SAFETY DATA SHEET
(acc. to Regulation (EC) no. 1907/2006 of the European Parliament and of the Council)
Date of issue: 19 November 2007
Revision: 2 (previous version dated 20 November 2002)
Product name:
Page: 1 of 7
ALTO ANTI-STONE
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
1.1 Identification of the substance/preparation
Name:
ALTO ANTI-STONE
Other names:
ANTI-STONE, ANTI-STONE SET, KALKSCHUTZKONZENTRAT
1.2 Use of the substance/preparation
Intended or recommended use of the
To be used for high-pressure cleaners, boilers, vessels, piping.
substance/preparation:
Description of the substance/
Neutral preparation preventing precipitation of calcareous salts.
preparation function:
1.3 Company/undertaking identification
Name or trade name of the manufacturer:
Registered office/place of business:
Identification no:
Telephone:
Fax:
Informing department:
Name or trade name of the distributor:
Registered office/place of business:
Identification no:
Telephone:
Fax :
Name or trade name of the competent person
responsible for the Safety Data Sheet elaboration:
Registered office/place of business:
Telephone/fax:
Email:
Nilfisk-ALTO
Industrivej 1,
9560 Hadsund
Denmark
0045 72182211
Department cleaning and care agents
EKOLINE, s.r.o. Brno
Hviezdoslavova 29, 627 00 Brno, CZ
+420 545 218 716, 545 218 707
ekoline@ekoline.cz
1.4 Emergency telephone
Tel: +45 72 182211
2. HAZARDS IDENTIFICATION
2.1 Overall classification of the substance/preparation
C; R 34
R 43
The preparation is classified as dangerous according to Directives 67/548/EEC and 1999/45/EC.
2.2 Adverse human health and environmental effects
The preparation causes burns. It may cause sensitisation by skin contact.
2.3 Other possible hazards
Use only in compliance with manufacturer’s instructions and conditions according to this SDS.
2.4 Information shown on the label – see Section 15
3. COMPOSITION/INFORMATION ON INGREDIENTS
3.1 General description
Aqueous solution containing sodium polyacrylate (< 5%) and the below given substances.
3.2 The preparation contains dangerous ingredients
Ingredient name
Content (%) CAS number ES number
[[(2-hydroxyethyl)imino]bis
6
5995-42-6
227-833-4
(methylene)]bisphosphonic acid
© EKOLINE s.r.o., Brno
Classification; R-phrases
C; R 34
SAFETY DATA SHEET
(acc. to Regulation (EC) no. 1907/2006 of the European Parliament and of the Council)
Date of issue: 19 November 2007
Revision: 2 (previous version dated 20 November 2002)
Product name:
Page: 2 of 7
ALTO ANTI-STONE
Sodium hydroxide
<3
1310-73-2
215-185-5
Hydrogen chloride
< 0.4
---
231-595-7
Phosphorous acid
< 0.1
10294-56-1
233-663-1
Orthophosphoric acid
< 0.1
7664-38-2
231-633-2
Magnesium nitrate
< 0.02
10377-60-3
233-826-7
Mixture of: 5-chloro-2-methyl-4isothiazolin-3-one [EC no. 247< 0.015
55965-84-9
500-7] and 2-methyl-2H-isothiazol
-3-one [EC no. 220-239-6] (3:1)
Note: Full wording of R-phrases is listed in Section 16.
Exposure limit values, if specified, are listed in Section 8.1.
---
C; R 35
C; R 34
Xi; R 37
Xn; R 22
C; R 35
C; R 34
O; R 8
Xi; R 36/38
T; R 23/24/25
C; R 34
R 43
N; R 50/53
4. FIRST AID MEASURES
4.1 General instructions
Never give anything by mouth to an unconscious person. Place the unconscious person into a recovery position
and seek medical help.
4.2 Inhalation
Move the affected person to fresh air and keep warm and at rest. If irregular breathing occurs, use an oxygen
mask (to be carried out by trained personnel only). If breathing stoppage occurs, apply artificial respiration and
seek medical help.
4.3 Skin contact
Take off contaminated clothing and wash the affected area thoroughly with a large quantity of water, and seek
medical help.
4.4 Eye contact
Holding eyelids apart, start immediately rinsing with running potable water for at least 15 minutes. Seek medical
help immediately.
4.5 Ingestion
Give 1-2 glasses of water to drink. DO NOT INDUCE vomiting! Seek medical help immediately.
4.6 Other information
Data not provided.
