SAFETY DATA SHEET 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY / UNDERTAKING 2 Product Name: Eco Safe Green Company: Worlds Best Products / Graffiti Ace 1203 Oakey Flat Road Narangba Qld 4504 Phone Number: Fax: 07 38866149 (office hours only) 07 38866336 EMERGENCY 1311 26 Revision: None Replaces SDS: No Safety Data Sheet compiler: Intended use: Graffiti removal from Trains, Stations, Platforms Sidings & Signs worldsbest@esc.net.au HAZARDS IDENTIFICATION Flammability: Human Health Effects: Environmental Effects: 3 COMPOSITION / INFORMATION ON INGREDIENTS Hazardous and non hazardous Ingredients: Water Workplace exposure limit values exist for the following constituents: 4 Combustible upon severe heat (See section 9 for flash point) Harmful by prolonged inhalation and if swallowed – may cause severe mouth irritation if swallowed Irritating to skin. No components classified as environmentally harmful Cane sugar alcohol (EC200-578-6) F;R11, concn. 10-20% Natural organic plant extracts Xn;R20/22, concn. 40-60% Alcohol exothylate (EC209-406-4) Xn;R22, concn. 5-10% Balance to 100% Ethanol (see section 8) FIRST-AID MEASURES Inhalation Skin Contact: Eye Contact: Ingestion: Bare Brick ‘GREEN’ Remove from exposure; remove to fresh air. If breathing is laboured, hold in a half-upright position; obtain medical attention Wash skin with soap and water and remove contaminated clothing. If liquid has contacted eyes, immediately wash out with plenty of water, holding the eyelids apart, Obtain medical attention. Wash out mouth with water. Give water to drink (unless patient is losing consciousness). Do not induce vomiting Issue1 December 2010 5 FIRE-FIGHTING MEASURES Extinguishing: Exposure Hazards: Protective Equipment for fire fighting: 6 Extinguishers - Carbon dioxide, foam Fumes may include carbon monoxide. Self-contained breathing apparatus ACCIDENTAL RELEASE MEASURES Personal Precautions: Environmental Precautions: Methods for Cleaning Up: Wear gloves, chemical goggles; overalls. Ventilate the area to clear any residual fumes Prevent residue from entering drains and water courses Sweep up damaged packaging and dispose of in accordance with local regulations. Water can be used to dissolve residue. Waste must be disposed of in accordance with Federal, State and Local government environmental control regulations. . 7 HANDLING AND STORAGE Handling: Storage: 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Workplace Exposure limit values Personal Protective Equipment: 9 Use in well-ventilated area controlled in compliance with occupational exposure limits. Do not intentionally breathe vapour and avoid contact with eyes, skin and clothing. The usual precautions for handling chemicals should be observed. Keep in a cool, well-ventilated place and away from severe heat sources. Alcohol LTEL 1200 mg/m3 (8h. TWA) Wear overalls and chemical goggles. Wear PVC or rubber gloves for short-term exposure or PVA or Viton gloves for prolonged exposure. Remove working clothes after work. Use respiratory equipment approved for organic vapours and mists if there is a risk of exposure to vapour in enclosed areas PHYSICAL AND CHEMICAL PROPERTIES Typical values – does not constitute a specification Physical State Pale lemon coloured liquid Appearance Odour Boiling point/range (°C) Flash Point (°C)(Abel closed cup) Flammability – auto ignition temp. (°C) Explosive properties Oxidising properties Vapour pressure (mbar @ 20°C) Relative Density (@15.5°C) Solubility in water Solubility in fat / solvent Partition coefficient (log Pow) Viscosity (mPa.s @ 20°C) Bare Brick ‘GREEN’ Clear/cloudy Aromatic Herbal >95 °C 90°C No data available None None No data available 1.0 Disperses Miscible No data available No data available Issue1 December 2010 10 STABILITY AND REACTIVITY Stability: Conditions to avoid: Materials to avoid Hazardous decomposition products 11 TOXICOLOGICAL INFORMATION Acute Toxicity -oral -inhalation -dermal Corrosivity/Irritation -eye -skin -respiratory tract Sensitisation -skin -respiratory Repeated-dose toxicity Mutagenicity Carcinogenicity Reproductive toxicity 12 Mobility Persistence and degradability Bioaccumulative potential Other adverse effects Irritating to eyes Irritating to skin, will cause dryness, cracking May cause irritation No evidence of sensitisation effects No evidence of sensitisation effects No data available on effects of repeated skin contact No evidence of mutagenicity No evidence of carcinogenicity No evidence of reproductive toxicity Does not contain components classified as harmful for the environment Disperses in water Biodegradable Not known None known DISPOSAL CONSIDERATIONS Waste Residue: Packaging: 14 Harmful if swallowed Harmful by inhalation -note occupational exposure limits in section 8 – inhalation of concentrations above the OEL may lead to light-headedness, nausea and headache. Can be absorbed through the skin ECOLOGICAL INFORMATION Ecotoxicity 13 Combustible. Extreme heat and flame Oxidising agents. Oxides of carbon, ie monoxide, dioxide Disposal should be in accordance with local or national legislation via an authorised waste disposal contractor to an approved waste disposal site. Dispose of through normal waste collection methods TRANSPORT INFORMATION Transport Classification UN Number Hazard Class Proper Shipping Name Packing Group Marine Pollutant Limited Quantity Bare Brick ‘GREEN’ Not Classified as dangerous goods for carriage NA NA Bare Brick ‘GREEN’ NA No 1 litre Issue1 December 2010 15 REGULATORY INFORMATION CHIP3 Classification CHIP Label Label Name Symbol Classified as hazardous Xi Bare Brick ‘GREEN’ Xi Named component Natural organic plant extracts Risk Phrases R20/22 Harmful by inhalation and if swallowed R38 Irritating to skin R65 Harmful: may cause lung damage if swallowed Safety Phrases S24/25 Avoid contact with skin and eyes S37/39 Wear suitable gloves and eye/face protection S23 Do not breathe vapour/spray S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label EC Number EC Directives Statutory Instruments 16 None required for label Dangerous Substances Directive 67/548/EEC as amended by 1992/32/EEC; Dangerous Preparations Directive 1999/45/EC; Safety Data Sheets Directive 91/155/EEC. The Chemicals (Hazard Information and Packaging for Supply) Regulations 2002 (CHIP3) The Hazardous Wastes Regulations 2005 and the List of Wastes Regulations 2005 The Control of Substances Hazardous to Health Regulations 2002 OTHER INFORMATION This product safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to ensure safe workplace operations Further references: Occupational exposure limits (EH 40) COSHH essentials (HSG 193) All sections have been amended in this revision to comply with the requirements of CHIP3 2002 and SDS ACoP L130 Bare Brick ‘GREEN’ Issue1 December 2010