Chem 152 Exam 3 Review and Topics Fall 2004 The third exam picks up where the last one left off, with Chapter 8 (reactions). It will also cover material from Chapter 10, Chapter 12 and Chapter 14. Here is a list of most of the topics we covered. Best way to study: Homework, Homework, Homework. Also, review your quizzes. Chapter 8 1. Evidence for Chemical Reactions 2. Writing Chemical Equations 3. Balancing Chemical Equations 4. Classifying Reactions a. Combination b. Decomposition c. Single Replacement d. Double Replacement i. Formation of Precipitate ii. Neutralization iii. Formation of Gas e. Combustion 5. Single Replacement Reactions a. Predicting Products (Activity Series) b. Writing Ionic and Net Ionic Equations 6. Double Replacement a. Predicting Products b. Writing Ionic and Net Ionic Equations Chapter 10: 1. Stoichiometry Problems a. moles to moles b. moles to grams c. grams to grams 2. Limiting Reactants: Concept and Calculations 3. Percent Yield Calculations Chapter 12: 1. Ionic Bonds 2. Covalent Bonds a. Electron dot structures of molecules b. Electron dot structures of polyatomic ions c. Electronegativities and Polar Covalent Bonds 3. Shapes of Molecules 4. Polar Molecules Chapter 14 (Sections 9 – 10): 1. Definitions: Solute, solvent, solution, concentration 2. Molarity Calculations 3. Dilution Calculations There are some review problems in the textbook (but these are far from a complete review, see note above about homework, quizzes and notes). Answers are below. Pages 224 – 225 Key Concepts: 8 – 10, 13 – 15 Key Terms: 8, 11 – 16 Review Exercises: 12 – 15 Pages 308 - 309 Key Concepts: 7 Review Exercises: 1, 2, 6, 9 (note: in #1, 2 & 6, "STP" means "standard temperature and pressure", it is not needed to do the problem). Pages 396 – 397 Key Concepts: 1, 3 – 5 Key Terms: 1 – 7, 20 Review Exercises: 3 – 5, 13 – 14 ANSWERS TO REVIEW QUESTIONS: Pages 224 – 225 Key Concepts: 8. Hg 9. Ag 10. The reaction is: HCl(aq) + NaHCO3(aq) --> NaCl(aq) + H2O(l) + CO2(g) The bubbles are due to the carbon dioxide gas produced. 13. 2Al(s) + 6HNO3(aq) --> 2Al(NO3)3(aq) + 3H2(g) 15. HNO3(aq) + KOH(aq) --> KNO3(aq) + H2O(l) Key Terms: 8. precipitate 14. double replacement 11. combination 15. neutralization 12. decomposition 16. activity series 13. single replacement Review Exercises: 12. 2 Co(HCO3)3(s) --> Co2(CO3)3(s) + 3 H2O(s) + 3 CO2(g) 13. Co(s) + Ni(NO3)2(aq) --> Co(NO3)2(aq) + Ni(s) 14. Pb(NO3)2(aq) + 2 LiI(aq) --> PbI2(s) + 2 LiNO3(aq) 15. H2CO3(aq) + 2 NH4OH(aq) --> (NH4)2CO3(aq) + 2 H2O(l) Pages 308 – 309 Key Concepts: Review Exercises: 7. a) 2.50 mole O2 b) 5.00 mole SO3 1. 2.26 x 1023 2. 10.5 g 6. 0.389 g CH4 Pages 396 – 397 Key Concepts: 1. ionic bond 3. 5. e- pair geometry (family) = tetrahedral; Key Terms: 1. covalent bond 2. octet rule 3. double bond 4. electronegativity 5. polar covalent bond 9. 57.4 g of Fe HI 4. O2 molecular shape = bent 6. 7. 20. valence shell electron pair repulsion theory (VSEPR) bond angle molarity Review Exercises: 3. 5. 13. 4. e- pair geometry (note: this is the "family" or "shape group" I refered to in lecture, I will not ask you for this on the test, I will ask you for the molecular shape) tetrahedral; molecular shape = trigonal pyramidal; bond angle is a little less than 109.5º (actual bond angle = 107º) 2.00 g NaOH 14. 274 mL