D. A. Knight - PUBLICATIONS 47. Surface Modification Using Phosphonic Acids and Esters Petit, M.; Janvier, P.; Knight, D. A.; Bujoli, B. in preparation for submission to Chem. Rev. 46. Synthesis of Chiral Allylphosphonates and Resolution using 31P NMR Spectroscopy Vaden, O. K.; Knight, D. A. in preparation for submission to J. Org. Chem. 45. Organometallic Phosphonic Acids. Synthesis and Structural Characterization of Chiral and Achiral Chromium Arene Tricarbonyl Complexes Olano, L. R.; Deemie, R. W.; Tran, H.; Congiardo, L. K. B.; Mague, J. T. Fettinger, J. C.; Knight, D. A. in preparation for submission to J. Organomet. Chem. 44. Synthesis, Characterization and Post-Synthetic Modification of Layered Cadmium Vinylphosphonate [C2H3PO3Cd]•H2O Congiardo, L. K. B.; Mague, J. T.; Funk, A.; Yngard, R.; Knight, D. A. J. Chem. Crys .submitted. 43. The Michaelis-Becker Reaction in Phosphonium and Imidazolium Ionic Liquids Vu, A.; Shaffer, E.; Congiardo, L. K. B.; Knight, D. A. Phosphorus, Sulfur Silicon Relat. Elem. in press. 42. Cobalt(III) Complexes as Antiviral and Antibacterial Agents Chang, E. L.; Simmers, C.; Knight, D. A. Pharmaceuticals 2010, 3, 1711-1728. 41. Effects of Co(III), Ni(II), and Ru(III) Amine Complexes on Sindbis Virus: Possible Mechanisms of Antiviral Action Knight, D. A.; Hickey, T. E.; Bongard, J. E.; Thach, D. C.; Chang, E. L. J. Inorg. Biochem. 2010, 104, 592-598. 40. A Cobalt-Amine Based Metal Complex as an Antibacterial Compound Chang, E. L.; Zabetakis, D.; Knight, A.; van Hoek, M.L. US Patent Appl. 12/494,750 (06/30/09). 39. A New Coordination Mode for Tris(2-carboxyethyl)phosphine: Synthesis, Structure and Characterization of the Mixed Valence Co(II)/Co(III) Complex [Co{P(CH 2CH2COO)2 (CH2COOH)}2][Co(H2O)4] [Na2(H2O)4]Cl2 • 6H2O Knight, D. A.; Deschamps, J.; Butcher, R.; Simmers, C.; Chang, E. L. Polyhedron, 2008, 27, 1795-1801. 38. Antiviral Properties of Cobalt(III)-Complexes Delehanty, J. B.; Bongard, J. E.; Thach, D. C.; Knight, D. A.; Hickey, T.; Chang, E. L. Bioorg. Med. Chem. 2008, 16, 830-837. 37. Method of Using a Cobalt-Amine Based Metal Complex as an Antiviral Compound and a Method for the Preparation of Functionalized Analogs Thereof Chang, E. L.; Delehanty, J. B.; Thatch, D. C.; Bongard, J. ; Knight, A. US Patent Appl. 2008012835 (11/02/07). 36. Organometallic Supramolecular Mixed Valence Cobalt(I)/Cobalt(II) Aquo Complexes Stabilized with the Water-soluble Phosphine Ligand p-TPPTP (p-triphenylphosphine triphosphonic acid) Schull, T. L.; Henley, L.; Deschamps, J. R.; Butcher, R. J.; Maher, D. P.; Klug, C. A.; Swider-Lyons, K.; Dressick, W. J.; Bujoli, B.; Greenwood, A. E.; Congiardo, L. K. B.; Knight, D. A. Organometallics, 2007, 26, 2272-2276. 35. Artificial Nucleases for Anti-viral, Anti-bacterial Applications Chang, E. L.; Knight, D. A.; Goldman, E. R.; Delehanty, J. B.; Soni, R. Patent Appl. 2005. 34. Inhibition of RNA Translation by Cobalt Hexammine Knight, D. A.; Bongard, J.; Delehanty, J. B.; Chang, E. L. Proceedings-2003 Joint Service Scientific Conference on Chemical and Biological Defense Research 2005, VA-1. 33. Monofunctionalized Tetraazamacrocyles for use in Bioconjugation and Catalysis Bongard, J.; Hartsock, R. W.; Stegbauer,W. D.; Streich, F. C.; Barnum, R.; Chang, E. L.; Knight, D. A. Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, 2005, 35, 727. 32. RNA Hydrolysis and Inhibition of Translation by a Co(III)-cyclen Complex Delehanty, J. B.; Stuart, T. C.; Knight, D. A.; Goldman, E. R.; Chang, E. L. RNA 2005, 11, 831. 