Open pit mines and porcelanites in Most Lignite District THE CZECH REPUBLIC IV. THE NORTH BOHEMIAN LIGNITE BASIN The North Bohemian Lignite Basin (Most Lignite District) is the largest Neogene freshwater sedimentary basin (870 km2) in the Czech Republic. The basin is situated among Ústí nad Labem – Most – Chomutov towns. The lignite seam with thickness from 30 to 55 m is exploited from open pit mines with depth from 160 to 210 m. The lignite mining on outcrops of lignite seam started in 1550, but expansion of mining in open pit mines took place after 1946 (Malkovský et al.1985). The production 76 million metric tonne of lignite (before 1991) was reduced and now is about 49 million metric tonne per year. Lignite is used as fuel for power stations. Fossil burning-out of lignite seams on outcrops On the outcrops of fossil burned lignite seam there are many occurrences of porcelanites of early Quaternary age. They originated by thermal alteration and caustic metamorphism of clays and siltstones at temperature ranging from 890°C to 1150°C (Fediuk 1988). In colored porcelanites (Figs. 2 - 10) the variety of minerals (anhydrite, aragonite, cristobalite, epsomite, hallysite, hematite, hyalite, calcite, quartz, limonite, magnetite, opal, gypsum, sulphur, staffeite, wad, and feldspar) including glass occur (Bouška and Dvořák, 1997). The porcelanites were also quarried as stone aggregates for building of temporal roads in open pit coal mines. They found utilisation as a material for production of natural pigments and the selected parts of variegated porcelanites were polished and use as decorative stones. Recent fires in open pit lignite mines and on the waste piles In open pit lignite mines the lignite often underlies to self-ignition, especially in places of historical and mine subsurface workings (Figs. 11 - 16). The spontaneous heating and/or burning of lignite remains also occur on lignite waste piles. According to the temperature (from hot zones near the place of burning to cold condensed zones), big variety of the secondary minerals originated. In the North Bohemian Lignite basin the following secondary minerals have been identified: sulphur, alunogen, mascagnite, realgar, salammoniac, thenardite, hallotrichite, tschermigite, hematite, maghemite and wad. Sulphur, which originates due to thermal decomposition of Fe-sulphides even contains a small amount of native silver (Bouška and Dvořák, 1997). Some of the secondary minerals are presented in Figs 17-22 1 Open pit mines and porcelanites in Most Lignite District Fig. 1 Places with local of porcelanite occurrences (red) and temporary mined lignite seam (light brown) in North Bohemian Lignite Basin. Fig. 2 (Most Lignite District, CR). Outcrop of burning out lignite seam with porcelanites. Dobrčice (50°28´54.6´´N; 13°44´42.6´´ E). Photo by Zdenek Dvořák, 2008. 2 Open pit mines and porcelanites in Most Lignite District Fig. 3 (Most Lignite District, CR). Yellow porcelanite (with high content of TiO2. Dobrčice, outcrop in old quarry. Polished sample. Size of sample 5 x 7 cm. Photo by Zdenek Dvořák, 2008. Fig. 4 (Most Lignite District, CR). Speckled brown-red and blue-greyed porcelanite (with high content of TiO2). Zelénky, outcrops in old quarry (50°36´7.5´´N; 13°47´35.2´´ E). Polished sample. Size of sample 8 x 6 cm. Photo by Zdenek Dvořák, 2008. Fig. 5 (Most Lignite District, CR). Speckled red and blue - greyed porcelanite (with high content of TiO2). Zelénky, outcrops in old quarry. Polished sample. Size of sample 7 x 5 cm. Photo by Zdenek Dvořák, 2008. 