Fall 2008 Final Exam Review Answer Key Scientific Method Know the difference between: Hypothesis – A testable observation seen in nature theory – An explanation supported by many experiments law – an observation seen in nature Accuracy/Precision – looking at measurements Accuracy – how close a set of measurements is to the published standard. Precision – how close a set of measurements is to each other. Matter What is the formula for density? Density = mass/volume What is the density of water ? 1.00 g/ml If equal amounts of water, ethylene glycol (density = 1.11 g/mL, and butane (density = 0.599 g/ml), were mixed in a jar, which would be on top? On bottom? Top – butane, middle – water, bottom – ethylene glycol Be able to calculate density by using the water displacement method to determine volume. Final volume – initial volume = volume of object. Use this in the density formula Complete the chart below: State Definition – mention shape, volume, compressibility, etc . . . Solid Definite shape and volume. Incompressible. Rigid structure. Atoms are close together. Liquid Definite volume only, Incompressible. Flowing structure. Takes the shape of its container. Atoms slide past each other. Gas No definite shape or volume. Compressible. Takes the shape & volume of its container. Particles are “far” apart from each other. Relate state to the Kinetic Theory Slowest movement out of all three and thus the lowest energy. Particles are traveling at a faster rate than solids thus the kinetic energy of a liquid is higher than that of a solid. Highest kinetic energy. Fast moving particles. List at least four types of evidence that a chemical change has taken place: 1. precipitate production 2. hue color change (ex: clear to red) 3. temperature change 4. gas production (bubbles are produced) Know the difference between physical properties & chemical properties. Know the difference between homogeneous vs. heterogeneous Homogenous – the same throughout – pure substances, H2O, solutions – sweeten tea Heterogenous – NOT the same throughout – vegetable soup – sugar & sand mixtures Fall 2008 Final Exam Review Atomic Structure Fill out the following chart: Subatomic particle Charge proton neutron electron Relative Mass (amu) 1 1 1/1840 +1 0 -1 Location Inside nucleus Inside nucleus Outside nucleus A positive ion has more protons than electrons. A negative ion has more electrons than protons. A neutral atom has an equal number of protons and electrons. An isotope has the same number of protons of other isotopes of that element, but it contains a different number of neutrons. Isotope U - 240 Atomic Mass Look on periodic table Look on periodic table U - 238 Mass Number 240 Protons 92 Neutrons 148 Electrons 92 238 92 146 92 Helium has two naturally occurring isotopes, helium-3 and helium-4. The atomic mass of helium is 4.003 amu. Which isotope is more abundant in nature? Helium-4 Radioactivity Why does a radioactive isotope undergo radioactive decay? To become stable Type of Radiation Symbol alpha 4 2He beta 0 -1e gamma 0 0Y Penetration ability least Mass 4 amu heaviest 0 most 0 How it affects the nucleus Atomic number decreases by 2; Mass number decreases by 4 Atomic number increases by 1; Mass is not affected. Not affected Describe nuclear fission: Splitting of a nucleus into fragments in order to increase stability. Describe nuclear fusion: The process of binding smaller nuclei into a single larger & more stable nucleus. This is how elements heavier than helium are produced. Define half-life: is the time required for one-half of a radioisotope’s nuclei to decay into its products. Periodicity Fall 2008 Final Exam Review On a periodic table be able to identify the location of the alkali metals, halogens, noble gases, chalcogen, and alkaline earth metals. Alkali metals – s1 – loses 1 electron – Group 1A Alkaline earth metals – s2 – loses 2 electrons – Group 2A Chalcogens – p4 – gains 2 electrons – Group 6A Halogens – p5 – gains 1 electron – Group 7A Noble Gases – p6 – doesn’t lose or gain electrons - STABLE Know the number of valence electrons for each of the groups listed above. Alkali metals – 1 valence electron Alkaline earth metals – 2 valence electrons Chalcogens – 6 valence electrons Halogens – 7 valence electrons Noble Gases – 8 valence electrons Know the electron configuration for each element of the periodic table. Know which elements are solids, liquids and gases. List the liquids: Hg (metal) Br (nonmetal) List the gases: H2, N2, O2, F2, Cl2, plus ALL of the noble gases Know which elements are metals, nonmetals and metalloids. Be able to identify these on a blank periodic table. List the metalloids: B, Si, Ge, As, Sb, Te, Po, At Metals form positive ions Nonmetals form negative ions Give 5 characteristics of a metal: malleable, ductile, good conductor of heat and electricity, reacts with an acid, shiny (has luster) Give 5 characteristics of a nonmetal: brittle, poor conductor of heat and electricity, does NOT react with an acid, dull Describe how electromagnetic radiation is emitted: (know all the steps) 1. A stable atom absorbs energy from an outside source. 2. The atom’s electrons jump to a higher energy level – (this causes the atom to become unstable.) 3. In order for the atom to become stable again, the electrons return to the ground state thus releasing the extra energy in the form of light. Know the following periodic trends: Trend Atomic radius Ionic radius Electronegativity Ionization energy - Across the period Decrease Decrease Increase Increase Down a group Increase Increase Decrease Decrease Fall 2008 Final Exam Review What happens to the radius of an atom that becomes a positive ion? The atom gets MUCH smaller. (radius decreases) What happens to the radius of an atom that becomes a negative ion? The atom gets MUCH bigger (radius increases) Chemical Bonding Describe the following bond types in terms of what happens to the electrons: Ionic Bonds – A bond formed that involves a TRANSFER of electrons. Covalent Bonds – A bond formed when two atoms SHARE electrons between them. Metallic Bonds – A bond formed between two metal ions whereby their electrons are contributed to the “SEA of electrons”. Bonding occurs to satisfy the _octet_ rule. Why? Once the atom has an electron configuration of a noble gas, it becomes stable. Write the formula for the following compounds: Magnesium hydroxide Mg(OH)2 Aluminum nitride AlN______ Aluminum nitrate __Al(NO3)3__________ Aluminum nitrite ___ Al(NO2)3__________ Gold III phosphate ___AuPO4_________ Gold III phosphide ___AuP________ Gold III phosphite ___AuPO3________ Write the formula for the following compounds: Chloric acid ___HClO3___________ Sulfuric acid ____H2SO4________________ Hydrosulfuric acid __H2S_______ Dinitrogen pentoxide _N2O5_____ Name the following: H2CO3 SCl6 CuNO3 Ca3(PO4)2 _carbonic acid__ __sulfur hexachloride__ __copper (I) nitrate___ __calcium phosphate___ Give the name for single bonded hydrocarbons __alkanes__ Give the name for hydrocarbons containing a double bond __alkenes_____ Give the name for hydrocarbons containing a triple bond __alkynes___________ What makes a molecule polar? Due to unevenly shared covalent ponds, one side of a molecule is negative while the other side is positive. Give 2 examples of a polar molecule _water_ ___ammonia____ Fall 2008 Final Exam Review What is meant by “like” dissolves in “like” – polar substances will dissolve in only polar substances. For example, NaCl is polar (sodium is positive and chlorine is negative) so it will dissolve in water, since water is polar. Equations: Relate the Law of Conservation of Mass to a balanced equation. The number and types of atoms must be the same on both sides of the yield sign How would you classify the following equations? _2_MgO _2_ Mg + _1_O2 _2_Na + _1_H2O _2_NaOH + _1_H2 _____decomposition_______ _____single replacement______ 1 NaOH + _1_HCl _1_NaCl + _1_H2O _____double replacement_____ _2_ Mg + __O2 __ C3H8 _2__ MgO + _5_O2 Balance the above equations _3__ CO2 ________synthesis & combustion_ + _4_H2O ____combustion______