Skandian Grupp OÜ
Date of preparation: 15.09.2010
MATERIAL SAFETY DATA SHEET
Date of prior version: 07.02.2005
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKING
1.1. Identification of the substance or preparation
TURPENTINE-LINSEED OIL
1.2. Application of the substance or preparation
Protective agent for wood
1.3. Identification of the company/undertaking
Manufacturer
Skandian Grupp OÜ
Address: Kuremaa Borough, Jõgeva County, 48403 Estonia
Phone: +372 604 5626
e-mail: skandiangrupp@hot.ee
Registry code 10933572
1.4. Emergency phone number:
General emergency phone 112
Poisoning information hotline 16662
2. IDENTIFICATION OF HAZARDS
2.1 Fire and explosion hazard
Flammable
2.2 Health hazard
Xn - Harmful
Harmful in case of inhalation, skin contact and ingestion.
Irritating to eyes and skin.
May cause sensitization by skin contact.
Harmful: may cause lung damage if swallowed.
2.3 Environmental hazard
N - Environmental hazard
Toxic to aquatic organisms; may cause long-term adverse
effects in the aquatic environment..
3. COMPOSITION / INFORMATION ON THE COMPONENTS
3.1. Overview of the composition
3.2. Information on ingredients
Transparent volatile liquid with a characteristic odour.
EC No.
CAS No.
Name of the component
Content of the component
in preparation, %
232-350-7
8006-64-2
Turpentine
< 25%
3.3. Other information
Letter code of the hazard
symbol and number
of the R-phrase
R10;Xn; R20/21/22-65;
Xi; R36/38; R43;N; R51/53
Information to be indicated on the packaging label is described in
clause 15.
4. FIRST AID MEASURES
4.1 General information - Seek medical help in case of any doubt or occurrence of disease
symptoms.MATERIAL SAFETY DATA SHEET
TURPENTINE-LINSEED OIL
2
4.2 Inhalation
Remove the patient into fresh air, keep warm and at rest. If necessary, administer oxygen or artificial respiration.
Seek medical help in case of more severe damage.
4.3 Skin contact
Remove contaminated clothes. Wash the skin with soap and water. Seek medical help if skin irritation persists.
4.4 Eye contact
Rinse with plenty of water for several minutes, also under eyelids. Continue rinsing for several minutes, moving
the eye into extreme positions. Contact an eye specialist (hazard of corneal damage).
4.5 Ingestion
Rinse the mouth cavity with plenty of water and seek medical help. DO NOT induce vomiting!
4.6 Information for physician or other professional administering first aid
Show the label and the material safety data sheet.
5. FIRE FIGHTING MEASURES
5.1. Suitable extinguishing materials
Dry powder, foam or carbon dioxide.
5.2. Unsuitable extinguishing materials
Never use water.
5.3. Special hazards in case of fire
Irritating and health-damaging compounds may be released during burning.
5.4. Special protective equipment in case of fire
Compressed-air-operated protective mask, protective clothing.
5.5. Special instructions
Vessels and containers of the product located near open flame shall be cooled down with a jet of water from a
sufficient, safe distance.
6. ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions
Persons in a contaminated area shall be evacuated to the upwind part of the area. Fire and explosion risks are
eliminated by isolating the area from sources of ignition and preventing vapours from accumulating in hollows
and closed spaces.
6.2. Environmental precautions
Try to prevent the contamination from spreading and the material from entering the environment. Liquid product
shall be collected before it can spread into drains, soil and water.
6.3. Spillages
Collect as much of the material as possible into a clean container for re-use or disposal. Residues shall be
absorbed with a special oil absorber which shall be stored in a fire-proof environment (spontaneous combustion
may occur). Waste containing the product shall be disposed of in compliance with national regulations.
6.4. Other necessary information
Environmental contamination shall immediately be reported to the local rescue service (Phone No. 112).
Sufficient personal protection equipment shall be used at all work operations.
7. HANDLING AND STORAGE
7.1. Handling
The product shall be handled in a well-ventilated space. Use a protective mask if necessary. The liquid/vapours
are highly flammable. Prevent sparks caused by static electricity. Production shall be isolated from sources of
ignition. Smoking is prohibited!
MATERIAL SAFETY DATA SHEET
TURPENTINE-LINSEED OIL
3
7.2. Storage
Store at a cool, well-ventilated place.
8. EXPOSURE CONTROL / PERSONAL PROTECTION
8.1. Limits of exposure
8.2. Exposure control
8.2.1. Exposure control in working environment
The product shall be used in a closed system or ensuring sufficient ventilation. Do not eat, drink or smoke in the
working area. Wash hands before breaks; wash yourself with running water and soap in a shower after work. A
bottle with water for rinsing the eyes shall be kept at the workplace. Apply skin cream after work. Working
clothes should be washed with alkaline washing agents.
8.2.1.1. Respiratory protection
Use a protective mask fitted with an A-filter if necessary.
8.2.1.2. Hand protection
Use nitrile protective gloves of a material impermeable for aromatic hydrocarbon compounds. The gloves shall
be replaced regularly to prevent the chemical from filtering through the material.
