MACROMOLECULES MODELING STRUCTURES FROM NMR DATA Peter R. Seidl1,2, Erika C.A.N.Chrisman1, Príscila O. Menechini3, Katia Z. Leal2, Sonia M.C. de Menezes4 1 Departamento de Processos Orgânicos, Escola de Química, Universidade Federal do Rio de Janeiro, Rio de Janeiro, RJ, Brazil, 2Programa de Pós-graduação em Química Orgânica, Instituto de Química, Universidade Federal Fluminense, Niterói, RJ, Brazil, 3 Departamento de Engenharia Química, Universidade Federal Rural do Rio de Janeiro, Seropédica, RJ, 4CENPES, PETROBRÁS, Rio de Janeiro, RJ, Brazil The complexity of chemical entities that make up petroleum fractions poses a serious problem for the identification of structural features that are used for modeling their properties. A wide variety of analytical techniques has been applied to the asphaltene constituents of different types of petroleum for this purpose. In the case of interactions that lead to the aggregation of asphaltene molecules, it is of fundamental importance to characterize the aromatic ring systems and locate the positions to which saturated rings and chains are attached. NMR spectroscopy provides this type of information. Selective excitation techniques can be used to identify different types of aromatic and aliphatic carbons and hydrogens and their relative proportion may be obtained by integration of certain regions of the spectrum. The carbon-hydrogen ratio obtained from elemental analysis can then be used to obtain the degree of unsaturation. From this data and starting from a minimum of three aromatic rings and the corresponding number of naphtenic rings, different types of aromatic carbons are calculated and this data is used to generate the possible asphaltene structures. Finally, the structure that best fits the NMR data is chosen among the possible structures.