To: Sciences in Cold and Arid Regions (scar@lzb.ac.cn) Permanent corresponding author's email: ?????? Thermal conductivity of reinforced soils: A literature review Muge Elif Orakoglu 1,2, JianKun Liu 1* 1. School of Civil Engineering, Beijing Jiaotong University, Beijing 100044, China 2. Technical Education Faculty, Department of Construction, Firat University, Elazig, Turkey *Correspondence to: Ph.D., JianKun Liu, Professor of School of Civil Engineering, Beijing Jiaotong University, Beijing 100044, China. Tel: +86-10-51684096; E-mail: jkliu@bjtu.edu.cn ABSTRACT This paper aims a review of the literature related to soil reinforcements to achieve lower soil thermal conductivity (λ). The use of various natural and synthetic fibers, polymers, geosynthetics, agricultural waste/materials, and nanoclays is discussed and existing prediction models that have been thought to affect low thermal conductivity are presented. Keywords: reinforced soil; heat flux; soil thermal conductivity 1 Introduction Soil thermal conductivity is defined as key parameter in heat flux in a unit time through a unit cross sectional area of soil under a unit temperature gradient. The constitutive equation for thermal conduction based on the temperature gradient was presented by Fourier in equation (1) (Fourier, 1955; Tritt, 2004): Q A dT dx (1) where, dT/dx is the temperature gradient, A is a cross-sectional area, Q is the heat flow, and λ is thermal conductivity of soil. Soil thermal conductivity plays a significant role in heat flux. Several methods are available for determining soil thermal conductivity, and those pertaining to reinforced soils are divided into two categories: steady-state and transient state. The steady-state method is explained by Fourier’s solution based on the heat conduction equation in a known heat flux and a known thermal gradient. There are various available techniques of the steady state method, namely, guarded-hot-plate apparatus, heat flow meter apparatus, guarded comparative-longitudinal heat flow technique, rhometer apparatus, and the Rapid k method (Mitchell and Kao, 1978). The transient state method is based on the soil thermal conductivity while the temperature of the reinforced sample changes in a period of heating or cooling. The transient methods include the thermal needle method, which is widely used in soils due to its simplicity and commercial availability (Barry-Macaulay et al., 2013). Table 1 summarizes the literature pertaining to methods used in measuring soil thermal conductivity. A number of studies suggest that determining soil thermal conductivity through in-situ measurement procedures is expensive and time-consuming. That is why many empirical relations have been developed to estimate the soil thermal conductivity (λ) based on effective parameters such as soil texture, moisture content, temperature, porosity, and saturation (Camillo and Schmugge, 1981; Campbell, 1985; Sundberg, 1988; Becker et al., 1992, Tarnawski and Leong, 2000; Côté and Konrad, 2005). 2 Usowicz et al. (2006) developed a statistical-physical model based on a non-linear regression equation using the parameters of water content, bulk density, organic matter, and content of quartz and other minerals (as determined based on content of sand, silt, and clay). Pei et al. (2013) established a thermal conductivity model of soil-rock media by a multiple linear regression method (Equations (2) and (3)) based on the saturation, temperature, porosity, dry density, and water content. They compared this with the other three primary general models, namely, the BP neural model, the physical model and the CK model, and they developed a general regression model based on the apparent heat capacity theory specifically relevant to in cold regions. The main multiple linear model equations (Zhang, 2003; Zhang et al., 2012b) are as follows. For the unfrozen state: u (1.913 10.313) (0.127 0.118) w (0.869 3.355) d (7.110 12.595)n (2.076 2.948) Sr (2) For the frozen state: f (16.028 14.954) (0.042 0.174) w (4.581 4.866) d (17.448 17.846)n (0.882 4.273) Sr (3) where λu is thermal conductivity of unfrozen soil, w is water content, ρd is dry density, n is porosity, Sr is the saturation ratio, and λf is thermal conductivity of frozen soil. References Steady State Nikolaev et al., 2013 Table 1 The methods used for measuring soil thermal conductivity Methods Abuel-Naga et al., 2009 Barry-Macaulay et al., 2013 Ekwue et al., 2006 Alrtimi et al., 2014 Mottaghy et al., 2008 Low et al., 2014 Transient State Mochizuki et al., 2008 Nusier and Abu-Hamdeh, 2003 Komle et al., 2007 Akinyemi et al., 2006 de Zárate et al., 2010 Khedari et al., 2001 El-Rawi and Al-Wash, 1995 Canakci et al., 2007 Abu-Hamdeh, 2000 Waite et al., 2002 Guarded Hot plate; Ottawa sand (with 99% quartz) content, and Richmond Hill fine sandy loam Steady-state method (divided bar) , Transient-state method (needle probe); Soft saturated clay (Bangkok clay) Steady-state method (divided bar); Transient-state method (needle probe): Coode island silt, Basaltic clay, Brighton Group sand, Brighton group clayey sand, Fishermens bend silt, Residual siltstone, sandstone, siltstone and basalt rocks. KD2 sensors based on steady-state