Skandian Grupp OÜ Date of preparation: 15.09.2010 MATERIAL SAFETY DATA SHEET Date of prior version: 07.02.2005 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKING 1.1. Identification of the substance or preparation PINE RESIN TURPENTINE 1.2. Application of the substance or preparation thinner 1.3. Identification of the company/undertaking Manufacturer Skandian Grupp OÜ Address: Kuremaa Borough, Jõgeva County, 48403 Estonia Phone: +372 604 5626 e-mail: skandiangrupp@hot.ee Registry code 10933572 1.4. Emergency phone number: General emergency phone 112 Poisoning information hotline 16662 2. IDENTIFICATION OF HAZARDS 2.1 Fire and explosion hazard Flammable 2.2 Health hazard Xn - Harmful Harmful by inhalation, skin contact and if swallowed. Irritating to eyes and skin. May cause sensitization by skin contact. Harmful: may cause lung damage by ingestion. 2.3 Environmental hazard N - Environmental hazard Toxic to aquatic organisms; may cause long-term adverse effects in the aquatic environment. 3. COMPOSITION / INFORMATION ON THE COMPONENTS 3.1. Overview of the composition 3.2. Information on ingredients Transparent volatile liquid with a characteristic odour. EC No. CAS No. Name of the component Content of the component in preparation, % 232-350-7 8006-64-2 Turpentine 100% 3.3. Other information Letter code of the hazard symbol and number of the R-phrase R10;Xn; R20/21/22-65; Xi; R36/38; R43;N; R51/53 Information to be indicated on the packaging label is described in clause 15. 4. FIRST AID MEASURES 4.1 General information - Seek medical help in case of any doubt or occurrence of disease symptoms.MATERIAL SAFETY DATA SHEET Pine resin turpentine 2 4.2 Inhalation In case of inhalation of vapours, remove the patient into fresh air, keep warm and at rest. If necessary, administer oxygen or artificial respiration. Seek medical help in case of more severe damage. 4.3 Skin contact Remove contaminated clothes. Wash the skin with soap and water. Seek medical help if skin irritation persists. 4.4 Eye contact Rinse with plenty of water for several minutes, also under eyelids. Continue to rinse for several minutes, moving the eye into extreme positions. Contact an eye specialist (hazard of corneal damage). 4.5 Ingestion Rinse the mouth cavity with plenty of water and seek medical help. DO NOT induce vomiting! 4.6 Information for physician or other professional administering first aid Show the label and the material safety data sheet. 5. FIRE FIGHTING MEASURES 5.1. Suitable extinguishing materials Dry powder, foam or carbon dioxide. 5.2. Unsuitable extinguishing materials Never use water. 5.3. Special hazards in case of fire Irritating and harmful compounds may be released during burning. 5.4. Special protective equipment in case of fire Compressed-air-operated protective mask, protective clothing. 5.5. Special instructions Vessels and containers of the product located near open flame shall be cooled down with a jet of water from a sufficient, safe distance. 6. ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions Persons in a contaminated area shall be evacuated to the upwind part of the area. Fire and explosion risks are eliminated by isolating the area from sources of ignition and preventing vapours from accumulating in hollows and closed spaces. 6.2. Environmental precautions Try to prevent the contamination from spreading and the material from entering the environment. Liquid product shall be collected before it can spread into drains, soil and water. 6.3. Spillages Collect as much of the material as possible into a clean container for re-use or disposal. Residues shall be absorbed with a special oil absorber which shall be stored in a fire-proof environment (spontaneous combustion may occur). Waste containing the product shall be disposed of in compliance with national regulations. 6.4. Other necessary information Environmental contamination shall immediately be reported to the local rescue service (Phone No. 112). Sufficient personal protection equipment shall be used at all work operations. 7. HANDLING AND STORAGE 7.1. Handling The product shall be handled in a well-ventilated space. Use a protective mask if necessary. The liquid/vapours are highly flammable. Prevent sparks caused by static electricity. Production shall be isolated from sources of ignition. Smoking is prohibited!MATERIAL SAFETY DATA SHEET Pine resin turpentine 3 7.2. Storage Store at a cool, well-ventilated place. 8. EXPOSURE CONTROL / PERSONAL PROTECTION 8.1. Limits of exposure 8.2. Exposure control 8.2.1. Exposure control in working environment The product shall be used in a closed system or ensuring sufficient ventilation. Do not eat, drink or smoke in the working area. Wash hands before breaks; wash yourself with running water and soap in a shower after work. A bottle with water for rinsing the eyes shall be kept at the workplace. Apply skin cream after work. Working clothes should be washed with alkaline washing agents. 