical, or quantum mechicanl, model Werner Heisenberg: created uncertainty principle where the position and momentum of an electron can not be known at the same time