8.2.1.3. Eye protection
Protective goggles.
8.2.1.4. Skin protection
Use protective clothing and footwear, preferably of antistatic material.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1. General information
- Colourless, transparent liquid with characteristic odour
9.2. Important health, safety and environmental information
- pH
- Boiling point / boiling range
154 – 170 °C (turpentine)
- Flash point
-35°C (in closed container) (turpentine)
- Self-ignition temperature
253°C (turpentine)
- Melting point / melting range
-50 - -60°C (turpentine)
- Explosion limits
min
0.8 volume % (turpentine)
max
6.0 volume % (turpentine)
- Oxidising properties
- Vapour pressure
0.25 - 0.67 kPa (20°C)
- Relative density
~ 0.89 g/cm³
- Solubility
non-soluble in water
- Vapour density
4.7 (air=1)
10. STABILITY AND REACTIVITY
10.1. Conditions to avoid
Stable at normal temperature and pressure. Avoid storing of the product in open containers. Prevent occurrence
of static electricity, open flame, smoking. Avoid working in a space without air exchange.
10.2. Materials to avoid
Keep separated from highly oxidising substances - strong alkalies and strong acids.MATERIAL SAFETY
DATA SHEET
TURPENTINE-LINSEED OIL
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10.3. Hazardous decomposition products
Formed by slow decomposition of the product caused by air and light, oxidation products: calcium hypochlorite,
chlorine, stannous chloride, halogenes, mineral acids. Toxic smoke containing carbon monoxide is formed at
thermal decomposition.
11. TOXICOLOGICAL INFORMATION
11.1. Acute toxicity
at ingestion LD50 =5760 mg, rat (turpentine)
11.2. Irritating and corrosive effect
Irritating to eyes and skin.
11.3. Sensitizing properties
Contact with skin may cause allergy.
11.4. Risk of subsequent and long-term health damage
11.5 Information obtained from practical use
Harmful at inhalation, skin contact and ingestion.
Harmful: may cause lung damage if swallowed.
12. ECOLOGICAL INFORMATION
12.1. Ecotoxicity - Ecological information
Toxic to aquatic organisms; may cause long-term adverse effects in the aquatic environment.
LD50/96h/fish=> 198 mg/L
Bacteria: EC10 (Pseudomonas putida); 9000 mg/L
12.2 Mobility
Non-soluble in water. Product evaporates easily from ground and water surface.
12.3 Persistence and degradability
12.4 Bioaccumulation
Low bioaccumulation but easily volatile.
12.5 Other necessary information
The product shall not be released into bodies of water, drains and soil.
13. DISPOSAL
Residual chemical and used containers shall be disposed of according to the valid legislation regulating waste
management.
14. TRANSPORTATION
14.1. UN number
14.2. Packaging group
14.3. Land transport
14.3.1. Hazard division of cargo / ADR class
14.3.2. Hazard ID number
14.3.3. Name according to accompanying document
14.4. Sea transport
14.4.1. IMDG-code
14.4.2. Accurate technical name
14.5. Air transport
14.5.1. ICAO/IATA-code
14.5.2. Accurate technical name
1299
III
3
30
Turpentine
3
Turpentine
3
TurpentineMATERIAL SAFETY DATA SHEET
TURPENTINE-LINSEED OIL
15. OBLIGATORY INFORMATION ON THE LABEL
15.1. Information on the label
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15.1.1. Hazard symbol and its meaning
Xn - Harmful
N - Environmental hazard
15.1.2. Names of ingredients to be indicated on the label
Turpentine.
15.1.3. Risk phrases
R10 - Flammable.
R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed.
R36/38 - Irritating to eyes and skin.
R43 - May cause sensitization by skin contact.
R65 - Harmful: may cause lung damage if swallowed.
R51/53 - Toxic to aquatic organisms; may cause long-term adverse effects in the aquatic environment.
15.1.4. Safety phrases
S2 - Keep out of the reach of children.
S36/37 - Wear suitable protective clothing and gloves.
S46 - If swallowed, seek medical advice immediately and show the container or label.
S61 - Avoid release to the environment. Refer to special instructions / safety data sheets.
S62 - If swallowed, do not induce vomiting; seek medical advice immediately and show the container or label.
15.2. Local (national) legislation:
In accordance with the directive 1907/2006/EEC
15.3. VOC content: EU limits of VOC content: subgroup A/e(5) - 400 g/l (2010)
Maximum VOC content in product ready for use < 400 g/l.
16. OTHER INFORMATION
16.1. Purpose of use
16.1.1. Written verbal information
On the label
16.2. Instructions of use
On the label
16.3. Full text of the R-phrases indicated by numbers in clause 2
R10 - Flammable.
R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed.
R36/38 - Irritating to eyes and skin.
R43 - May cause sensitisation by skin contact.
R65 - Harmful: may cause lung damage if swallowed.
R51/53 - Toxic to aquatic organisms; may cause long-term adverse effects in the aquatic environment.
16.4. Additional information is provided by
Skandian Grupp OÜ
16.5. Sources for preparation of this material safety data sheet
Material safety data sheets submitted by manufacturers of the raw materials.