CHEMISTRY CLASS-12 GDS-2 ALKANE 8.According to reaction what is x ? 1.Which substance is called “chloroform C H Cl CH Cl 2 Na 2 NaCl x 2 5 3 “? A) CH C H Cl B) CH A) CH3Cl B) CH2Cl2 3 2 5 4 C) CHCl3 D)CHCl2F C) C H D) C H 5 12 3 8 2.When 2 moles of a four carbon hydrocarbon is burned , 10 moles of oxygen gas is used up. The molecular formula of hydrocarbon is : A) C4H8 B) C4H6 C) C4H10 D) C4H4 9. For saturated hydrocarbons ; I. General formula is CnH2n+1 II. Increasing the number of Carbon; increases boiling point III. sp3 hybrid orbitals are used 3.In Wurtz reaction , bromides of ethyl Which one(s) is/are correct? and propyl are used .So , the product(s) A) I B) II C) II – III D) I – III would be . . . . . . . . . . . . 1. C4H10 2. C5H12 3. C6H14 10.What is the formula of an alkane of which 0.25 mole is 11g ? A) 1 B) 2 C) 3 D) none of them A) C2H4 B) C3H8 4.Which one of the following alkanes is not produced by Wurtz Synthesize? A) C2H6 B) CH4 C) C3H8 D) C4H10 11. 5.Which is the compound whose 2.24 lt is 3 g at STP? (C : 12, H : 1, O : 16). A) CH4 B) C3H8 C)C2H4 D) C2H6 B) C2H5Br D) C3H8Br D) C3H6 C2H5Br + Mg X X + H2O Y + Z What is the substance represented by “Y” in the above reaction? A) C2H4 B) C2H6 C) C4H8 6.Which alkyl halide must be used to obtain ethane by the substitution reaction of H2? A) CH3Br C) C2H6 C) C3H4 D) C4H10 ? 12. C3 H 7 Br H 2 Ni A) C3H8 B) C3H6 C) C3H10 D) C4H8 13.which alkyl pairs must be used to obtain n-pentane? 7.How many liter of air is needed to burn the 4,48 liters of butane gas? A) methyl – propyl C) propyl – propyl A) 75 B) 72,8 C) 291,2 D) 145,6 SHELALE EDUCATIONAL CORPORATION 1 B) ethyl – propyl D) ethyl – butyl CHEMISTRY CLASS-12 14. 0.2 mole of an alkyl bromide weighs 19g. This alkyl bromide is used in the production of an alkane by Wurtz synthesis. If 1 mole of this alkane is burned, how many moles of CO2 can be obtained? A) 1 B) 2 C) 3 D) 4 GDS-2 20. 0.1 mole of an organic substance burns in 0.3 mole oxygen to produce 0.2 mole CO2 and 0.3 mole H2O. What is the formula of the organic substance? A) C2H6O B) C3H8 C) C2H4O D) C2H6 21. 15. I. II. III. Al4 C3 12HCl 4AlCl3 3CH 4 cyclo butane 2 - butyne 1 - butene what is the mass of aliminium carbide ? A)37.6 B)28.5 C)16.4 D)7.2 Which compound or compounds form/forms 0,8 mole H2O when each of them with 0,2 mole is burned with enough oxygen? A) I B) II C) I - II 22. 0.2 mole of an alkane burns to form 10.8g of H2O. which one of the following must be used to produce this alkane through Wurtz synthesis? D) I - III A)CH3Br C)C3H7Br 16.Which compound doesn't change the color of Br2 solution? A) C2H2 B) C2H4 B)C2H5Br D)C4H9Br C) C3H4 D) CH4 23. How many moles of O2 are needed to burn 0.5 mole of an alkane which has been orbtained from the reaction between CH3COONa and NaOH? 17.When 8,8 gram of an alkane is burned; 26,4 gram of CO2 is produced. What is the formula of this Hydrocarbon?(C: 12, O: 16) A) C2H6 3.36L Xgram A) 1 B) C3H8 C) C4H10 D) C5H12 B) 2 C) 2.5 D) 3 18.How many liter of air is needed to burn 1,4 liter of ethane? 24. How many moles of O2 are required to burn 2 moles of an alkane formed from C2H5COONa and NaOH? A) 4,9 A) 2 B) 7,5 C) 13,8 D) 24,5 B) 4 C) 6 D)7 25.How many gram of CH4 must be used to obtain 11 gram of CO2 after reaction? (C: 12, H: 1) 19.How many liter of air is needed to burn the 88 gram of propane at STP? A) 318,3 B) 954,4 C) 1120 D) 477,2 SHELALE EDUCATIONAL CORPORATION 2 CHEMISTRY CLASS-12 A) 2 B) 4 C) 6 D) 8 A) 0,36 26. 