Skandian Grupp OÜ
Date of preparation: 19.03.2010
MATERIAL SAFETY DATA SHEET
Date of prior version: 01.07.2005
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKING
1.1. Identification of the substance or preparation
TAR BALM
1.2. Application of the substance or preparation
Natural protective agent for wood
1.3. Identification of the company/undertaking
Manufacturer
Skandian Grupp OÜ
Address: Kuremaa Borough, Jõgeva County, 48403 Estonia
Phone: +372 604 5626
e-mail: skandiangrupp@hot.ee
Registry code 10933572
1.4. Emergency phone number:
General emergency phone 112
Poisoning information hotline 16662
2. IDENTIFICATION OF HAZARDS
2.1 Fire and explosion hazard
Flammable
2.2 Health hazard
Xn - Harmful
Harmful in case of inhalation, skin contact and ingestion.
Irritating to eyes and skin.
May cause allergy by skin contact.
Harmful: may cause lung damage if swallowed.
2.3 Environmental hazard
Toxic to aquatic organisms; may cause long-term adverse
effects in the aquatic environment..
3. COMPOSITION / INFORMATION ON THE COMPONENTS
3.1. Overview of the composition
Preparation, mixture
3.2. Information on ingredients
EC No.
CAS No.
Name of the component
Content of the component
in preparation, %
232-350-7
8006-64-2
Pine turpentine
~ 20
232-347-8
8011-48-1
Stump tar *
~ 55
Letter code of the hazard
symbol and number
of the R-phrase
R10;Xn; R20/21/22-65; Xi;
R36/38, R43;N; R51/53
Xn; R20/21/22 – Xi; R43
*contains 44% of free and bound fatty and resinous acids, 3% phenolic compounds.
3.3. Other information
Information to be indicated on the packaging label is described in
clause 15.
MATERIAL SAFETY DATA SHEET
Tar balm
2
4. FIRST AID MEASURES
4.1 General information - Seek medical help in case of any doubt or occurrence of disease symptoms.
4.2 Inhalation
Remove the patient into fresh air. Let the patient rest in a half-sitting position, keep warm.
4.3 Skin contact
Remove contaminated clothes. Wash the skin with soap and water.
4.4 Eye contact
Rinse with plenty of water for several minutes, also under eyelids.
4.5 Ingestion
Rinse the mouth cavity with plenty of water and seek medical help.
DO NOT induce vomiting!
4.6 Information for physician or other professional administering first aid
Show the label and the material safety data sheet.
5. FIRE FIGHTING MEASURES
5.1. Suitable extinguishing materials
Dry powder, foam or carbon dioxide.
5.2. Unsuitable extinguishing materials
Never use water.
5.3. Special hazards in case of fire
Irritating and health-damaging compounds may be released during burning. Explosion hazard in case of
accumulation of vapours heavier than air.
5.4. Special protective equipment in case of fire
Compressed-air-operated protective mask, protective clothing.
5.5. Special instructions
Vessels and containers of the product located near open flame shall be cooled down with a jet of water from a
sufficient, safe distance.
6. ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions
Persons in a contaminated area shall be evacuated to the upwind part of the area. Fire and explosion risks are
eliminated by isolating the area from sources of ignition and preventing vapours from accumulating in hollows
and closed spaces.
6.2. Environmental precautions
Try to prevent the contamination from spreading and the material from entering the environment. Liquid product
shall be collected before it can spread into drains, soil and water.
6.3. Spillages
Collect as much of the material as possible into a clean container for re-use or disposal. Residues shall be
absorbed with a special oil absorber which shall be stored in a fire-proof environment (spontaneous combustion
may occur). Waste containing the product shall be disposed of in compliance with national regulations.
6.4. Other necessary information
Products containing oil may cause spontaneous combustion if absorbed in a porous material. Such residues shall
be collected and stored immersed in water until destructing or burned immediately. Contaminated cleaning
cloths and other waste shall be collected into a fireproof container. Environmental contamination shall
immediately be reported to the local rescue service (Phone No. 112). Sufficient personal protection equipment
shall be used at all work operations.MATERIAL SAFETY DATA SHEET
Tar balm
3
7. HANDLING AND STORAGE
7.1. Handling
The product shall be handled in a well-ventilated space. Use a protective mask if necessary. The liquid/vapours
are highly flammable. Prevent sparks caused by static electricity. Production shall be isolated from sources of
ignition. Smoking is prohibited!
7.2. Storage
Store at a cool, well-ventilated place (at temperatures not exceeding +30°C). Avoid direct sunlight.
8. EXPOSURE CONTROL / PERSONAL PROTECTION
8.1. Limits of exposure
8.2. Exposure control
8.2.1. Exposure control in working environment
The product shall be used in a closed system or ensuring sufficient ventilation. Do not eat, drink or smoke in the
working area. Wash hands before breaks; wash yourself with running water and soap in a shower after work. A
bottle with water for rinsing the eyes shall be kept at the workplace. Apply skin cream after work. Working
clothes should be washed with alkaline washing agents.
8.2.1.1. Respiratory protection
If the concentration of pollutants in the working area exceeds the permissible limit, a gas mask fitted with an A2
filter or a respirator with a type P2 differentiating filter shall be used.
8.2.1.2. Hand protection
Use nitrile protective gloves of a material impermeable for aromatic hydrocarbon compounds.
(Time of penetration of chemical through the glove material > 480 min.) EN 374. The gloves shall be replaced
regularly to prevent the chemical from filtering through the material.
8.2.1.3. Eye protection
Protective goggles are necessary if a respirator or half-mask is used. EN 166.