methodology; Piarco sandy loam, Maracas clay loam, and Talparo clay New thermal cell that utilizes steady-state methods; fine sand, coarse sand, ground glass, and fluorspar with cement (20%) Divided bar method; Crystalline rocks Guarded hot plate method in accordance with BSEN 12664 (2001); clayey soil, Portland cement, newspaper, aerated lightweight concrete compositions Heat probe method by Kasubuchi; natural Toyoura sand, glass beads, NaCl solution Single-probe and dual-probe methods; Sand and loam Two needle probes; a grid of temperature sensors, evenly distributed inside the sample; two additional thermal probes; fine-grained reddish sand, coarse-grained moist sand, gravels with various grain size distributions (1 cm- to 6 cm), and for comparison and calibration pure water (with convection suppressed by adding agar-agar), compact ice, and compact granite. Single needle sensor; soils from Nigeria, heavy metals, namely, Fe, Cu, Ni, Cr, Cd, Zn, Md, Pb, As. Multi-current hot wire method; two different clays, namely, magnesium bentonite (BEMG) and sabhasana (SABA) According to JIS 2618, hot-wire method: compositions of cement, sand, and fiber waste of fiber coconut and durian Upper and lower thermo-couple wires; soil- cement mixtures Single heater and thermocouple probe; clayey and chalky limestone Single probe device; Jordanian clay loam and loam soils Von Herzen and Maxwell’s needle-probe method; four porous mixtures of quartz sand and methane gas hydrate 3 Park and Hartley, 1992 Bovesecchi and Coppa, 2013 2 Line-heat-source method based on hot-wire methods; unbounded and bounded sand A stainless-steel tube inside of which a Pt wire heater and T sensor (type T thermocouple); Pozzolanic soil (a fine sandy, unconsolidated, alluvial soil from Lazio, Italy, based on volcanic ash) and blue marlstone rocks The thermal conductivity of reinforced soils As is known, reinforced soils are solid composites which consist of a combination of two or more different structures in which their identities are preserved. The advantages of newly produced composites are higher specific strength, stiffness, and lower thermal conductivity (Kazemian et al., 2010). Reinforced soil techniques are based on the example of the bricks made from clay reinforced with straw by the Egyptians in the third millennium BC (Mathews and Rawling, 1994). Various soil types blended with waste-created bricks, fibers, geosynthetics, and polymer have been examined to determine the effects on thermal properties. Table 2 shows various reinforcement materials for blending soils. Polyesters have the widest range of use because of their simple handling and cheap price. Many researchers have focused on determining the different thermal parameters of polyester composites with variable fibers. For example, Sultana et al. (2013) studied sand polyester composites, and their experiments showed that the thermal conductivity decreased with an increase in sand content from 10% to 60%. Al-Malah and Abu-Jdayil (2007) studied bentonite (natural clay)-based unsaturated polyester composites. They determined the lowest thermal conductivity of an unsaturated polyester composite with 50% filler content and 40% polyester content in weight. Natural materials Fibers Fibers Synthetic materials Geosynthetics Table 2 Various soil reinforcement materials Coconut (Coir), Sisal, Palm, Jute, Flax, Barley Straw, Bamboo, Cane, Wood Fibers, Broom, Sawdust, Sugar Palm, Pineapple leaf, Sunn hemp, Rice husk, Kenaf Geomembrane polymers Polyethylene (HDPE, VLDPE etc.) Polypropylene (PP), Polyvinyl chloride (PVC) Polyester (PET), Impermeable Cholorosulphonated polyethylene Polyethylene (PE), (CSPE) Glass, Nylon, Steel, Ethylene Interpolymer alloy (EIA) Polyvinyl alcohol (PVA), Rubber) Polyurethane, Polyvinyl chloride Nonwoven Needle punched Chemical bonded Geotextile Geotextiles, Geogrids, Geocells, Permeable Heat bonded Geonets, Geocomposites Knitted Woven Processed types of agriculture waste/materials have been widely tested by blending them (various types of soils, cement, sand, and water) to create new composites. Raut et al. (2011) reviewed the use of waste materials in different compositions to develop waste-created bricks, and they determined that this approach was economical, environmentally sustainable option. Zhang et al. (2012a) revealed the thermal conductivity of soil in earthen ruins by adding different concentrations (5%, 10% and 15%) of potassium silicate (PS). Their test results showed that the 4 larger the PS concentration, the lower thermal conductivity (Figure 1). Bederina et al. (2007) studied the effect of the addition of wood shavings (wastes of woodworking activities) on thermal conductivity of sand concretes made from dune sand and river sand. They also compared their experimental results with a theoretical approach based on the auto-coherent method. They found that an increase in waste contents decreased the thermal conductivity of sand concrete. Additionally, Xu and Chung (2000) determined the thermal conductivity of cement pastes and mortars decreases with the addition of sand, in contrast to opposite effects of silica fume addition. Rim et al. (1999) studied the thermal and mechanical