Quarterly Status Report: Project #26 September through November, 2005 Project Title: An Integrated Geoscience Approach to CO2 Leakage Prediction and Detection at Geologic Sequestration Sites Principal Investigator: Tom Wilson, Henry Rauch & Tim Warner Quaterly Report: September-November 05 1.0 Assessment Summary Budget Status: We are under-budget on our expenses. Lack of interaction with the Southwestern Regional Partnership makes us hesitant to hire masters students and a post-doc at this time. We are unsure what kinds of subsurface and surface geology data exist for the San Juan Basin Pilot site and what kinds of dedicated activities may be needed to develop databases that may not for the Simon Canyon pilot area or to expand existing but incomplete databases. Work Performed: Task 1 (Wilson) Startup delays, perceptions and recommendations As noted in October, startup on our project has been delayed due to uncertainties in the exact location of the ECBM pilot test area and delays in initiating detailed studies of the pilot test area by the Southwest Regional Carbon Sequestration Partnership. Further, we note that the Southwestern Regional Partnership web site (http://www.southwestcarbonpartnership.org/) does not appear to be up and running. In general we have been unable to locate any databases that might have been developed as part of the regional partnership’s Phase I efforts. The Southwest Partnership (SWP) recently scheduled a kickoff meeting for December 15th and 16th in Socorro, New Mexico. We have not initiated any direct contacts with the SWP at this point to avoid interfering with the development of forthcoming collaborative efforts between NETL and the SWP on their Phase II efforts. However, now that a kickoff meeting is in the planning stages, we will conference call with Brian McPherson (technical contact for the Southwest Region Partnership) prior to their meeting to get some feedback on the extent of background data that may have been compiled during Phase I to support Phase II pilot efforts. At that time we will request databases likely to have been developed as part of their Phase I efforts and will design needed expansions to, and developments of, databases required for our study. Given the apparent lack of information about the site, we suggest that an extended background development effort is necessary and justified. Also, although CO2 injection has been delayed, we do not know what this means about initial field development. In most cases coalbed methane production is preceded by a lengthy period of water production. As noted in the SWP Phase II fact sheet (see http://www.netl.doe.gov/coal/Carbon%20Sequestration/rcsp/phase2/pdf /southwest.pdf) the SWP activities include a Terrestrial Riparian Restoration Project which will involve the desalinization of water produced from the ECBM pilot. We will want to have our background efforts completed or at least significantly underway prior to dewatering of the coal seam, since the dewatering activity may affect conditions in overlying aquifers as well as microseepage of light hydrocarbons to the surface. These activities have, in the past generated considerable concern in the Four-Corners area (see http://www.ogap.org/wcbmp.htm) and given impetus to several citizens action groups. We will need to begin groundwater testing as soon as 1 possible to provide baseline data concerning issues of ground water contamination, the development of methane and hydrogen sulfide seeps, and loss of stock water supply wells. Such environmental concerns, should they arise, could easily bring carbon sequestration activities in this area and in others to an early halt. Remote Sensing In the last monthly report, existing imagery were noted and illustrated. The table below summarizes available imagery from the San Juan Basin pilot area. Imagery Landsat orthophoto Ikonos Radarsat Type TM TM TM ETM+ ETM+ ETM+ resolution 30 30 30 30 30 30 1 1m/4m Date ID (eg P/R) 89-07-05 34/34 89-07-05 34/35 89-07-04 35/34 02-08-26 34/34 01-06-04 34/35 00-09-12 35/34 ? Archuleta + 2002-03 2002-09 Standard 25m 1996-2005 Several with different incidence angles available # of bands 7 7 7 7 + pan 7 + pan 7 + pan mono 4 + pan 4 + pan Have No No Yes Yes Yes Yes Yes No No No No QuickBird imagery has not been collected over the site. QuickBird is a satellite image that provides 0.6 to 0.7 meter resolution in a panchromatic view and 2.4 to 2.8 meter resolution in 4 additional bands spanning the visible and near infrared. Since a kickoff meeting is scheduled for mid-December we will place an order for a QuickBird new-collect during the next quarter. The QuickBird image will serve as a high resolution basemap for the background study. A proposal to obtain Radarsat data at non commercial rates is in preparation. The SWP plans to inject 71,000 tons of CO2 at the site. This is a significant volume and the possibility costs of obtaining radar interferograms to document surface uplift in response to injected CO2 and long term coal swelling will also be explored. Preliminary band ratios have been computed for a couple of the Landsat scenes. In the next quarter, we will explore different approaches to combining band ratios with other bands and also examine temporal change in bands and band combinations from different Landsat scenes as we attempt to gain familiarity with the local geology. Geologic background Discussions concerning the geologic background for the site reveal limited information over the Simon Canyon Pilot area. Discussion with New Mexico Survey coal geologist Gretchen Huffman and field geologist Sean Connell indicate that detailed surficial geologic maps of the area do not exist. The most detailed geologic map of the area appears to be a 1x2 degree 1:250,000 scale map of the region (USGS Miscellaneous Investigations Map I-1730). Fassett’s paper (Geologic and Coal Resources of the Upper Cretaceous Fruitland Formation, San Juan Basin, New Mexico and Colorado, Chapter Q, USGS Professional Paper 1625-B) provides an excellent reference to the geology of the Fruitland coal. The map on the following page 2 (Figure 1) taken from Fassett’s paper illustrates the general structure of the San Juan Basin on the top of the Pictured Cliffs Sandstone at the base of the coal bearing Fruitland Formation. The map reveals the pilot site is located in the deeper part of the basin. Surface elevations at the site vary from about 6300 to 6600 feet above sea level. Depths to the Fruitland are approximately 3000 feet,and net thickness of the Fruitland Formation coal beds is between 50 to 60 feet in the Figure 1: Depth to the base of the Fruitland Formation. Approximate location of the SWP ECBM pilot area is circled. Figure 2: Stratigraphic cross section showing coal distribution within the Fruitland Formation. Section passes near the pilot site. Position approximated by red rectangle. 