Geophysical Research Letters Supporting Information for Seismic anisotropy in the lowermost mantle near the Perm Anomaly Maureen D. Long and Colton Lynner Department of Geology and Geophysics, Yale University, New Haven, CT USA Contents of this file Text describing the SKS-SKKS splitting discrepancy method in detail Captions for Supplementary Figures S1 to S5 Captions for Supplementary Tables S1 to S3 Additional Supporting Information (Files uploaded separately) Figures S1 to S5 Tables S1 to S3 Introduction Supplementary information to this article includes a description of the SKS-SKKS splitting discrepancy method, captions for the supplementary figures and tables, a list of supplementary references, supplementary Figures S1-S5, and supporting Tables S1-S3. SKS-SKKS splitting discrepancies: Assumptions, limitations, and interpretation Clear discrepancies between the measured shear wave splitting parameters for SKS and SKKS phases measured for the same event-station pair were first documented in the literature by James and Assumpçao [1996] and first exploited to constrain anisotropy in the lower mantle by Niu and Perez [2004]. The splitting of SK(K)S phases is very commonly used to constrain anisotropy in the upper mantle beneath the seismic station; several lines of evidence suggest that the upper mantle makes the major contribution to the splitting of core-refracted phases, including the generally good agreement between SK(K)S splitting and models of upper mantle anisotropy derived from surface waves [e.g., Becker et al., 2012]. A number of recent papers have used the SKS-SKKS discrepancy technique to study anisotropy in the lower mantle [e.g., Niu and Perez, 2004; Hall et al., 2004; Restivo and Helffrich, 2006; Long, 2009; He and Long, 2011; Lynner and Long, 2012, 2014a; Roy et al., 2014; Ford et al., 2015]. Here we provide a description of the assumptions and limitations of this measurement technique, along with the limitations inherent in the interpretation of discrepant SKS-SKKS splitting data. 1 The SKS-SKKS splitting discrepancy technique exploits the similarity in the ray propagation paths for SKS and SKKS phases in the upper mantle to look for a signal from anisotropy in the lowermost mantle. If the transverse component waveforms for an SKS phase and an SKKS phase from the same seismogram are significantly different (and therefore the waves exhibit different shear wave splitting), then the difference can be attributed to anisotropy in the lowermost mantle. The reason for this is that the two phases sample the upper mantle in a nearly identical way, while they sample different portions of the lowermost mantle (and have a modest difference in propagation angle just above the core-mantle boundary, or CMB). Therefore, large differences in the estimated splitting parameters for the two phases implies a contribution from anisotropy in the lower mantle; such differences cannot be easily explained in terms of anisotropy in the upper mantle [e.g., Niu and Perez, 2004; Hall et al., 2004; Restivo and Helffrich, 2006; Long, 2009]. It is important to keep in mind, however, that in the vast majority of cases (approximately 95%), lowermost mantle anisotropy does not cause significant splitting of SK(K)S phases [Niu and Perez, 2004; Restivo and Helffrich, 2006; Nowacki et al., 2011]. Therefore, lowermost mantle anisotropy is not the first-order contributor to SK(K)S splitting at the stations examined in this study (or in any other study of lowermost mantle anisotropy) Rather, the SKS-SKKS splitting discrepancy method seeks to identify subtle, intermittent, and localized contributions from the lowermost mantle to the splitting of a small minority of SK(K)S arrivals at a given station (or set of stations). While the observation of strong SKS-SKKS splitting discrepancies is a straightforward indicator of a contribution from anisotropy in the lower mantle, the interpretation of discrepant measurements in terms of actual structure is somewhat complicated. One assumption that is usually made in SKS-SKKS splitting discrepancy studies is that the most likely source of the anisotropy is the D” region at the base of the mantle, as there is abundant evidence from other types of seismic data that the D” region often has strong anisotropy [Nowacki et al., 2011, and references therein], while the bulk of the lower mantle is generally thought to be isotropic [e.g., Meade et al., 1995; Visser et al., 2008]. However, a contribution to discrepant SKS-SKKS splitting from elsewhere in the lower mantle cannot generally be ruled out [e.g., Niu and Perez, 2004]. Another inference that is generally made from discrepant SKS-SKKS splitting observations is that strongly discrepant measurements typically reflect lateral variability in seismic anisotropy at the base of the mantle. That is, because SKS and SKKS