properties of a clay-cement-wood composite with different proportions of wood aggregates. Their test data showed that an increase wood aggregates (from 10% to 50%) decreased the thermal conductivity (from 0.24 to 0.08 W/(m·K)) (Figure 2). The use of natural cellulose fibers such as flax, palm, sisal, kenaf, straw, and jute in polymeric matrices in soil reinforcement methods has gained a great of attention in civil engineering applications due to their desirable properties (Alamri et al., 2012). Millogo et al. (2014) determined the engineering and thermal properties of pressed adobe blocks (PABs) fabricated with Hibiscus cannabinus fibers. Their test results showed that thermal conductivity decreased with increasing amounts and lengths of the fibers. There was a greater decrease in the thermal conductivity with long fibers (60 mm in length) than with 30 mm long fibers (Figure 3). Khedari et al. (2005) produced soil-cement blocks reinforced with coconut fibers in 18 different mix ratios. Their results showed that the thermal conductivity decreased when the fiber content increased (Figure 4). Khedari et al. (2001) figured out the effects on thermal conductivity of 18 coconut fiber specimens and 12 durian specimens prepared with different fiber lengths, grain sizes of sand, and mixing proportions (cement, sand, fiber). They found that packing fibers in composites creates voids in the composites, and short-length fibers are more difficult to coordinate and pack than longer ones. Thus, the short fiber lengths create many voids in composites, resulting in lower thermal conductivity (Figures 5, 6). Figure 1 Change of thermal conductivity with addition of potassium silicate to the soil of earthen ruins (Zhang et al., 2012a) 5 Figure 2 Influence of weight percentage of wood aggregates in a clay-cement-wood composite on thermal conductivity (Rim et al., 1999) Figure 3 Change of thermal conductivity with adding coconut fibers to soil-cement block (Khedari et al., 2005) Figure 4 Change of thermal conductivity with adding Hibiscus cannabinus fibers to pressed adobe blocks (Millogo et al., 2014) 6 Figure 5 Change of thermal conductivity in composites with adding young coconut fibers of different lengths and different sand sizes (Khedari et al., 2001) Figure 6 Change of thermal conductivity in composites with adding durian fibers of different lengths and different sand sizes (Khedari et al., 2001) Gorhan and Simsek (2013) investigated the thermal conductivity of clay bricks made with rice husks. Their results showed that the thermal conductivity coefficients increased in samples with added rice husks and increasing firing temperatures as compared to reference samples. Also, the thermal conductivities of the samples with added coarse rice husks were lower than those of the samples with added ground rice husks. Alami (2013) determined the thermal conductivity of two composites different filler materials and different dispersed-phase materials. Clay-fronds-crushed olive pits and clay-straw-olive husks were also tested and the results revealed that the clay-straw-husks specimen had a great reduction in thermal conductivity. Bal et al. (2013) revealed a decline in the thermal conductivity of laterite samples (10cm×10cm×3cm) with added millet waste. Baniassadi et al. (2011) investigated the mechanical and thermal properties of polymer (polyamide resin)/nanoclay (organo-modified montmorillonite) composites with added nanoclay. Their experimental test results showed that the addition of nanoclay increased the thermal conductivity of polyamide resin, and the higher the amount of nanoclay, the higher the thermal conductivity. Additionally, Hostler et al. (2009) studied the thermal conductivity of clay-based aerogels. The thermal conductivity of samples was determined with and without added poly (vinyl alcohol). The test data revealed that the polymer decreased thermal conductivity, and this reduction was related to a more complex interaction between the polymer and the clay. 3 Conclusions 7 This paper provides a review of thermal conductivity in soils reinforced with different materials. Fibers, polyester composites, agricultural wastes/materials and clay nanoparticles have been successfully used in various soils to reduce the thermal conductivity which enables them to be used as a thermal insulator. Clearly the thermal conductivity of soils reinforced with various natural and synthetic fibers and agricultural waste/materials decreases with increased added material contents, added material surface frictions, and existing chemical binders. Conversely, the thermal conductivity increases with addition of nanoclay to polymer/nanoclay composites, increased fiber contents and higher firing temperature. Our literature review shows that, both experimental and modeling, adding various fibers and materials produces lower soil thermal conductivity. Future research should assess reinforced soils with more waste materials and various fiber matrices (two or more) and polymer composites to address problems arising from clumping effects, fiber aspect ratios and weight fractions, gradation, and particle shapes and sizes. 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