8.2.1.1. Respiratory protection If necessary, use a protective mask fitted with an A filter. 8.2.1.2. Hand protection Use nitrile protective gloves of a material impermeable for aromatic hydrocarbon compounds. Protective gloves shall be replaced regularly to prevent the chemical from filtering through the material. 8.2.1.3. Eye protection Protective goggles. 8.2.1.4. Skin protection Use protective clothing and footwear, preferably of antistatic material. 9. PHYSICAL AND CHEMICAL PROPERTIES 9.1. General information - colourless, transparent liquid with a characteristic odour 9.2. Important health, safety and environmental information - pH N/A - Boiling point / boiling range 154 – 170°C - Flash point -35 °C (in a sealed container) - Self-ignition temperature 253°C - melting point / melting range -50 - -60°C - Explosion limits min 0.8 volume % max 6.0 volume % - Oxidising properties - Vapour pressure 0.25 – 0.67 kPa (20°C) - Relative density ~ 0.87 g/cm³ - Solubility non-soluble in water - Vapour density 4,7 (air = 1) 10. STABILITY AND REACTIVITY 10.1. Conditions to avoid Stable at normal temperature and pressure. Avoid storing of the product in open containers. Prevent occurrence of static electricity, open flame, smoking. Avoid working in a space without air exchange.MATERIAL SAFETY DATA SHEET Pine resin turpentine 4 10.2. Materials to avoid Keep separated from highly oxidising substances - strong alkalies and strong acids. 10.3. Hazardous decomposition products Formed at slow degradation of the substance caused by air and light. Oxidation products: oxidants, calcium hypochlorit, chlorine, stanneous chloride, halogenes, mineral acids. Toxic smoke containing carbon monoxide is released at thermal degradation. 11. TOXICOLOGICAL INFORMATION 11.1. Acute toxicity at ingestion: LD50 =5760 mg, rat 11.2. Irritating and corrosive effect Irritating to eyes and skin. 11.3. Sensitising properties Skin contact may cause allergy. 11.4. Risk of subsequent and long-term health damage 11.5 Information obtained from practical use Harmful at inhalation, skin contact and if swallowed. Harmful: may cause lung damage at ingestion. 12. ECOLOGICAL INFORMATION 12.1 Ecotoxicity - Ecological information Toxic to aquatic organisms; may cause long-term adverse effects in the aquatic environment. LD50/96h, fish = 198 mg/L Bacteria: EC10 (Pseudomonas putida); 9000 mg/L 12.2 Mobility Non-soluble in water, the product evaporates easily from ground and water surface. 12.3 Persistence and degradability 12.4 Bioaccumulation Low accumulation but easily volatile. 12.5 Other necessary information Do not release into bodies of water, drains and soil. 13. DISPOSAL Residual chemical and used containers shall be disposed of according to the valid legislation regulating waste management. 14. TRANSPORTATION 14.1. UN number 14.2. Packaging group 14.3. Land transport 14.3.1. Hazard division of cargo / ADR class 14.3.2. Hazard ID number 14.3.3. Name according to accompanying document 14.4. Sea transport 14.4.1. IMDG-code 14.4.2. Accurate technical name 14.5. Air transport 14.5.1. ICAO/IATA-code 14.5.2. Accurate technical name 1299 III 3 30 Turpentine 3 TurpentineMATERIAL SAFETY DATA SHEET Pine resin turpentine 5 3 Turpentine 15. OBLIGATORY INFORMATION ON THE LABEL 15.1. Information on the label 15.1.1. Hazard symbol and its meaning Xn - Harmful N - Environmental hazard 15.1.2. Names of ingredients to be indicated on the label Turpentine 15.1.3. Risk phrases R10 - Flammable. R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. R36/38 - Irritating to eyes and skin. R43 - May cause sensitization by skin contact. R65: Harmful: may cause lung damage if swallowed. R51/53 - Toxic to aquatic organisms; may cause long-term adverse effects in the aquatic environment. 15.1.4. Safety phrases S2 - Keep out of the reach of children. S36/37 - Wear suitable protective clothing and gloves. S46 - If swallowed, seek medical advice immediately and show the container or label. S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. S62 - If swallowed, do not induce vomiting; seek medical advice immediately and show the container or label. 15.2. Local (national) legislation: In accordance with the directive 1907/2006/EEC 16. OTHER INFORMATION 16.1. Purpose of use 16.1.1. Written verbal information On the label 16.2. Instructions of use On the label 16.3. Full text of the R-phrases indicated by numbers in clause 2 R10 - Flammable. R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. R36/38 - Irritating to eyes and skin. R43 - May cause sensitization by skin contact. R65: Harmful: may cause lung damage if swallowed. R51/53 - Toxic to aquatic organisms; may cause long-term adverse effects in the aquatic environment. 16.4. Additional information is provided by Skandian Grupp OÜ 16.5. Sources for preparation of this material safety data sheet Material safety data sheets submitted by manufacturers of the raw materials.