Chapter 3 A property matter Worksheet 3.2 What features of particles give matter different properties? To be able to understand the properties of many different materials we need to be able to visualise their structure. As atoms and molecules are extremely small we often create models with familiar objects to help with the visualisation process. Making models of metals Collect a small, empty cardboard box or metal tray. Fill it with ping pong balls or marbles. Now pour a layer of sand over the marbles. This is your model of a metal. The marbles represent metal ions. The sand represents the ‘sea’ of delocalised electrons. Notice how the sea is free to flow and slide over the metal ions. The table below explains some properties of metals in terms of this structure. Property Explanation Metals are shiny The mobile electrons in the ‘sea’ reflect most of the light Metals conduct electricity The mobile electrons transfer the current (a flow of electrons) through the metal Metals are ductile The marbles and the sand can be easily accommodated in a much narrower tray, showing that the metal can be easily shaped into a wire Two other properties of metals are that they are malleable and good conductors of heat. 1 Use your model to help you to explain these properties. Many metals are mixed with other metals to improve their properties. The mixtures of metals are called alloys. Brass, for example, is an alloy of copper and zinc. 2 How could you modify your model of a metal to represent an alloy? Oxford Big Ideas Science 3 ISBN 978 0 19 556453 2 © Oxford University Press Australia 3 Do you think the model that you have created is useful for demonstrating the structure of a metal lattice? What are the limitations of the model? 4 Can you think of a different way of making a model of a metal – perhaps using different materials? Using models to explain what happens when atoms of non-metals meet: Jelly jube molecules For this activity you will need a packet of jelly jubes or fruit pastilles and a packet of toothpicks. Sort the jelly jubes into different colours and sizes. Create a table like the one below to identify the atom represented by each jelly jube. Description of jelly jube Atom represented Symbol Small, red oxygen O Large black carbon C small white hydrogen H Small yellow sulfur S Large green Chlorine Cl Jelly jube molecules (a group of two or more atoms held together by bonds) are made up of jube atoms linked by toothpicks that represent bonds (forces that link atoms together). Oxford Big Ideas Science 3 ISBN 978 0 19 556453 2 © Oxford University Press Australia 5 Use the jubes and the toothpicks to make models of the molecules listed in the table below and then draw a diagram to show how the atoms are arranged. Molecule Chemical formula Hydrogen gas H2 Sketch of the model Shell diagram O2 Oxygen gas Water H2O Hydrogen sulfide H2S Methane CH4 Carbon Dioxide CO2 Oxford Big Ideas Science 3 ISBN 978 0 19 556453 2 © Oxford University Press Australia You may find that there are several different ways that you could create the molecule. Work through the activity Shapes of Simple Molecules Part 1 to learn about how atoms are arranged. A covalent bond is a strong bond between two non-metal atoms. It consists of a shared pair of electrons. A covalent bond can be represented by a straight line or dot-and-cross diagram. Use this website to learn more about covalent bonds: http://www.bbc.co.uk/schools/gcsebitesize/science/add_aqa/atomic/covalentrev1.shtml Try the Test Bite at the end of the section on covalent bonding. 6 Why does an oxygen molecule contain a double bond? 7 How many bonds can a nitrogen atom make? What are the properties of molecular substances? Simple molecular substances. Many common substances consist of small molecules which are held together by covalent bonds. The bonds which hold the atoms in the molecules are strong but the bonds between molecules are weak. The substances melt and boil at low temperatures. Many are gases or liquids at room temperature. Examples are oxygen, methane, carbon dioxide, sulphur, nitrogen Giant molecules Some substances are continuous structures of atoms that are covalently linked together. Diamond and graphite are examples of these. Both of these substances contain only carbon atoms but the atoms are arranged differently so the substances behave quite differently. Use the jelly jubes and toothpicks to make a model of the structure of diamond, and one of the structure of graphite. You will need to have a lot of jubes the same colour to represent the carbon atoms. More information on diamond and graphite can be found at this website: http://www.dynamicscience.com.au/tester/solutions/chemistry/bonding/UntitledFrameset-2.html Choose ‘Covalent-3D-network lattice diamond from the left hand menu. 8 Do the jelly jube models help you to understand how atoms are arranged and bonded in covalent molecules? Oxford Big Ideas Science 3 ISBN 978 0 19 556453 2 © Oxford University Press Australia 9 Name one advantage of using jelly jubes to make models in this way. 10 Name one disadvantage of using jelly jubes to make these models. 11 Carbon forms many different carbon compounds. How many electrons does a carbon atom need to have a full valence shell? 12 Draw electron dot diagrams to show how the carbon atoms are sharing electrons in the diamond structure. Compare this with the arrangements in the graphite structure. 13 Watch the animation at this site to see the process of diamond sublimation: http://www.dynamicscience.com.au/tester/solutions/chemistry/bonding/bonding10c.htm Why does it require such a high temperature for this to happen? Oxford Big Ideas Science 3 ISBN 978 0 19 556453 2 © Oxford University Press Australia 14 Read the information about of the substances listed in the table and decide which one is a metal, which one is an ionic compound and which one is a covalent compound. Give reasons for your answer. Substance Description of substance at room temperature Conducts electricity as a solid? Dissolves in water? Melting point X Yellow solid No Yes 119 Y Silvery solid Yes No 98 Z White crystals No Yes 772 (°C) 15 Match the following words with their meanings: Word or phrase Meaning covalent Made up of ions, which are charged particles metallic bonding A mixture of two or more metals conductivity Able to move around ionic An array of positive metal ions in a sea of electrons valence electrons Covalent bonds between the atoms extend in all directions. alloy The ability of a substance to conduct electricity property A very large molecule consisting of many smaller structural units linked together. molecule Outermost electrons of an atom network A characteristic of a substance mobile A group of at least two atoms in a definite arrangement held together by very strong (covalent) chemical bonds. macromolecule Shared between Oxford Big Ideas Science 3 ISBN 978 0 19 556453 2 © Oxford University Press Australia