0.2 moles of an alkane yeilds 18g of H2O when it is burned. Which of the following must be used to obtain these alkane by Wurtz synthesis, A) B) C) D) GDS-2 B) 7,2 C) 14,4 D) 2,16 32. To burn 20 lt of a mixture of C2H4 and C3H8 gases, 70 liters of O2 is needed under the same conditions. What is the volume of C2H4 in the mixture? C2H5Br CH3Br n- propylbromide isopropyl bromide A)5 B)7.5 C)10 D)15 33. How many moles of O2 are required to burn 1 mole of an alkane whose 0.25 mole produces 16.8 lt CO2 when it is burned under STP? A)1.5 B) 2.5 C) 3.0 D)5.0 27. 80 % of an alkane is carbon. What is the formula of alkane? A) C2H6 B) C3H8 C) C2H8 D) C4H10 34.What is the name of the substance X 28. 4.48 liters of a gas shown by the in the reaction? general formula Cn H2n+2 is 6 grams at C6 H5Br CH3Br 2Na X Y ? STP. What is “n” in the formula? A) benzene B) bromobenzene C) methane D) toluene A) 1 B) 2 C) 3 D) 4 35. When 3,2 g of hydrocarbon is 29. In the compound shown with the burned in excess amount of O2 at STP m H 1 condition; 4,48L of CO2 and 7,2 g of general formula CnH2n+2 . mC 4 H2O are produced. What is the molecular formula of this organic Which is the correct formula for this compound? compound? A)CH4 B)C2H6 C)C3H8 A) C4H8 D) C4H10 B) C2H4 C) CH4 D) C2H6 36. 10 cm 3 of a gas containing C and H 30. What is the gas having the general reacts with 50 cm3 of O2 and forms 30 formula CnH2n+2 and 58 g/mole cm3 of CO2 gas and a certain amount of molecular mass? water under the same conditions. What is the formula of this compound? A)C4H10 B)C 4H8 C)C3H8 D)C5H10 A) C3H4 B) C3H6 C) C3H8 D) C4H6 31. How many grams of Al4C3 must be used to obtain 6.72 l of CH4 at STP 37.When 0,88 gram of an organic conditions .(Al:27,C:12) compound is burnt, 2,2 gram of CO2 and SHELALE EDUCATIONAL CORPORATION 3 CHEMISTRY CLASS-12 1,08 gram of H2O are formed. What is the simplest formula of compound? A) (C5H12O)n C) (CH3)n GDS-2 43. One method to synthesize saturated hydrocarbons is Wurtz reaction whose general equation is. 2R X 2Na R R 2NaX B) (C5H12)n D) (C4H9O)n What is the formula of alkane produced with the reaction of 2-bromobutane with Na? 38.When 0,1 mole of hydrocarbon is burned completely; 0,2 mole of CO2 and 0,3 mole of H2O are produced. What is the chemical formula of this hydrocarbon? A) N - octane B) 2 methylhexane C) 3,4 –dimethylhexane D)3-methylexane A) C2H2 B) C2H4 C) C2H6 D) C4H6 39. Which organic compound can be produced from the reaction below? 44. What is the condensed formula of the compound for which 0.3 mole of it heat CH 3COONa NaOH ....... Na2CO3 is 21 grams? A) CH 4 B) C2 H6 C) C2 H5OH D) None of them A) C2H2 B) C3H6 C) C4H8 D)C5H10 45.What is the formula of compound, 15 grams of which produces 1 molCO2 when burned? (C:12,H:1) 40.What is the formula of alkane if 2,2 grams of RCOONa reacts with 0,8 grams NaOH? (Na:23, H:1, O:16) A) C2H2 B)C2H4 C)C2H6 D) C3H8 A)C2H6 B)C3H8 C)C3H4 D)C5H12 46.When 0.1 mole sample of an alkane is burned 0.4 mole of water vapor is 41.When a 0.1 mol of an alkane is burned 7.2 g of water vapor is produced. produced. What is the formula of the alkane?(C: 12 , H: 1 , O: 16 ) What is the formula of the alkane? A)C3H8 B)C2H6 A) C3H8 B) C2H6 C)CH4 D)C4H10 42. How many moles of carbondioxide are produced by burning out 30 g of ethane? A)5 mol B)6 mol C)4 mol D)2 mol C) CH4 D) C4H10 47.After burning 12 gram organic compound 0.6 mol CO2 and 0.8 mol H2O are formed. What is the emperical formula of organic matter? A)C3H8O2 B)C3H8O SHELALE EDUCATIONAL CORPORATION 4 CHEMISTRY CLASS-12 GDS-2 ALKENE 49. Which of the following substances will turn KMnO4 solution rapidly from purple to colorless ? A) methane B) ethane C) ethene D)propane III. It doesn’t consist of a ring. What is the chemical formula of this hydrocarbon 50.Which one of the following substances will turn bromine water rapidly from orange-red to colorless ? 