3 Open pit mines and porcelanites in Most Lignite District Fig. 6 (Most Lignite District, CR). Yellow porcelanite (for macrophoto of sample see Fig. 3). Mineral composition: mullite, cristobalite and anatase. Thin section, optical microscopy, paralel nicols. Photo by Jiří Ščučka, 2008. Fig. 7 (Most Lignite District, CR). Red spotted porcelanite. (for macrophoto of sample see Fig. 4). Mineral composition: mullite, cristobalite, hematite and anatase with glass. Thin section, optical microscopy, paralel nicols. Photo by Jiří Ščučka, 2008. Fig. 8 (Most Lignite District, CR). Blue-greyed porcelanite with narrow oxidative rim on surface of contractive cracks. Mineral composition: mullite, cristobalite, hematite and anatase with glass in a matrix. Dobrčice. Thin section, optical microscopy, paralel nicols. Photo by Jiří Ščučka, 2008. Fig. 9 (Most Lignite District, CR). Spotted porcelanite with low grade of thermal transformation. Mineral composition: opal, quartz, mullite, cristobalite, hematite and glass. Dobrčice. Thin section, optical microscopy, paralel nicols. Photo by Jiří Ščučka, 2008. 4 Open pit mines and porcelanites in Most Lignite District Fig. 10 (Most Lignite District, CR). Glass origined from lignite ash and clays in place of burned-out lignite seam. Mineral composition: glass, mullite, cristobalite, cordierite, hematite and anatase. Dobrčice. Thin section, optical microscopy, cross nicols. Photo by Jiří Ščučka, 2008. Fig. 11 (Most Lignite District, CR). Spontaneous burning in actual cut in open pit mine in places of historical mine workings in lignite seam. Open pit lignite Mine Bílina (50°34´22.47´´N; 13°43´43.6´´ E). Photo by Karel Mach, 2008. Fig. 12 (Most Lignite District, CR). Detail of spontaneous burning of lignite actual cut in open pit mine in places of location of historical mine workings in lignite seam. Open pit lignite Mine Bílina. Photo by Karel Mach, 2008. 5 Open pit mines and porcelanites in Most Lignite District Fig. 13 (Most Lignite District, CR). Detail of spontaneous lignite burning. Open pit lignite Mine Bílina (50°34´56.0´´N; 13°43´14.4´´ E). Photo by Karel Mach, 2008. Fig. 14 (Most Lignite District, CR). Bucket wheel excavator KU-300 and fire of lignite seam in place of historical mine workings in lignite seam. Open pit lignite Mine Bílina. Photo by Karel Mach, 2008. Fig. 15 (Most Lignite District, CR). Detail of fire in old historical mine working in lignite seam. Open pit lignite Mine Bílina. Photo by Karel Mach, 2008. 6 Open pit mines and porcelanites in Most Lignite District Fig. 16 (Most Lignite District, CR). Spontaneous combustion of rest of lignite in waste pile and origin of native sulphur crust in condensing zone. Open pit lignite Mine Bílina. Photo by Karel Mach, 2008. Fig. 17 (Most Lignite District, CR). Crystals of sulphur in surrounding of place of hot gasses output. Open pit lignite Mine Bílina. Photo: Photo by Jiří Svejkovský, 2008. Fig. 18 (Most Lignite District, CR). Crystals of sulphur on fragment of rock in cool parts of lignite waste pile. Open pit lignite Mine Bílina. Size: 8 cm. Photo by Jiří Svejkovský, 2008. 7 Open pit mines and porcelanites in Most Lignite District Fig. 19 (Most Lignite District, CR). Details of crystal aggregates of native sulphur on the surface of waste pile in condensing zone. Open pit lignite Mine Bílina. Size 10 cm. Photo by Zdenek Dvořák, 2008. Fig. 20 (Most Lignite District, CR). Crystals of kladnoite [(C6H4(CO2)2 NH]. Sample is from cool part surface of lignite waste pile in condensing zone. Size of crystal is 2 mm. Open pit lignite Mine Bílina. Photo by Zdenek Dvořák, 2008. Fig. 21 (Most Lignite District, CR). Arsenic-sulphur melt from surface condensing zone in place of spontaneous lignite burning. Open pit coal Mine Bílina. Size of aggregate is 3 mm. Photo by Zdenek Dvořák, 2008. Fig. 22 (Most Lignite District, CR). Crystals of native sulphur from surface condensing zone in place of spontaneous lignite burning. Open pit coal Mine Bílina. Size of object is 4 mm. Photo by Zdenek Dvořák, 2008. 8