http://hazard.com/msds/mf/perm/files/81860.TXT
PERMATEX INDUSTRIAL CORPORATION
07/02/97
ROCKY HILL, CONNECTICUT 06067
TELEPHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET
Page
01 of 06
Permatex(R) Blue RTV Silicone Gasket Maker
81860
1.
CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name:
Item No.:
Part No.:
Part Number:
Product Type:
2.
Permatex(R) Blue RTV Silicone Gasket Maker
Sensor-Safe
81860
6MA
6MA
RTV-Silicone Aerosol
COMPOSITION, INFORMATION ON INGREDIENTS
Ingredients
CAS No.
%
SEALANT
Non-hazardous ingredients
Poly(dimethylsiloxane),
hydroxy terminated
Ethyltriacetoxysilane
Methyltriacetoxysilane
SILICA, AMORPHOUS (FUMED)
ACETIC ACID
Proprietary
80-90
70131-67-8
17689-77-9
4253-34-3
7631-86-9
64-19-7
1-10
1-10
1-10
1-10
***
106-97-8
74-98-6
75-28-5
5-80
5-80
5-80
PROPELLANT
BUTANE
PROPANE
ISOBUTANE
***When this product is exposed to moisture, 3-5% acetic acid may be
formed.
Ingredients which have
Exposure Limits (TWA)
Ingredients
exposure limits
ACGIH
(TLV)
OSHA
(PEL)
OTHER
10mg/m3 TWA
6mg/m3 TWA
None
SEALANT
SILICA, AMORPHOUS (FUMED)
ACETIC ACID
10 ppm TWA
25 mg/m3
10 ppm TWA
25 mg/m3
None
PROPELLANT
PERMATEX INDUSTRIAL CORPORATION
07/02/97
ROCKY HILL, CONNECTICUT 06067
TELEPHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET
Page
02 of 06
Product Name:
Item No.:
Permatex(R) Blue RTV Silicone Gasket Maker
Sensor-Safe
81860
2. COMPOSITION, INFORMATION ON INGREDIENTS
(continued)
BUTANE
PROPANE
800 ppm TWA
1900mg/M3
Asphyxiant
800 ppm TWA
1900mg/M3
1000 ppm
1800 mg/m3
Exposure Limits (STEL)
Ingredients
ACGIH
(TLV)
OSHA
(PEL)
15 ppm
37 mg/m3
None
None
None
SEALANT
ACETIC ACID
PROPELLANT
3.
HAZARDS IDENTIFICATION
Toxicity:
Eye and skin irritant.
Moderately toxic by ingestion.
If use creates respirable particles, some
respiratory systems injury may occur. May
enhance
Primary Routes of Entry:
Signs and symptoms
of Exposure:
eyes,
allergic conditions in certain people.
Skin, ingestion, inhalation, eyes.
Acetic acid produced during cure irritates
nose throat. May cause moderate corneal
injury and
considerable redness to eyes.
Inhalation may may cause difficulty in
breathing.
Ingestion may cause vomiting. Swallowing
large
amounts may cause digestive discomfort.
Existing Conditions
Aggravated by Exposure:
Heart disease and respiratory disorders.
Methyltriacetoxysilane: Eye, skin, and
pulmonary
disorders.
Literature Referenced
Carcinogen
Ingredients
IARC OSHA
Target Organ and Other Health Effects
NTP
SEALANT
Non-hazardous ingredients
NO
Poly(dimethylsiloxane),
hydroxy terminated
NO
Ethyltriacetoxysilane
NO
Methyltriacetoxysilane
NO
No Data
NO
NO
No Data
NO
NO
No Data
NO
NO
No Data
NO
NO
PERMATEX INDUSTRIAL CORPORATION
07/02/97
ROCKY HILL, CONNECTICUT 06067
TELEPHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET
Page
03 of 06
Product Name:
Item No.:
Permatex(R) Blue RTV Silicone Gasket Maker
Sensor-Safe
81860
3. HAZARDS IDENTIFICATION
(continued)
SILICA, AMORPHOUS (FUMED)
NO
ACETIC ACID
NO
NUI
NO
N/A
COR EYE GAS IMM IRR
NO
NO
PROPELLANT
BUTANE
CAR CNS IRR
NO NO
NO
PROPANE
CAR CNS IRR
NO NO
NO
ISOBUTANE
CAR CNS LUN
NO NO
NO
-----------------------------------------------------------------------------Abbreviations
N/A
CNS
EYE
IMM
LUN
4.
Not Applicable
Central nervous system
Eyes
Immune system
Lung
Cardiac
Corrosive
Gastrointestinal
Irritant
Nuisance dust
FIRST AID MEASURES
Ingestion:
calm.
Inhalation:
Skin Contact:
Wash
Eye Contact:
5.
CAR
COR
GAS
IRR
NUI
Do not induce vomiting.
Keep individual
Obtain medical attention.
Remove to fresh air. Treat symptomatically.
Wipe off paste with paper towel or cloth.
exposed area with soap and water.
Flush at least 15 minutes with water. Obtain
medical attention.