phases sample slightly different regions of the lower mantle (see, e.g., the maps in Figures 3 and 4 of the paper), the simplest possibility is that there is a difference in anisotropic structure between the portion of D” being sampled by the SKS phase, and that sampled by the SKKS phase. An alternative explanation invokes an anisotropic geometry at the base of the mantle that would cause different splitting for SKS and SKKS phases, given the difference in propagation angle (about 15° at the base of the mantle). For an arbitrary anisotropic symmetry, differences in predicted splitting would be expected for different propagation directions. However, for most realistic anisotropic geometries expected for D” (e.g., crystallographic preferred orientation of post-perovskite or ferropericlase, or shape preferred orientation of aligned melt), the splitting parameters vary fairly smoothly as a function of propagation direction, except at a few distinct directions [e.g., Nowacki et al., 2011; Ford et al., 2015]. Such smooth variations would not be expected to cause significant discrepancies under most conditions, even taking into account the difference in propagation direction and path length for SKS vs. SKKS phases. In either case, however, significant discrepancies in splitting between the phases implies a contribution from anisotropy in the lower mantle near either the SKS exit point near the CMB, the SKKS exit point, or both. 2 Another nuance in the interpretation of SKS-SKKS splitting discrepancies is the fact that while clearly discrepant SKS-SKKS splitting requires a contribution from anisotropy in the lower mantle, the observation of non-discrepant SKS-SKKS splitting for any given pair does not necessarily rule out a contribution from the lowermost mantle. Globally, in about 95% of cases, splitting parameters measured for the two phases agree (within errors) [Niu and Perez, 2004]. This observation is used to argue against a first-order contribution to the global SK(K)S splitting database from lower mantle anisotropy, along with other observations [e.g., Niu and Perez, 2004; Long, 2009; Becker et al., 2012; Nowacki et al., 2011]. However, for any given nondiscrepant SKS-SKKS pair, it is possible that lowermost mantle anisotropy is contributing to the splitting of both phases in a similar way, or that both phases are sampling anisotropy in the lowermost mantle, but in a raypath geometry that does not cause splitting (that is, along the “null directions” of lowermost mantle anisotropy). When examining maps of non-discrepant and discrepant SKS-SKKS pairs, therefore, it is important to remember that an observation of non-discrepant splitting does not necessarily imply a lack of anisotropy in that region; it may be that both phases are sampling the same anisotropy, or that they are propagating at a direction that does not cause splitting. Indeed, in most studies of SKS-SKKS splitting discrepancies it is common to see discrepant observations interspersed with non-discrepant observations with only slightly different propagation paths [e.g., Long, 2009; He and Long, 2011; Lynner and Long, 2014a]. This may be due to small-scale variations in anisotropic structure, variability in the propagation direction for different SKS-SKKS pairs, or natural variability in noisy seismic data. While strong SKS-SKKS discrepancies are a straightforward indicator of a contribution from lowermost mantle anisotropy, in general they cannot be interpreted directly in terms of lowermost mantle structure, unless the anisotropic signal in the upper mantle beneath the seismic station is well known. If the upper mantle signal is not well known, then it is impossible to isolate the portion of the splitting of the SKS and SKKS phases due to lowermost mantle anisotropy; instead, one can only say that one or both of the phases has been affected by the lowermost mantle. For this reason, in some studies of SKS-SKKS splitting discrepancies, stations are selected such that the upper mantle anisotropy is well understood and simple; if this is the case, then the waveforms can be corrected for the effect of the upper mantle and the portion of the signal due to D” anisotropy can be isolated. We take this approach in the present study. The downside of this approach is that there are fewer stations to work with; however, it has a major advantage in that we can directly isolate the portion of the splitting signal due to the lowermost mantle in many cases. Furthermore, in this situation we can then make use of observations of non-discrepant pairs to rule out a contribution from the lowermost mantle in many cases. For cases where there is no contribution to splitting from the upper mantle (that is, either the station overlies apparently isotropic upper mantle, or the waves are polarized close to a fast or slow direction of upper