5. FIRE-FIGHTING MEASURES
5.1 Suitable extinguishing media
Powder, carbon dioxide, foam.
5.2 Unsuitable extinguishing media
Direct water jet.
5.3 Special exposure hazards
Hazardous gases and vapours (oxides of carbon and nitrogen, traces of hydrogen chloride) are released in fire.
5.4 Special protective equipment for fire-fighters
Self-contained breathing apparatus.
5.5 Other information
Prevent the extinguishing media used from entering sewerage and water sources. Cool containers placed in the
vicinity of fire with water spray.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions
Provide sufficient ventilation of the area. Use personal protective equipment – see Section 8.
© EKOLINE s.r.o., Brno
SAFETY DATA SHEET
(acc. to Regulation (EC) no. 1907/2006 of the European Parliament and of the Council)
Date of issue: 19 November 2007
Revision: 2 (previous version dated 20 November 2002)
Product name:
Page: 3 of 7
ALTO ANTI-STONE
6.2 Environmental precautions
Prevent the preparation from entering sewerage and water sources. If such a release occurs, inform competent
authorities.
6.3 Recommended methods of cleaning up and disposal
Contain large quantities of the preparation with a sand/soil dyke, pump the preparation into suitable containers.
For small quantities use inert materials (sand, soil, binders), and place contaminated material into containers for
hazardous waste. Then wash the contaminated area with water.
For disposal of the waste see Section 13.
Note: See Section 8 for personal protective equipment and Section 13 for waste disposal.
7. HANDLING AND STORAGE
7.1 Handling
At work, use personal protective equipment specified in Section 8. Prevent contact with skin and eyes. Do not
inhale vapours. Provide sufficient ventilation. Handle the preparation according to written rules on safety,
protection of human health and the environment (see §44a of Act no. 356/2003 Coll.).
7.2 Storage
Store in original packaging in sealed vessels, in dry, cold and well ventilated places, at 0-40°C.
Keep separately from oxidising agents, strong alkalis and strong acids, as well as from food, drinks and feeds.
7.3 Specific use(s) of end products
Not required.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Exposure limit values
Czech Republic:
Control parameters of preparation ingredients are specified in Decree no. 178/2001 Coll., as amended.
Substance
CAS
PEL/NPK-P
Notes
ppm conversion
(mg/m3)
factor
Orthophosphoric acid
7664-38-2
1/2
--Sodium hydroxide
1310-73-2
1/2
--The manufacturer states:
Mixture: 5-chloro-2-methyl-2H-isothiazolin-3-one and 2-methyl-2H-isothiazol-3-one (3:1) – TWA 0.076mg/m3,
CMI
Limit values of biological exposure tests indicators for the preparation are not given specified in Decree no.
432/2003 Coll.
EU:
Exposure limit values according to Directive 2000/39/EC
8 hours
CAS
Substance name
mg/m3
ppm
7664-38-2
Orthophosphoric acid
1
--
Short time
mg/m3
ppm
2
--
Note
--
8.2 Exposure controls
Provide adequate ventilation. Ensure that only personnel using personal protective equipment handle the
preparation. Contaminated work clothing may be reused only after being thoroughly cleaned. Wash hands and
face thoroughly with soap and water after finishing work. Do not eat, drink or smoke at work.
Provide an emergency shower and eyewash in the workplace.
© EKOLINE s.r.o., Brno
SAFETY DATA SHEET
(acc. to Regulation (EC) no. 1907/2006 of the European Parliament and of the Council)
Date of issue: 19 November 2007
Revision: 2 (previous version dated 20 November 2002)
Product name:
Page: 4 of 7
ALTO ANTI-STONE
8.2.1 Occupational exposure controls
Respirator with organic vapours filter in the case of long-term exposure or the
Respiratory protection:
generation of vapours.
Tight protective goggles.
Eye protection:
Protective gloves resistant to caustic agents.
Hand protection:
Work clothing and closed footwear.
Skin protection:
Czech Republic: Personnel responsible for occupational safety of employees shall determine a method for
monitoring the substance content in the workplace atmosphere and specification of protective equipment
according to Government Decree no. 178/2001 Coll., as amended.