61. Which one belongs to the olefines? A)C4H8 B)C4H10 C)C5 H12 D)C4H6 A) C2H2 B) C4H8 C) C2H6 D) C3H4 D) C2H4 65. CH – CH CH HBr 3 2 Product is expected I. CH3 CH2 CH2 Br 52.What is the type of following reaction ? II. CH CBrH CH A) CH4 B) C3H8 C) C4H10 3 HC heat CH2 Br2 III. CH3 CBr Br H3C H3C CH A) I CH2 Br A) B) C) D) 3 B) II CH 2 C) III D) I – III 67. Which organic compound can be produced from the reaction below? Combustion Reaction Addition Reaction Extraction Reaction Wurtz Reaction H2 SO4 CH3CH 2OH .............. H 2O 1800 C A) Ethylene C) Ethanol 54. In this equation: Cn H2n O2 CO2 H2O B) Propanal D) Styrene , the coefficient of O2 in the balanced 68. Which type of organic compound equation is can be produced from the reaction below? 2n 1 2n 1 A) B) 2 3n 1 C) 2 2 3n D) 2 Ni CH 3CH CH 2 H 2 ............. A) Alkyne B) Alcohol 58.For a hydrocarbon. C) Alkane D) Alkene I. There are cıs and trans isomers II. When 1 mole of this compound is 69.Which compound has a capability to burned; 6 moles of O2 are consumed undergo addition reaction of Hydrogen? SHELALE EDUCATIONAL CORPORATION 5 CHEMISTRY CLASS-12 D) A) butane C) 1,2 – difluoroethylene B) ethane D) CCl4 GDS-2 butane 83. Which one has an ability to make addition reaction of hydrogen? 70.If 1 mole of H2O is removed from 1 mol of propyl alcohol ,which one of the followings is produced ? A)C2H6 B)C2H5OH C)C2H4Br2 D)C2H2 A)Propane C)Propyne 86. What is the hydrocarbon which forms a white precipitate with ammoniacal AgNO3 solution and decolorizes bromine solution? B)Propene D)Acetone ALKYNES 76. What hydrocarbons have common formula CnH2n-2? A) CH4 92. Which of the following alkynes cannot react with ammoniacal AgNO3 A) Ethylene B) Cycloparaffines C)Acetylene D)Saturatedhydrocarbons solution? A) HC CH 77.Which one is a member of the acetylene class? A) C2H4 B) C2H6 B) C2H6 C) C2H4 D) C2H2 B) CH3 --C CH C) HC C--CH 2 --CH3 D) CH3 --C C--CH3 96. Which organic compound can be produced from the reaction below? C) C3H4 D) C3H6 CaC H O ............ Ca(OH )2 2 2 80. What is the coefficient of O2 in the A) Ethylene combustion reaction of a hydrocarbon C) Acetylene having the general formula CnH2n-2 ? A) n 1 C) 3n 1 3n 1 2 2n 1 D) 2 B) Propane D) Methanol 98. What is the formula of compound if 10g of CnH2n-2 is burned to give 9 gram of H2O? A) C2H2 B) C3H4 C) C4H6 D) C2H4 B) 81. CH3 C C Na CH3 Cl Which compound is expected to be formed? A) 2 - butyne B) 1 - butyne C) 2 - butene SHELALE EDUCATIONAL CORPORATION 6 CHEMISTRY CLASS-12 CLASSİC QUESTİONS 113. Draw the structural formulas of the following compounds: a) cis -2 ,3 -dichloro-2-butene b) p-bromotoluene c) methyl t-butyl ether d) 2,3-butanediol e) 2-butanone 101. complete the following reactions. H2 H 2 Y C 2 H 2 X 106. 114. Write the equations for each of the following reactions, a) Propene + Hydrogen b) 1-butyne + Hydrogen (excess) CaO 3C X CO X 2 H 2O Y Ca (OH ) 2 Determine molecular formulas of X and Y. 117. When methyl iodide reacts with 2-iodobutane in the presence of sodium metal which hydrocarbon is produced? 107. Write structural formulae of and names of the alcohols which have the molecular formula of a. C3H8O b. C4H10O 118. Complete the following reactions a) CH3CH =CH CH3 +HBr b) CH3CH2CH=CH2+H2O c) CH3CCH+2HBr d) CH3CH2CH3+O2 108. Which alcohols are used as reactants to produce the following ethers? a. CH 3CH 2 119. Complete the following reactions a) Propene+Water b) 2-Butene + Water c) 2-Butene + HCl d) 1-Pentene+HBr e) Propene +Water O CH 2CH 3 b. O 110. (R-COO)2Ca GDS-2 R- C- R + CaCO3 O In the reaction above, 15,8g of (R-COO)2Ca produces 10g of CaCO3. Find the formula of ketone produced. SHELALE EDUCATIONAL CORPORATION 7