mantle anisotropic symmetry), a non-discrepant observation of null splitting for both SKS and SKKS implies a lack of contribution from the lower mantle as well. Our approach to selecting statins in this study, therefore, is to use long-running stations at which we have already examined SKS splitting parameters as a function of backazimuth, and to only use stations that exhibit simple upper mantle splitting patterns whose waveforms can be easily corrected for the effect of upper mantle anisotropy. We use two types of stations in this study: 1) stations for which we observe null SKS arrivals over a wide backazimuthal range, which suggests that to first order, the upper mantle does not cause significant splitting at the periods used (~8-50 sec), or 2) stations for which we measure consistent SKS splitting 3 parameters in several backazimuthal quadrants, suggesting that the upper mantle can be approximated with a single, horizontal layer of anisotropy. (Examples of SKS splitting patterns for stations used in this study are shown in Figure S1.) For either of these two cases, it is straightforward to correct the waveforms for the effect of upper mantle anisotropy (by rotating and time-shifting the horizontal components appropriately) and isolate the contribution from the lowermost mantle. We do not use stations that exhibit systematic variations in measured SKS splitting patterns with backazimuth, as that suggests multiple layers of upper mantle anisotropy beneath the station and it is difficult to make an accurate correction for the upper mantle in these cases. We also do not use stations for which the backazimuthal coverage for SKS is poor, as this means we cannot distinguish between simple and complex upper mantle anisotropy patterns. We emphasize, again, that at the stations selected for use in this study, the lowermost mantle does not make the first-order contribution to the splitting of SK(K)S phases; the first-order aspects of the SK(K)S splitting patterns are controlled by the upper mantle. Rather, our analysis technique aims to isolate infrequent, localized contributions from the lowermost mantle to the splitting of a small number of SK(K)S arrivals in our dataset. Of course, for the small minority of cases for which we observe significant SKS-SKKS splitting discrepancies, this contribution from the lower mantle will cause a small amount of variability in the overall splitting patterns that reflects a contribution from D” for certain SK(K)S arrivals. These subtle deviations from the “simple” upper mantle splitting patterns, identified by searching for SKS-SKKS splitting discrepancies in this study, reflect localized contributions from lowermost mantle anisotropy. As discussed in the main text, it is important to rule out alternative explanations for differences in transverse component waveforms (and thus discrepant splitting measurements) for SKS and SKKS phases before attributing the discrepancies to lowermost mantle anisotropy. The possible effects of finite-frequency wave propagation, small-scale isotropic heterogeneity in the upper or lowermost mantle, interference from other seismic phases, and difference in propagation direction between the two phases are discussed in the main text and in a previous study [Lynner and Long, 2014a]. Another possible explanation for discrepant SKS-SKKS splitting is topography on the CMB, or other dipping structures at the base of the mantle, which might modify the polarizations of SKS and SKKS phases differently. This scenario was explored in detail by Restivo and Helffrich [2006], who suggested that anomalies in the polarization of SK(K)S phases upon (or shortly after) their exit from the CMB may be imparted by strong CMB topography, dipping interfaces within D”, or significant lateral velocity heterogeneity at the base of the mantle. In any of these cases, the polarization of the converted wave may deviate (up to ~20° in the Restivo and Helffrich [2006] study) from the purely SV polarization predicted by ray theory for homogeneous, non-dipping layers. While we considered this possibility, it is unlikely to be the primary explanation for the observations in our dataset, as we examined the polarizations (using algorithms built in to SplitLab) of the SKS and SKKS phases in our study both before and after correction for any splitting, as part of our normal processing routine. We did not observe any systematic deviations in initial polarizations from the prediction of SV polarized waves in our dataset, which suggests that in general, the differences in the observed transverse components for discrepant pairs were imparted by anisotropy, and not by dipping interfaces at the base of the mantle. We note, however, that Restivo and Helffrich (2006) documented a small number of anomalous SK(K)S polarizations beneath out study area, so it is possible that this effect makes a small contribution to our dataset. 