8.2.2 Environmental exposure controls
Czech Republic: See Act no. 86/2002 Coll., on the atmosphere protection; Act no. 254/2001 Coll., on waters.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 General information
Physical state (at °C):
Colour:
Odour:
Liquid
Colourless
Odourless
9.2 Important healt, safety and environmental information
pH (at °C):
7.0 (100%), 6.9-7.5 (1% aqueous solution)
Boiling point/boiling range (°C):
Data not provided
Flash point (°C):
Data not provided
Flammability:
Data not provided
Explosive properties:
Data not provided
Explosive limits: upper limit (% vol.): Data not provided
lower limit (% vol.):
Data not provided
Oxidising properties:
Data not provided
Vapour pressure (at °C):
Data not provided
Relative density (at °C):
1.065 – 1.075g/cm3
Solubility (at °C):
Data not provided
Water solubility (at °C):
Soluble
Partition coefficient n-octanol/water:
Data not provided
Viscosity:
Data not provided
Vapour density:
Data not provided
Evaporation rate:
Data not provided
9.3 Other information:
Data not provided
10. STABILITY AND REACTIVITY
Stable under normal usage and storage conditions.
10.1 Conditions to avoid
Not known.
10.2 Materials to avoid
Oxidising and reducing agents.
10.3 Hazardous decomposition products
Hazardous gases and vapours (hydrogen chloride traces) are released in fire.
11. TOXICOLOGICAL INFORMATION
11.1 Description of exposure symptoms
Inhalation
corrosive effects for mucous membranes.
Skin contact
burning and corrosive effects.
Eye contact
severe burns and corrosive effects as well as irreversible damage.
Ingestion
corrosive substance, may cause severe and permanent damage to mouth, throat and stomach.
© EKOLINE s.r.o., Brno
SAFETY DATA SHEET
(acc. to Regulation (EC) no. 1907/2006 of the European Parliament and of the Council)
Date of issue: 19 November 2007
Revision: 2 (previous version dated 20 November 2002)
Product name:
Page: 5 of 7
ALTO ANTI-STONE
11.2 Dangerous-to-health effects
Acute toxicity
- LD50 ,oral, rat (mg/kg):
- LD50, dermal, rat or rabbit (mg/kg):
- LC50, inhalatory, rat (mg/L):
325 (sodium hydroxide)
>2,000 (sodium polyacrylate)
Data not provided
Data not provided
Sub-chronic - chronic toxicity
Data not provided.
Sensitisation
Data not provided.
Carcinogenity
The preparation and substances are not listed in NTP, IARC and ACGIH inventories.
Mutagenicity
Data not provided.
Toxicity for reproduction
Data not provided.
12. ECOLOGICAL INFORMATION
12.1 Ecotoxicity
- LC50, 96 hrs., fish (mg/L):
- EC50, 48 hrs., daphnia (mg/L):
- IC50, 72 hrs., algae (mg/L):
145 Poecilia reticulata (sodium hydroxide)
76 Daphnia magna (sodium hydroxide)
22 (15min.) Photobacterium phosphoreum (sodium hydroxide)
12.2 Mobility
Data not provided.
12.3 Persistence and degradability
Data not provided.
12.4 Bioaccumulative potential
Data not provided.
12.5 Results of PBT assessment
Data not provided.
12.6 Other adverse effects
Data not provided.
13. DISPOSAL CONSIDERATION
13.1 Possible danger resulting from the substance/preparation disposal
According to the Waste Catalogue the product is dangerous waste.
European Waste Catalogue (EWC):
The user should assign the waste codes according to the product application used.
Waste code:
15 01 10* Packaging containing remains of hazardous substances or packaging contaminated with such
substances
15 02 02* Absorbing agents, filer materials, cleaning textiles and protective clothing contaminated with
hazardous substances
13.2 Suitable methods for the substance/preparation and contaminated packaging disposal
Hand over labelled waste, including its identification sheet, for disposal to a specialised company authorised to
carry out such activities.
© EKOLINE s.r.o., Brno
SAFETY DATA SHEET
(acc. to Regulation (EC) no. 1907/2006 of the European Parliament and of the Council)
Date of issue: 19 November 2007
Revision: 2 (previous version dated 20 November 2002)
Product name:
Page: 6 of 7
ALTO ANTI-STONE
13.3 Legal regulations relating to waste
Czech Republic: Act no. 185/2001 Coll., on waste, as amended. Should this preparation and its packaging
become waste, the end user must assign appropriate waste code in compliance with Decree no. 381/2001 Coll., as
amended. Act no. 477/2001 Coll., on packaging, as amended.
Disposal must be made according to official regulations.
