Name: Lab Partners: Date Completed: You Light Up My Life Purpose: This lesson allows you to collect evidence regarding some of the properties of substances, and look for patterns. Predict: Make some predictions regarding the following substances. Predict: 1) whether the substance will conduct electricity, 2) whether the substance will dissolve in water. Put your predictions in the left hand portion of the table. Predictions Substances Conduct? Y/N Dissolve? Y/N Test Results Conduct? Y/N Dissolve? Y/N Conduct when dissolved? H2O(l), water Al(s), aluminum foil C12H22O11(s), sugar, sucrose NaCl(s), salt, sodium chloride SiO2(s), sand, silicon dioxide C20H42(s), wax, paraffin C2H6O(l), ethanol Cu(s), copper CaCl2(s), calcium chloride CuSO4(s), copper sulfate Test 1: Conductivity Using the conductivity apparatus, test the conductivity of each sample. Test 2: Dissolving Take a very small portion of each substance and try to dissolve it in 25-30 mL of water. Enter your results in the right hand portion of the table. Before proceeding to the next substance, test any dissolved substances for conductivity. Test 3: Conducts When Dissolved. If the substance dissolves in water, test this liquid with the conductivity apparatus. Enter your results in the final column of the table. When a substance does not dissolve enter N/A in the last column for Not Applicable. Answer questions: 1. Make a list of those substances that conduct electricity but do not dissolve in water. What other things do these substances have in common? (Think about their properties and their chemical formulas.) 1 2. Divide the substances that dissolve in water into two categories: those that conduct electricity once they are dissolved, and those that don't. Substances that dissolve in water Conduct Don’t conduct 3. What do the substances that conduct electricity once they are dissolved have in common? 4. What do the substances that do not conduct electricity once they are dissolved have in common? (Leave water out.) 5. Write a generalizing statement about the substances that do not light up the bulb. 6. Write a generalizing statement about the substances that do light up the bulb. 7. Predict whether isopropanol, C3H8O(1), will conduct electricity. State your reasoning. Making Sense 1. If it is dangerous to take a bath with a blow dryer, what must also be true about the water in the bathtub? 2. Which place would be safer during a lightning storm, the ocean or a bath of pure water? Explain your reasoning. 3. Predict whether each will conduct electricity, dissolve in water, and/or conduct electricity once dissolved. State your reasoning in each case. a. MgCO3(s) magnesium carbonate b. C4H6O(1) acetone c. Ti(s) titanium d. LiNO3(s) lithium nitrate e. CuZn(s) bronze 2 Electron Glue Here are some possible models to explain how electrons provide the glue to stick atoms together. Each sphere in the drawing represents an atom. The gray shaded areas represent where the negatively charged electrons might be found in each model. Model 1: IONIC Properties: Made of metal and non-metal atoms Dissolves in water Conducts electricity when dissolved but not when solid Description of drawing: Spheres without gray areas represent metal atoms. Spheres with gray areas are non-metal atoms. Metal atoms have "given up" their valence electrons to non-metal atoms. Model 2: NETWORK COVALENT Properties: Made entirely of nonmetal atoms Does not dissolve in water Does not conduct electricity Very hard solids Description of drawing: Valence electrons connect atoms with each other in all directions - like a grid or network. Model 3: METALLIC Properties: Made entirely of metal atoms Do not dissolve in water Conduct electricity Bendable solids Description of drawing: Valence electrons are free to move throughout the substance like a "sea" of electrons. Model 4: MOLECULAR COVALENT Properties: Made of nonmetal atoms Some dissolve in water, some do not Do not conduct electricity Tend to be liquids or gases or softer solids Description of drawing: Valence electrons are shared between some atoms. This creates small stable units within the substance. 3 Electron Glue Purpose: This lesson helps to explain the physical properties of basic substances by examining the types of bonds that exist between the atoms of these substances. Step One: Read the 4 descriptions of possible models for bonding, on the handout. Chemical formula Na(s) NaCl(s) (salt) Hg(1) CuCl2(aq) SiO2(S) CH3CH20H(1) NaOH(aq) NaCI(aq) MgSO4(s) Name Sodium Sodium chloride Mercury Aqueous copper chloride Silicon dioxide(sand) Ethanol (drinking alcohol) Aqueous sodium hydroxide (Drano) Aqueous sodium chloride (salt water) Magnesium sulfate (Epsom salt) Chemical formula Cu(s) H2O(1) C(s) CH4(g) Si(s) Pt(s) Name Copper Water Carbon (diamond) Methane (natural gas) Silicon (computer chips) Platinum (jewelry) Step Two: Classify the 15 substances above according to which of the 4 models best describes their make-up and properties. Refer to your periodic table as needed. Ionic Covalent Network Metallic Molecular Covalent Are there any substances that don't seem to fit properly in the categories you have placed them into? List them below and explain. Use the models of bonding on the handout to answer the following: 1. Which model would you predict for the following substances? Explain your reasoning. C6H12O6 (sugar) KI (potassium iodide) He (helium) Au (gold) CO2 (carbon dioxide gas) 4 2. In the ionic solid, Model l, the non-metal atoms have a negative charge and the metal atoms have a positive charge. What do you think causes these charges? 