http://hazard.com/msds/mf/perm/files/80001.TXT PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 01 of 05 Form-A-Gasket(R) #1 Sealant 80001 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: Item No.: Part No.: Product Type: 2. Form-A-Gasket(R) #1 Sealant 80001 1A Sealant COMPOSITION, INFORMATION ON INGREDIENTS Ingredients CAS No. Clay Rosin ISOPROPYL ALCOHOL Vegetable oil Soybean derivative IRON OXIDE 1332-58-7 8050-09-7 67-63-0 68187-84-8 8002-43-5 1309-37-1 Ingredients which have % 50-55 20-25 10-15 5-10 1-3 0.1-0.5 exposure limits Exposure Limits (TWA) Ingredients ACGIH (TLV) OSHA (PEL) Clay 2 mg/m3 dust ISOPROPYL ALCOHOL IRON OXIDE 400 ppm TWA 983 mg/m3 5 mg/M3 (Fe) 10 mg/m3 dust None 5 mg/m3 respir. 400 ppm TWA None 980 mg/m3 10 mg/M3 (Fe) None particulate Exposure Limits (STEL) Ingredients ACGIH (TLV) OSHA (PEL) ISOPROPYL ALCOHOL 500 ppm 1230 mg/m3 500 ppm 1225 mg/m3 3. HAZARDS IDENTIFICATION Toxicity: (estimated) Eye irritant. Oral LD50 greater than 5000 mg/kg OTHER Primary Routes of Entry: Signs and symptoms of Exposure: Inhalation, ingestion, contact. Vapor above TLV is irritating to eyes, nose, throat and can cause headache, dizziness, and nausea. Existing Conditions Aggravated by Exposure: Skin, eye, and respiratory disorders. PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 02 of 05 Product Name: Item No.: Form-A-Gasket(R) #1 Sealant 80001 3. HAZARDS IDENTIFICATION (continued) Literature Referenced Carcinogen Ingredients IARC OSHA Target Organ and Other Health Effects NTP Clay AC4 NUI NO NO NO Rosin ACS ALG IRR RES NO NO NO ISOPROPYL ALCOHOL ALG CNS IRR NO N/A NO Vegetable oil No Data NO NO NO Soybean derivative No Data NO NO NO IRON OXIDE AC4 ALG LUN NO N/A NO -----------------------------------------------------------------------------Abbreviations N/A AC4 CNS LUN RES Not Applicable ACS ACGIH sensitizer ACGIH-Unclassifiable as human carc. ALG Allergen Central nervous system IRR Irritant Lung NUI Nuisance dust Respiratory 4. FIRST AID MEASURES Ingestion: calm. Do not induce vomiting. Keep individual Obtain medical attention. Remove to fresh air. If symptoms persist, Inhalation: obtain medical attention. Wash with soap and water. Flush at least 15 minutes with water. Skin Contact: Eye Contact: Obtain medical attention. 5. FIRE FIGHTING MEASURES Flash Point: Does not apply Per ASTM D 4359 this product is a solid. Recommended Extinguishing Agents: Carbon dioxide, foam, dry chemical Hazardous Products formed by Fire or Thermal Decomp Aliphatic aldehydes, carboxylic acids, oxides of carbon. Unusual Fire or Explosion Hazards: None Explosive Limits: (% by volume in air)Lower (% by volume in air)Upper 2% 12% PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET 03 of 05 Product Name: Item No.: 6. Form-A-Gasket(R) #1 Sealant 80001 ACCIDENTAL RELEASE MEASURES Steps to be taken in case of spill or leak: adequate ven- Remove sources of ignition. Maintain Page tilation. Scrape up as much as possible and store in a closed container until disposal. Residues may be cleaned up with isopropyl alcohol. 7. HANDLING AND STORAGE Safe Storage: (Contact Loctite Customer information) Handling: away Store away from heat and flame. Service 1-800-243-4874 for shelf Life Avoid prolonged breathing of vapors. Keep from eyes. Avoid prolonged skin contact. 8. EXPOSURE CONTROLS, PERSONAL PROTECTION Eyes: Skin: Ventilation: Safety glasses or goggles. Rubber or plastic gloves. Must be adequate to avoid exceeding TLV. See Section 2 for Exposure Limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Odor: Boiling Point: pH: Solubility in Water: Specific Gravity Volatile Organic Compound (EPA Method 24) Vapor Pressure: Vapor Density: Evaporation Rate (Ether = 1) 10. Red-Brown Paste Alcoholic 180°F Does not apply Partial 1.5 at 77°F 15.4%; 231 grams per liter 33 mm at 68°F 2.07 7.7 STABILITY AND REACTIVITY Stability: Hazardous Polymerization: Incompatibility: Conditions to Avoid: Hazardous Decomposition Products (non-thermal): Stable Will not occur Strong oxidizers Not available None PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 04 of 05 Product Name: Item No.: 11. Form-A-Gasket(R) #1 Sealant 80001 TOXICOLOGICAL INFORMATION See Section 3. 12. ECOLOGICAL INFORMATION No data available 13. DISPOSAL CONSIDERATIONS Recommended methods of disposal: regulations. EPA Hazardous Waste Number 14. Unrestricted Unrestricted None None Unrestricted Unrestricted None REGULATORY INFORMATION CA Proposition 65: 16. NH - Not a RCRA Hazardous Waste Material TRANSPORTATION INFORMATION DOT (49 CFR 172) Domestic Ground Transport Proper Shipping Name: Hazard Class or Division: Identification Number: Marine Pollutant: IATA Proper Shipping Name: Class or Division: UN or ID Number: 15. Incinerate following EPA and local No Prop65 chemicals are known to be present. OTHER INFORMATION Estimated NFPA(R) Code: Health Hazard: Fire Hazard: Reactivity Hazard: Specific Hazard: 2 2 0 Does not apply Estimated HMIS(R) Code: Health Hazard: Flammability Hazard: Reactivity Hazards: 2 2 0 Personal Protection: See Section 8. NFPA is a registered trademark of the National Fire Protection HMIS is a registered trademark of the National Paint and Coatings Assn. Assn. PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 05 of 05 Product Name: Item No.: Form-A-Gasket(R) #1 Sealant 80001 16. OTHER INFORMATION (continued) Prepared By: Title: Safety Company: 06067 (24hr.) Phone: Revision Date: Stephen Repetto Research Chemist, Environmental Health & Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT (860) 571-5100 April 23, 1997 Revision: 0037