Princeton 2012/Barron 4th ed. AP Practice Problems Unit 5 – Compounds & Moles Multiple Choice (no calculator) For questions 1-2, one or more of the following responses will apply; each response may be used more than once or not at all in these questions. A. B. C. D. E. Moles Liters Grams Atmospheres Volts 1. One mole of solid zinc has a mass of 65.39 of these. (P5.1) 2. These units can be calculated by dividing a quantity by 6.02×1023. (P5.2) 3. What is the mass ratio of fluorine to boron in a boron trifluoride molecule? (P5.4) a. b. c. d. e. 1.8 to 1 3.0 to 1 3.5 to 1 5.3 to 1 6.0 to 1 4. What is the mass of oxygen in 148 grams of calcium hydroxide (Ca(OH)2)? (P5.6) a. b. c. d. e. 16 grams 24 grams 32 grams 48 grams 64 grams 5. An ion containing only oxygen and chlorine is 31% oxygen by mass. What is its empirical formula? (P5.7) a. b. c. d. e. ClOClO2ClO3ClO4Cl2O- 6. What is the percent composition by mass of the elements in the compound NaNO3? (P5.9) a. b. c. d. e. Na 20%, N 20%, O 60% Na 23%, N 14%, O 48% Na 23%, N 14%, O 63% Na 27%, N 16%, O 57% Na 36%, N 28%, O 36% 7. The composition of a typical glass used in bottles is 12.0% Na2O, 12.0% CaO, and 76% SiO2. Which of the following lists the three compounds in order of greatest to least number of moles present in a typical sample of bottle glass? (P5.11) a. b. c. d. e. SiO2, CaO, Na2O SiO2, Na2O, CaO Na2O, SiO2, CaO Na2O, CaO, SiO2 CaO, Na2O, SiO2 Princeton 2012/Barron 4th ed. 8. The concentration of sodium chloride in sea water is about 0.5 molar. How many grams of NaCl are present in 1 kg of sea water? (P5.12) a. b. c. d. e. 30 grams 60 grams 100 grams 300 grams 600 grams 9. A sample of a hydrate of CuSO4 with a mass of 250 grams was heated until all the water was removed. The sample was then weighed and found to have a mass of 160 grams. What is the formula for the hydrate? (P5.13) a. b. c. d. e. CuSO4 10 H2O CuSO4 7 H2O CuSO4 5 H2O CuSO4 2 H2O CuSO4 H2O 10. A compound containing only sulfur and oxygen is 50% sulfur by weight. What is the empirical formula for the compound? (P5.14) a. b. c. d. e. SO SO2 SO3 S2O S3O 11. A sample of a hydrate of BaCl2 with a mass of 61 grams was heated until all the water was removed. The sample was then weighed and found to have a mass of 52 grams. What is the formula for the hydrate? (P5.21) a. b. c. d. e. BaCl2 5 H2O BaCl2 4 H2O BaCl2 3 H2O BaCl2 2 H2O BaCl2 H2O 12. A hydrocarbon was found to be 20% hydrogen by weight. If 1 mole of the hydrocarbon has a mass of 30 grams, what is its molecular formula? (P5.22) a. b. c. d. e. CH CH2 CH3 C2H4 C2H6 13. A hydrocarbon contains 75% carbon by mass. What is the empirical formula for the compound? (P5.24) a. b. c. d. e. CH2 CH3 CH4 C2H5 C3H8 14. When chlorine gas is combined with fluorine gas, a compound is formed that is 38% chlorine and 62% fluorine. What is the empirical formula of the compound? (P5.25) a. b. c. d. e. ClF ClF2 ClF3 ClF5 ClF7 Princeton 2012/Barron 4th ed. For questions 16-18, one or more of the following responses will apply; each response may be used more than once or not at all in these questions. I. II. III. IV. V. ammonium ion calcium ion bromide ion iron (III) phosphate ion 15. Which of these carries a single negative charge? (B4.1) a. b. c. d. e. I II III IV V 16. Which pair of these will form a compound? (B4.2) a. b. c. d. e. I and II II and IV III and V I and IV II and V 17. How many different compounds can be made from these ions? (B4.3) a. b. c. d. e. 1 2 4 6 9 18. Which of the following is the permanganate ion? (B4.7) a. ClO4b. PO4-3 c. MnO2 d. SO4-2 e. MnO4- 19. The correct name for Fe(NO3)3 is (B4.9) a. b. c. d. e. Iron nitrite Iron (II) nitrate Ferrous nitroxide Iron (III) sulfate Iron (III) nitrate 20. What is the formula for an ionic compound formed from aluminum and chlorine? (B4.13) a. b. c. d. e. AlCl Al3Cl Al3Cl3 AlCl3 Al2Cl3 21. Which of the following is NOT correctly named? (B4.15) a. Clchloride ion b. ClO- hypochlorite ion c. ClO4- perchlorate ion d. ClO2- chlorous ion e. ClO3- chlorate ion 22. Which of the following is NOT a correct chemical formula? (B4.16) a. b. c. d. e. SrBr2 Ca2O3 Mg3N2 Na2S AlI3 23. Which of the following is a correct formula? (B4.17) a. b. c. d. e. NH4SO3 CaC2H3O2 Na2ClO4 Ba(CO3)2 KH2PO4 Princeton 2012/Barron 4th ed. For questions 24-26, one or more of the following responses will apply; each response may be used more than once or not at all in these questions. I. II. III. IV. V. molarity mass percentage molar mass empirical formula molecular formula 24. For the compound FeCl3 we can, with the aid only of a periodic table determine its (B6.1) a. b. c. d. e. I and III II III and V II, III, and IV V 25. We can determine the ______ if we know the _______. (B6.3) a. b. c. d. e. I, III II, III III, V IV, II V, I 26. We can determine the ______ if we know the ______ and ______. (B6.4) a. b. c. d. e. I, III, II II, I, V V, III, IV IV, I, II V, III, I 27. What is the simplest formula for a compound composed of only carbon and hydrogen and containing 14.3% H? (B6.8) a. b. c. d. e. CH CH4 C4 H CH2 CH3 28. What is the molar mass of Al(NO3)3? (B6.9) a. 165.00 b. 56.99 c. 213.00 d. 88.99 e. 184.99 29. A substance has an empirical formula of CH2. Its molar mass is determined in a separate experiment as 83.5. What is the most probable molecular formula for this compound? (B6.14) a. b. c. d. e. C2H4 C6H2 C4H2 CH12 C6H12 30. What is the percentage of potassium in K3PO4? (B6.17) a. b. c. d. e. 14.6% 29.2% 18.4% 55.2% 39.1% Princeton 2012/Barron 4th ed. 31. Which of the following is NOT a base metric unit (SI unit)? (B6.19) a. b. c. d. e. Meter Liter Mole Second Kilogram 32. Determine the empirical formula for a compound that is 25% hydrogen and 75% carbon. (B6.24) a. b. c. d. e. CH CH2 CH4 C2H8 C4 H Princeton 2012/Barron 4th ed. Answer Key Unit 5 – Compounds and Moles Multiple Choice 1. C 2. A 3. D 4. E 5. A 6. D 7. A 8. A 9. C 10. B 11. D 12. E 13. C 14. C 15. C 16. E 17. D 18. E 19. E 20. D 21. D 22. B 23. E 24. D 25. D 26. C 27. D 28. C 29. E 30. D 31. B 32. C