14. TRANSPORT INFORMATION
14.1 Road transport (acc. to the European Agreement on the international transport of dangerous
goods (ADR), passed under no. 64/1987 Coll., as amended)
ADR/RID:
Class:
8
Classification code:
C9
Packing group:
II
Safety mark:
8
Hazard identification number
80
UN number, proper shipping name: 1760 CORROSIVE LIQUID, N.O.S. (Sodium hydroxide)
Note:
Transport conditions are defined, inter alia, by the European Agreement on
the international transport of dangerous goods by road (ADR) for particular
UN number.
14.2 Sea transport
IMDG:
Class:
UN number:
Packing group:
Marine pollutant:
Technical name:
8
1760
II
CORROSIVE LIQUID, N.O.S. (hydrochloric acid)
14.3 Air transport
ICAO/IATA:
Class:
UN number:
Packing group:
Technical name:
Notes:
8
1760
II
CORROSIVE LIQUID, N.O.S. (hydrochloric acid)
15. REGULATORY INFORMATION
15.1 Information shown on the label (acc. to Directives 67/548/EEC and 1999/45/EC)
ANTI-STONE
Contains:
Sodium hydroxide, mixture of: 5-chloro-2-methylisothiazol-3(2H)one and 2-methylisothiazol-3(2H)-one (3:1)
R 34 Causes burns.
R 43 May cause sensitisation by skin contact.
S 23
S 24
S 26
Do not breathe vapours/aerosols.
Avoid contact with skin.
In case of contact with eyes, rinse immediately with plenty of water and seek
Corrosive
medical advice.
S 28 After contact with skin, wash immediately with plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S 45 In case of accident or if you feel unwell, seek medical advice immediately (show
the label where possible).
Manufacturer: Nilfisk-ALTO, Industrivej 1, 9560 Hadsund, Denmark, Tel. 0045 72182211
© EKOLINE s.r.o., Brno
SAFETY DATA SHEET
(acc. to Regulation (EC) no. 1907/2006 of the European Parliament and of the Council)
Date of issue: 19 November 2007
Revision: 2 (previous version dated 20 November 2002)
Product name:
Page: 7 of 7
ALTO ANTI-STONE
Note:
All hazardous substances and preparations which are offered and used by the consumer must bear on their labels
the following:
S 1/2 Keep locked up and out of reach of children.
15.2 Special provisions and legal regulations at CZ level:
See §44a of Act no. 258/2000 Coll., as amended, part 8 clauses 6, 8, 9 and 10.
Packaging intended for sale to the consumer must have a palpable warning for the blind according to Act no.
356/2003 Coll., on chemical substances and chemical preparations, §19, cl. 2.
Packaging intended for sale to the consumer must have a closure preventing opening by children according to
Act no. 356/2003 Coll., on chemical substances and chemical preparations, §19, cl. 2.
15.3 Special provisions and legal regulations at EU level
Not required.
16. OTHER INFORMATION
16.1 List of R-phrases used in the Safety Data Sheet
R 8 Contact with combustible material may cause fire.
R 23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
R 22 Harmful if swallowed.
R 34 Causes burns.
R 35 Causes severe burns.
R 36/38 Irritating to eyes and skin.
R 37 Irritating to respiratory system.
R 43 May cause sensitisation by skin contact.
R 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.16.2 Training advice
Czech Republic: see Labour Code, Act no. 262/2006 Coll., as amended. Read written rules on safety, protection
of human health and the environment (see §44a of Act no. 356/2003 Coll., as amended).
16.3 Recommended restrictions of use
The substance shall not be used for any other purpose than the intended one (see Section 1.2). Since specific
conditions of the substance usage are beyond the supplier control, it is the user’s responsibility to adapt specified
notices for local laws and regulations. Safety information describes the product in terms of safety, and therefore
may not be considered to be technical information about the product.
16.4 Further information
Further information shall be provided by the Safety Data Sheet elaborator or manufacturer.
16.5 Sources of key data:
The information contained herein is based on our best knowledge and the present legislation, especially Act no.
356/2003 Coll., as amended, incl. implementary regulations, and Regulation no. 1907/2006 of the European
Parliament and of the Council (EC). Further, the Safety Data Sheet has been elaborated on the basis of the
original Safety Data Sheet provided by the manufacturer.
16.6 Changes resulting from the SDS revision
Completely reviewed (previous version dated 20 November 2002). The preparation is now classified as
dangerous according to Directives 67/548/EEC and 1999/45/EC.
© EKOLINE s.r.o., Brno