4 Supplementary Figure Captions Figure S1. Examples of SKS splitting patterns as a function of backazimuth for selected stations used in this study. Top row: Stereoplots of SKS splitting measurements measured at stations (HGN and ITHO) at which we infer a negligible contribution from upper mantle anisotropy to the SKS splitting patterns. Circles indicate null (that is, non-split) SKS arrivals, while the orientation and length of the bars indicate the fast direction and delay time, respectively, of split arrivals. All measurements are plotted as a function of backazimuth (azimuth around circle) and incidence angle in the upper mantle (distance from center). Bottom row: Stereoplots of SKS splitting measurements measured at stations (ARU and VTS) at which we infer a “simple” contribution from upper mantle anisotropy; that is, the upper mantle anisotropy can be represented with a single, homogeneous, horizontal anisotropic layer. Plotting conventions are as in the top row. SKS splitting patterns and upper mantle anisotropy for the stations used in this study are documented in detail in Lynner and Long [2013, 2014b] and Ford et al. [2015]. Figure S2. Histogram of the number of measurements obtained as a function of epicentral distance. Histogram shows the number of non-discrepant pairs (blue) along with discrepant pairs (red, yellow, and black, as indicated by the legend). There are no systematic differences in the number of observed discrepant pairs as a function of distance. Figure S3. Plot of the measured delay times for splitting due to anisotropy in the lowermost mantle as a function of epicentral distance. These measurements correspond to the measurements in Figure 4 of the paper and have been corrected for the effect of anisotropy in the upper mantle. There is no systematic change in measured fast direction as a function of epicentral distance, although the number of measurements is small (10). Figure S4. Plot of splitting as a function of distance from the center of the Perm Anomaly (top panel) and from the edge of the African LLSVP (bottom panel). For the top figure, we have taken the subset of measurements which lie closer to the Perm Anomaly than to the edge of the African LLSVP, as delineated by the cluster analysis of Lekic et al. [2012], and plotted delay time measurements of D”-associated anisotropy (corresponding to Figure 4 of the paper) as a function of distance from the center of the anomaly. Null measurements are represented as zero delay time with error bars that extend up to delay times of 0.5 sec, which represents the approximate detection limit for shear wave splitting at the periods under study here. For the bottom figure, we have combined our measurements of D”-associated splitting along the northern border of the African LLSVP (western portion of Figure 4) with the dataset presented in Lynner and Long [2014a] that samples a larger geographical region surrounding the LLSVP. Non-null measurements of lowermost mantle anisotropy from this study are shown with blue diamonds; measurements from Lynner and Long [2014a] are shown in red. Figure S5. Similar to the left panel of Figure 3, except the background map shows lateral gradients in shear wavespeed at the base of the mantle, from Lekic et al. [2012]. These gradients are represented by the median range of Vs (m/s) over a distance of 5° in the five tomographic models considered by Lekic et al. [2012]. Supplementary Table Captions 5 Table S1. List of stations used in this study. Columns indicate the station name, network code, station latitude, station longitude, upper mantle delay time (sec), and upper mantle fast direction (degrees). For those columns marked NULL, no upper mantle correction is needed. Table S2. Measured shear wave splitting parameters obtained using the transverse component minimization method for SKS-SKKS pairs, measured before upper mantle corrections. Columns indicate the station name, event date, julian day of event, station latitude (degrees), station longitude (degrees), event latitude (degrees), event longitude (degrees), event depth (km), phase type (SKS vs. SKKS), 95% confidence region lower bound for fast direction (degrees), fast direction (degrees), upper bound on fast direction (degrees), lower bound for delay time (sec), delay time (sec), upper bound for delay time (sec), null flag (yes for null, no for non-null), agreement flag (3 for discrepant pairs, 2 for non-discrepant pairs). Table S3. Estimates of shear wave splitting parameters due to lowermost mantle anisotropy, obtained using the transverse component minimization method. Where needed, corrections have been applied to account for any contributions to splitting from upper mantle anisotropy beneath the station. 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