31. Organometallic Phosphonic Acids: Synthesis and Application Schull, T. L.; Knight, D. A. Coord. Chem. Rev. 2005, 249, 1269. 30. Carboxylic Acid Functionalized and Supported Cobalt(III) Cyclen Complexes for Catalytic Hydrolysis of Phosphodiester Bonds Knight, D. A.; Delehanty, J. B.; Goldman, E. R.; Bongard, J.; Streich, F.; Edwards, L. W.; Chang, E. L. J. Chem. Soc., Dalton Trans. 2004, 2006. 29. cis-[PtCl2(p-TPPTP(H)8)2]Cl2•4H2O•(CH3CH(OH)CH3): a platinum phosphine complex exhibiting both inter- and intramolecular hydrogen bonding Schull, T. L.; Butcher, R.; Dressick, W. J.; Brandow, S. J.; Byington, L. K.; Knight, D. A. Polyhedron 2004, 23, 1375 28. DNA Cleavage using Artificial Hydrolases Chang, E. L.; Soni, R. Delehanty, J. B.; Bongard, J.; Streich, F.; Knight, D. A. Proceedings-2003 Joint Service Scientific Conference on Chemical and Biological Defense Research 2003, NT-P2 27. Artificial Endonucleases as Antiviral, Antibacterial Agents Knight, D. A.; Delehanty, J. B.; Goldman, E. R.; Bongard, J.; Streich, F.; Edwards, L. W.; Chang, E. L. Proceedings-2003 Joint Service Scientific Conference on Chemical and Biological Defense Research 2003, DECON-P6. 26. Dichloro(methyl 4-[(1,4,7,10-tetraazacyclododec-1-yl)methylbenzoate) cobalt(III) methyl sulfate Deschamps, J. R.; Knight, D. A.; Goldman, E. R.; Delehanty, J. B.; Chang, E. L. Acta Crys, E. 2003, C59, m916. 25. Synthesis and X-Ray Crystal Structure of a Chiral Organometallic Phosphonate [6-1,2-C6H4(OCH3) (P(O)(OCH2CH3)2)]Cr(CO)3 Olano, L. R.; Tran, H.; Mague, J. T.; Knight, D. A. J. Chem. Crys. 2003, 33, 497-501. 24 Rhodium Catalyzed Allylic Isomerization in Water Schull, T. S.; Knight, D. A. Synth. Comm. 2003, 33, 827. 23. Coordination Chemistry of the Water-Soluble Ligand TPPTP and Formation of a [Mo(CO)5(m-TPPTP)] Monolayer on an Alumina Surface Harper, B. A.; Knight, D. A. George, C.; Brandow, S. L.; Dressick, W. J.; Dalcey, C. S.; Schull, T. L. Inorg. Chem. 2003, 42, 516. 22. Aqueous Phase Palladium Catalyzed Coupling: A Green Chemistry Laboratory Experiment Harper, B. A.; Rainwater, J. C.; Birdwhistell, K.; Knight, D. A. J. Chem. Ed. 2002, 79, 729. 21. Rhodium-mediated Delamination of Layered Copper and Zinc Vinylphosphonates Kim, V.; Butcher, R. J.; Harper, B. A. Schull, T. L.; Knight, D. A. J. Chem. Soc., Dalton Trans. 2002, 824. 20. A Synthetic Route to a New Surface-Active Phosphine Ligand: 12-DPDP (12-Diphenylphosphinododecylphosphonate) Schull, T. L.; Knight, D. A. Tetrahedron, 2000, 56, 7093. 19. A Convenient Synthesis of the Water-Soluble Ligand Hexasodium Tris(4-phosphonatophenyl)phosphine Dressick, W. J.; Brandow, S. L.; Schull, T. L.; Knight, D. A J. Org. Chem. 2000, 65, 5059. 18. An Organometallic Sol-Gel Route to Layered Zinc Phenylphosphonate and Encapsulation of 6(C6H6)Cr(CO)3 Deemie, R. W.; Rao, M.; Knight, D. A. J. Organomet. Chem., 1999, 585, 162. 17. New Chiral Phosphine-Phosphonites Ligands Derived from (2R, 3R)-Dimethyl Tartrate, (S)-Binapthol and (1R,2S)-Ephedrine Schull, T. L.; Knight, D. A. Tetrahedron: Asymmetry, 1999, 10, 207. 16. Spectroscopic Evidence for Hemilabile Behavior in a -Ketophosphonate Complex of Molybdenum(VI) Miggins M.; Fettinger, J. C.; Islam, M. Q.; Knight, D. A. Synth. React. Inorg. Met. Chem. 1998, 28, 543. 15. Synthesis and Characterization of an Organometallic Phosphonic Acid: X-ray Crystal Structure of [6-pC6H4(CH2PO3H2)2]Cr(CO)3l Deemie, R. W.; Fettinger, J. C.; Knight, D. A. J. Organomet. Chem., 1997, 538, 257. 14. Synthesis of Phosphonic Acid Ester Functionalized Arene Chromium Tricarbonyl Complexes Deemie, R. W.; Knight, D. A. Inorg. Chim. Acta, 1997, 254, 163. 