3. In the metallic solid, Model 3, the "sea" of electrons has a negative charge. What charge would the spherical atoms have? Explain. 4. In covalent substances electrons are shared between atoms. What differences do you see in Models 2 and 4? 5. Use the models to explain the following evidence: a. molecular covalent substances are often gases b. ionic substances are brittle 6. Explain how the location of the "electron bonds" in Model 3 might account for the softness and flexibility of copper metal. 7. Explain how the location of the electron bonds in Model 2 might account for the incredible hardness of a diamond. 8. Remember from our previous lesson that both sugar and salt dissolve in water, but sugar does not conduct electricity. We can conclude that they are bonded differently. Use the models to explain how these two substances might be different once they dissolve. Making Sense If you have the chemical formula of a substance, how and what can you figure out about its properties? Explain. Use the compound silver nitrate, AgNO3 as an example. 5 Homework Reading Assignment: Model 1 is a description of what chemists call ionic bonding. Ionic bonding occurs strictly between metal and nonmetal atoms. In ionic bonding some of the valence electrons of a metal atom are transferred to a nonmetal atom so that each atom ends up with a noble gas configuration. Usually one, two, or three electrons are transferred from one atom to another. This transfer of an electron causes the metal atom to have a net positive charge (+) and the nonmetal atom to have a net negative charge (). The Cl individual atoms in ionic solids are referred to as ions because of their charges. These opposite charges are attracted to one another. On the right is a drawing of a chunk of salt, NaCl, a very common ionic substance. Na+ Notice how the sodium and chloride ions alternate throughout the structure. The positive and negative ions alternating in three dimensions make the solid quite strong because of their strong attractions to one another. The sodium ion is written Na+ and the chloride ion is written Cl. When ionic solids are placed in contact with water, they dissolve. They remain ions, with charges, but now the individual ions are surrounded by water molecules and distributed throughout the water. Once dissolved, ionic compounds will conduct electricity . Models 2 and 4 both represent bonding that is referred to by chemists as covalent bonding. The valence electrons are shared between atoms, such that the electrons are attracted to two nuclei. In Model 4, the bonding is called molecular covalent. This means that the atoms are connected into small units, called molecules, by covalent bonds. However, the molecules themselves are not connected by covalent bonds to one another. Thus, molecular covalent substances consist of a large group of individual molecules. The picture shows an artist's idea of a small collection of water molecules. Note that whenever we are talking about molecules in chemistry, we are referring to covalently water bonded groups of atoms. Molecular covalent substances tend to be liquids, gases or molecules soft solids. This is because the individual molecules have more freedom to move within the substance. Model 2 represents a very specific type of covalent bonding called network covalent bonding. This means that there is a covalent connection between each atom and all of the adjacent atoms that surround it. This extended network covalent bonding creates a very strong substance that is not easily broken apart. Diamond and silicon are examples of substances that have network covalent bonding. Diamond is made entirely of carbon atoms. If we looked at a chunk of diamond on a particulate level, we'd see that each carbon atom is bonded in three dimensions to the carbon atoms surrounding it. The illustration shows an artist's rendering of a piece of diamond from an atomic level. The shared electrons have been replaced by sticks showing the connections between all the atoms. SiO2 Silicon dioxide, sand (SiO2), is another network covalent substance. You may have chosen to put it in the molecular covalent category because it is made of two nonmetal atoms. Nevertheless, it is a very hard solid, unlike the molecular covalent compounds. Its hardness comes from an extended network of covalent bonds throughout the material. Model 3 is referred to as metallic bonding. In the case of metallic bonding each atom contributes electrons to the solid. Thus, each atom becomes essentially positive in charge, having lost some electrons. The electrons then form a sort of sea of electrons around the atoms. The atoms in turn are attracted to the negatively charged "sea". On the right is an artist's rendering of a block of iron, Fe, atoms. The "sea of electrons" is not visible. Fe 6 Name: Per: Date: Electron Glue Answer the following questions: 1. Think about the physical properties of the following substances, and decide which type of bonding you would probably find in each substance. Explain your reasoning. a. hair gel b. motor oil c. silver bracelet d. sodium bicarbonate (baking soda) 2. Look at the chemical makeup of the following substances and decide which type of bonding you would probably find in each substance. a. Zn(s) zinc b. C3H8(1) propane c. CaCO3(s) calcium carbonate 7