FIRE FIGHTING MEASURES
Flash Point:
212°F (Base only)
Method: Tag closed
cup
Recommended
Extinguishing Agents:
Carbon dioxide, water fog, dry chemical
Hazardous Products formed
by Fire or Thermal Decomp Acetic acid, formaldehyde, silica fume,
carbon
dioxide
Unusual Fire or
Explosion Hazards:
Containers may vent, rupture, or burst at
elevated
temperatures.
Explosive Limits:
(% by volume in air)Lower
(% by volume in air)Upper
1.8%
9.5%
PERMATEX INDUSTRIAL CORPORATION
07/02/97
ROCKY HILL, CONNECTICUT 06067
TELEPHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET
Page
04 of 06
Product Name:
Item No.:
6.
Permatex(R) Blue RTV Silicone Gasket Maker
Sensor-Safe
81860
ACCIDENTAL RELEASE MEASURES
Steps to be taken in case
of spill or leak:
Maintain
Wipe and/or scrape up spilled material.
good ventilation for large spills.
Place
scrap
material in a well-ventilated place and
allow to
cure to rubber.
7.
HANDLING AND STORAGE
Safe Storage:
(Contact Loctite Customer
information)
Handling:
away
Store away from heat, spark or open flame.
Store below 120°F.
Service 1-800-243-4874 for shelf Life
Avoid prolonged breathing of vapor.
Keep
from eyes. Avoid prolonged skin contact.
Keep away from heat, sparks, or open flame.
Do not smoke while using. Wash hands after
use.
When spraying more than one half can or more
than
one can consecutively, use NIOSH/MSA
approved
respirator.
8.
EXPOSURE CONTROLS, PERSONAL PROTECTION
Eyes:
Skin:
long
Ventilation:
maintain
Safety glasses or goggles.
Rubber or plastic gloves. Long sleeves and
pants.
Provide adequate local ventilation to
vapor concentration below TLV.
Use self contained breathing apparatus when
vapor
concentration exceeds TLV.
See Section 2 for Exposure Limits.
9.
PHYSICAL AND CHEMICAL PROPERTIES
The properties listed below apply to the base material only.
Appearance:
Odor:
Boiling Point:
pH:
Solubility in Water:
Specific Gravity
Volatile Organic Compound
(EPA Method 24)
Vapor Pressure:
Vapor Density:
Blue paste
Acetic acid
None: Polymeric Material
Does not apply
Nil
1.04
9.6% ; 100 grams per liter (calculated)
66 psig
More than 1
PERMATEX INDUSTRIAL CORPORATION
07/02/97
ROCKY HILL, CONNECTICUT 06067
TELEPHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET
Page
05 of 06
Product Name:
Item No.:
Permatex(R) Blue RTV Silicone Gasket Maker
Sensor-Safe
81860
9. PHYSICAL AND CHEMICAL PROPERTIES
(continued)
Evaporation Rate
(Ether = 1)
10.
STABILITY AND REACTIVITY
Stability:
Hazardous Polymerization:
Incompatibility:
moisture.
Conditions to Avoid:
Hazardous Decomposition
Products (non-thermal):
11.
Slower than butyl acetate
Stable
Will not occur
Strong acids.
Adhesive is polymerized by contact with
Not available
Acetic acid fumes.
TOXICOLOGICAL INFORMATION
See Section 3.
12.
ECOLOGICAL INFORMATION
No data available
13.
DISPOSAL CONSIDERATIONS
Recommended methods of
disposal:
Follow EPA
Cured rubber scrap can be incinerated.
local regulations for disposal of aerosol
cans.
EPA Hazardous Waste
Number
14.
D001 - Hazardous waste per 40CFR 261.21
TRANSPORTATION INFORMATION
DOT (49 CFR 172)
Domestic Ground Transport
Proper Shipping Name:
Hazard Class or
Division:
Identification Number:
Marine Pollutant:
IATA
Proper Shipping Name:
Consumer Commodity
ORM-D
None
None
Consumer Commodity (Not more than 500 ml);
Aerosols, flammable n.o.s. (More than 500
ml)
Class or Division:
Class 9 (Not more than 500 ml);
Division 2.1 (More than 500 ml)
ID 8000 (Not more than 500 ml);
UN 1950 (More than 500 ml)
UN or ID Number:
PERMATEX INDUSTRIAL CORPORATION
07/02/97
ROCKY HILL, CONNECTICUT 06067
TELEPHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET
Page
06 of 06
Product Name:
Item No.:
15.
Permatex(R) Blue RTV Silicone Gasket Maker
Sensor-Safe
81860
REGULATORY INFORMATION
CA Proposition 65:
No Prop65 chemicals are known to be present.
16.
OTHER INFORMATION
Estimated NFPA(R) Code:
Health Hazard:
Fire Hazard:
Reactivity Hazard:
Specific Hazard:
1
Sealant: 1; Propellant: 4
0
Does not apply
Estimated HMIS(R) Code:
Health Hazard:
Flammability Hazard:
Reactivity Hazards:
Personal Protection:
1
Sealant: 1; Propellant: 4
0
See Section 8.
NFPA is a registered
trademark of the National Fire Protection
HMIS is a registered
trademark of the National Paint and Coatings
Assn.
Assn.
Prepared By:
Title:
Company:
06067
(24hr.) Phone:
Revision Date:
Stephen Repetto
Research Chemist, Health and Safety
Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT
(860) 571-5100
January 22, 1996
Revision: 0005