3 area. Coals are distributed through the Fruitland Formation as shown in the cross section in Figure 2 (Ayers and Zellers (1994) taken from Fassett). Characterization efforts have also included compilation of basic culture, township, range and section layers for the San Juan basin project area base map (see Figure 3). Figure 3: Preliminary base map of the area with culture, township, range and section layers. Several wells have been located in the vicinity of the proposed injection well. The general location of the pilot site is circled above. Several wells (see Figure 3) have been located using the New Mexico Oil Conservation Division Oil and Natural Gas Administration and Revenue Database. In the coming months well files in the area will be searched for drillers picks on formation tops to allow construction of structure and isopach maps of subsurface intervals across the site. Geophysical logs will also be located an downloaded from the on-line data base. In spite of delays in establishing links to the Southwest Regional Partnership concerning their plans for the San Juan Basin pilot, the details and limitations of their databases, additional database needs related to NETL tracer studies, and the time table for initiation of production from the injection well, we have made significant strides to initiate independent characterization efforts and move the planning for this effort forward. The forthcoming Southwest Regional 4 Partnership kickoff meeting should provide opportunities to answer many of our questions and to design site specific field efforts in support of the NETL tracer studies. Task 2(Rauch) Startup delays, perceptions, and planning Startup of Rauch's task project work has been delayed, for reasons noted above under Task 1 (Wilson). However, planning work is proceeding in preparation for later work. Rauch has had recent discussions with Art Wells, the primary NETL collaborator on our RDS research project regarding the coordination of our ground water monitoring activities with the tracer and soil gas monitoring efforts planned by Art Well's NETL team (Art Wells, Rod Diehl, and Brian Strazisar, and Curt White of Parsons Laboratory). Rauch has also been in recent discussions with the West Virginia University Sponsored Programs Office, with Parsons Laboratory at Pittsburgh PA NETL, and with Triad Black Rock Test Lab in Morgantown, WV, in an effort to obtain detailed price information for future ground water sample chemical analyses, and to secure a backup laboratory company to Parsons Laboratory at Pittsburgh NETL for these chemical analyses if needed. Contact has also been initiated with the Morgantown NETL Parsons Lab to obtain price information for future vadose zone gas analyses. Task 3(Warner) 1.1 Recommended Changes to Objectives As noted in earlier months, we are waiting for details on pilot site background, site preparation, and the timetable for deployment activities to unfold. As these details emerge, it may be necessary for us to modify objectives and field activities. One prominent concern, for example, relates to an apparent absence of detailed surficial geology maps of the pilot site and surrounding area. It may be necessary for us to undertake field mapping efforts in the area to provide the level of detailed information on surface lithology distributions that will be needed for interpretation of Landsat imagery and future hyperspectral imagery. We expect many of these uncertainties to be clarified following the Southwestern Regional Partnership’s kickoff meeting in mid-December. 1.2 Recommended Changes to Technical Approach None 1.3 Task Progress against major planned accomplishments Hiring of grad students and post-doc has been delayed to allow us to identify specific limitations in the Southwest Regional Partnership data bases for the San Juan Basin pilot area. We may need to change efforts to address these deficiencies. It will be best for us to consider these needs prior to advertising the post-doc position. Geological characterization of the San Juan Basin is well under way. Existing remote sensing data over the area has been identified. Some data (Landsat & orthophoto imagery) have been obtained. Preliminary analysis of Landsat data has been initiated. 2.0 Impact on project accomplishments All issues have been addressed in the preceding discussions 5 3.0 Task cost variances from planned budget No major cost variances. Hiring of grad students and post doc waits more definitive start date for NETL collaborative field effort. 4.0 Budget forecast As noted, we are currently under budget, so the forecast is good. 5.0 Open items/issues There has been some discussion that we should attempt characterization of a second pilot site in collaboration with one of the other regional partnerships. We would appreciate any efforts that NETL can bring to bear to resolve uncertainties in where our efforts should be dedicated. At present, we are operating under the assumption that our efforts should be focused on developing the background studies needed to precede initiation of the San Juan Basin ECBM pilot. If we are to redirect our efforts into some other area, we will need some advance notice to plan site characterization and a long enough window of time to carry out basic background studies. 6.0 Presentations and publications None 6