13. Synthesis and Characterization of Palladium(II) and Platinum (II) Complexes Containing Water-Soluble Hybrid Phosphine-Phosphonate Ligands Schull, T. L.; Fettinger, J. C.; Knight, D. A. Inorg. Chem., 1996, 35, 6717. 12. Oxidation of Organic Sulfides Using a -Ketophosphonate Complex of Molybdenum(VI): X-Ray Crystal Structure of MoCl2O2L (L = diethyl(2-phenyl-2-oxoethyl)phosphonate Miggins, M.; Kakarla, K.; Fettinger, J. C.; Knight, D. A. Anales de Quimica, Int. Ed. 1996, 92, 59. 11. The First Example of an Aryl Ring Substituted by Both Phosphine and Phosphonate Moieties: Synthesis and Characterization of the New Water-Soluble Phosphine Ligand Na2[Ph2P(C6H4-p-PO3)]•1.5H2O and Platinum(II) Complexes Schull, T. L.; Fettinger, J. C.; Knight, D. A. J. Chem. Soc. Chem. Comm 1995, 1487. 10. Diastereoselective Additions of Nucleophiles and Electrophiles to Isoquinoline and Quinoline Mediated by an Easily Resolved and Recycled Transition Metal Auxiliary: Enantioselective Syntheses of 1,2,3,4Tetrahydroisoquinoline Derivatives Stark, G. A.; Richter-Addo, G. B.; Knight, D. A.; Dewey, M. A.; Arif, A. M.; Gladysz, J. A. in "Stereoselective Reactions of Metal-Activated Molecules" Eds. Werner, H.; Sundermeyer, J.; Vieweg: Wiesbaden, 1995. 9. New Strategies for Enantioeselective Syntheses of 1-Alkyl- and 1,4-Dialkyl-1,2,3,4-tetrahydroisoquinolines: Diastereoselective Additions of Nucleophiles to Isoquinoline Mediated by an Easily Resolved and Recycled Chiral Transition Metal Auxiliary Richter-Addo, G. B.; Knight, D. A.; Dewey, M. A.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc., 1993, 115, 11863. 8. Synthesis and Structure of Chiral Rhenium Imine and Methyleneamido Complexes of the Formulas [(5C5H5)Re(NO)(PPh3)(1-NH=C(R)R')]+ TfO- and [(5-C5H5)- Re(NO)(PPh3)(1-N(R")=CH(R'"))]+ TfOKnight, D. A.; Dewey, M. A.; Stark, G. A.; Bennett, B. K.; Arif, A. M.; Gladysz, J. A. Organometallics 1993, 12, 4523. 7. Camphor-derived -Ketophosphine Complexes of Rhodium(III) and Iridium(III); X-ray Crystal Structure of cis, mer-Trichlorobis(1R)-endo-(+)-3-diphenylphosphinocamphor rhodium(III)Chloroform(1/2) Knight, D. A.; Cupertino, D. C.; Harman, M.; Hursthouse, M. B.; Cole-Hamilton, D. J. Polyhedron 1992, 11, 1987. 6. Synthesis, Structure, Dynamic Behavior, and Reactivity of Chiral Rhenium Primary Phosphine and Phosphido Complexes of the Formula [(5-C5H5)Re(NO)(PPh3)(PRH2)]+ X- and (5C5H5)Re(NO)(PPh3)(PRH) Zwick, B. D.; Dewey, M. A.; Knight, D. A.; Buhro, W. E.; Arif, A. M.; Gladysz, J. A. Organometallics 1992, 11, 2673. 5. Synthesis and Structure of -Complexes of the Chiral Lewis Acid [(5-C5H5) Re(NO)(PPh3)]+ and Aromatic Nitrogen Heterocycles Dewey, M. A.; Knight, D. A.; Arif, A. M.; Gladysz, J. A. Z. Naturforsch. B: Anorg. Chem., Org. Chem. 1992, 47b, 1175. 4. Carboethoxymethyl, Cyanomethyl and Methoxymethyl Complexes of Nickel (II) and their Carbonylation Reactions Belderrain, T. R.; Knight, D. A.; Irvine, D. J.; Paneque, M.; Poveda, M. L.; Carmona, E. J. Chem. Soc. Dalton Trans. 1992, 1491. 3. Synthesis, Structure and Reactivity of Chiral Rhenium Amido Complexes of the Formula (5C5H5)Re(NO)(PPh3)(NRR') Dewey, M. A.; Knight, D. A.; Arif, A. M.; Gladysz, J. A. Chem. Ber. 1992, 125, 815. 2. Synthesis, Structure and Reactivity of Chiral Rhenium Amine Complexes of the Formula [(5C5H5)Re(NO)(PPh3)(NRR'R")]+ TfO- Dewey, M. A.; Knight, D. A.; Klein, D. P.; Arif, A. M.; Gladysz, J. A. Inorg. Chem., 1991, 30, 4995. 1. Camphor-derived -Ketophosphine Complexes of Palladium(II) and Platinum(II) Knight, D. A.; Cupertino, D. C.; Cole-Hamilton, D. J. J. Chem. Soc. Dalton Trans., 1990, 3051.