8.2.1.4. Skin protection
Use protective clothing and footwear, preferably of antistatic material.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1. General information
- Oily brown liquid
9.2. Important health, safety and environmental information
- pH
- Boiling point / boiling range
155 – 170 (90%) °C (turpentine)
- Flash point
39 °C, DIN 51755 (turpentine)
- Self-ignition temperature
ca 255°C (turpentine)
- Explosion limits
min
0.8 volume %
max
- Oxidising properties
- Vapour pressure
399 Pa (20°C alpha-pinene)
- Relative density
~ 0.845 g/cm³, 20° C (turpentine)
- Solubility
a) in water
non-soluble (turpentine)
b) in fats
non-soluble (turpentine)
- Octanol-water partition coefficient (for ingredients) - Viscosity
100-5000 mPa.s(DIN 53015, 20°C)
- Vapour density
15-20 (>250°C, 0.05 kPa)MATERIAL SAFETY
DATA SHEET
Tar balm
4
10. STABILITY AND REACTIVITY
10.1. Conditions to avoid
Avoid storing of the product in open containers. Prevent occurrence of static electricity, open flame, smoking.
Avoid working in a space without air exchange.
10.2. Materials to avoid
Keep separated from highly oxidising substances - strong alkalies and strong acids.
10.3. Hazardous decomposition products
Gases hazardous to health are released at high temperatures (burning) (thick black smoke, CO, CO2). Avoid
inhalation of the gases.
11. TOXICOLOGICAL INFORMATION
11.1. Acute toxicity
11.2. Irritating and corrosive effect
Irritating to eyes and skin.
11.3. Sensitizing properties
Contact with skin may cause allergy.
11.4. Risk of subsequent and long-term health damage
11.5 Information obtained from practical use
Harmful at inhalation, skin contact and ingestion. Repeated contact may cause skin dryness or cracking. Vapours
may cause drowsiness and dizziness. Inhalation of vapours or spray of the product may cause headache and
feeling of unwellness.
12. ECOLOGICAL INFORMATION
12.1. Ecotoxicity - Ecological information
Toxic to aquatic organisms; may cause long-term adverse effects in the aquatic environment.
LD50/96h/fish=> 198 mg/L
Bacteria: EC10 (Pseudomonas putida); 9000 mg/L
12.2 Mobility
Non-soluble in water. Product evaporates easily from ground and water surface.
12.3 Persistence and degradability
12.3.1 Biodegradation
Easily biodegradable.
12.3.2 Bioaccumulation
Low bioaccumulation but easily volatile.
12.4 Other necessary information
The product shall not be released into bodies of water, drains and soil.
EU limits for VOC content: subgroup A/e(5) - 400 g/l (2010). Maximum VOC content in product ready for use:
< 400 g/l.
13. DISPOSAL
Residual chemical and used containers shall be disposed of according to the valid legislation regulating waste
management.
The waste is regarded as paint residues containing organic solvents. The container should be cleaned well before
disposal.MATERIAL SAFETY DATA SHEET
Tar balm
5
14. TRANSPORTATION
14.1. UN number
14.2. Packaging group
14.3. Land transport
14.3.1. Hazard division of cargo / ADR class
1263
III
3
14.3.2. Hazard ID number
14.3.3. Name according to accompanying document
14.4. Sea transport
14.4.1. IMDG-code
14.4.2. Accurate technical name
14.5. Air transport
14.5.1. ICAO/IATA-code
14.5.2. Accurate technical name
33
Paint
3
Paint
3
Paint
15. OBLIGATORY INFORMATION ON THE LABEL
15.1. Information on the label
15.1.1. Hazard symbol and its meaning
Xn - Harmful
15.1.2. Names of ingredients to be indicated on the label
Tar, pine turpentine.
15.1.3. Risk phrases
R10 - Flammable.
R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed.
R36/38 - Irritating to eyes and skin.
R43 - May cause sensitization by skin contact.
R65 - Harmful: may cause lung damage if swallowed.
R52/53 - Toxic to aquatic organisms; may cause long-term adverse effects in the aquatic environment.
15.1.4. Safety phrases
S2 - Keep out of the reach of children.
S24/25 - Avoid contact with eyes and skin.
S36/37 - Wear suitable protective clothing and gloves.
S51 - Handle in a well-ventilated area.
S43 - In case of fire, use foam, powder or CO2 extinguisher. Never use water!
S61 - Avoid release to the environment. Refer to special instructions / safety data sheets.
S62 - If swallowed, do not induce vomiting; seek medical advice immediately and show the container or label.
15.2. Local (national) legislation:
In accordance with the directive 1907/2006/EEC
15.3. VOC content: EU limits of VOC content: subgroup A/e (5) - 400 g/l (2010)
Maximum VOC content in product ready for use < 400 g/l.MATERIAL SAFETY
DATA SHEET
Tar balm
6
16. OTHER INFORMATION
16.1. Purpose of use
16.1.1. Written verbal information
On the label
16.2. Instructions of use
On the label
16.3. Full text of the R-phrases indicated by numbers in clause 2
R10 - Flammable.
R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed.
R36/38 - Irritating to eyes and skin.
R43 - May cause sensitization by skin contact.
R65 - Harmful: may cause lung damage if swallowed.
R52/53 - Toxic to aquatic organisms; may cause long-term adverse effects in the aquatic environment.
16.4. Additional information is provided by
Skandian Grupp OÜ
16.5. Sources for preparation of this material safety data sheet
Material safety data sheets submitted by manufacturers of the raw materials.