Physical and Chemical Reactions physical change - change of state, solid (s), liquid (l), gas (g), dissolving (aq) - involves intermolecular bonds rearrangements: chemical change/ chemical reaction - a reaction during which substances change into one or more new substances with different physical and chemical properties - re-arrangement of intramolecular bonds reactants --> products CHEMICAL REACTIONS Law of Conservation of Matter - in any chemical reaction, the mass of the products is always equal to the mass of the reactants, matter can't be created or destroyed So… making chocolate chip cookies have to have chocolate chips… recognizing chemical reactions - generally you will observe one or more of: - colour change - formation of a solid (when formed from two aq: precipitate) - formation of a gas - heat change Types of Chemical Reactions 1. Synthesis Reactions -the combination of two or more simple substances to form a more complex substance -also known as combination or addition reaction A + B --> AB H2 (l) + O2 (l)--> H2O (g) balance: 2H2 + O2 --> 2 H2O --> used to fuel space shuttles: Challenger exploded due to leaky O-ring special case: Combustion Reaction -if oxygen rapidly reacts with another element it can form a more complex compound by burning C(s) + O2 (g) --> CO2 (g) S (s) + O2 (g) --> SO2 (g) 2. Decomposition Reactions -the breakdown of large, more complex molecules or ionic compounds into smaller and simpler entities AB--> A + B 2 H2O2 (l) --> O2 (g) + 2 H2O (l) (hydrogen peroxide) Coefficient up front tells you that there are two H2O2 special case: thermal decomposition - decomposition reactions that occur as a result of heating ex. H2CO3 (aq) (carbonic acid) CO2 (g) + H2O (l) So…showing experimental conditions in chemical reactions: symbol meaning C Fe uv light the reactants are heated reactants are heated to a particular T reaction is performed in presence of catalyst (helps rxn go faster) light energy is necessary for the reaction (in this case uv light) Writing Chemical Equations word equation: identifies reactant and product by name, ex. sodium + chlorine --> sodium chloride -not much info, too long skeleton equation: lists reactants and products with + and --> signs, shows state ex. Na (s) + Cl2 (g) --> NaCl (s) -count up the number of atoms: has to be the same on both sides balanced chemical equation: reflects the law of conservation of mass ex. 2 Na(s) + Cl2 (g) --> 2 NaCl Steps in Balancing Chemical Equations 1. is the skeleton equation accurate? 2. balance atoms on both sides, other than H and O 3. polyatomic ions are balanced as a whole IF whole on both sides 4. balance H, O 5. balance lone elements, ex. Cl2 6. check! ex1. sulfur dioxide gas reacts with oxygen gas to produce gaseous sulfur trioxide 2 SO2 (g) + O2 (g) --> 2 SO3(g) ex2. when dissolved in water, copper (II) nitrate reacts with potassium hydroxide to form a water-soluble potassium nitrate and solid copper (II) hydroxide precipitate Cu(NO3)2 (aq) + 2KOH (aq) --> 2KNO3 (aq) + Cu(OH)2 (s) In Groups Balance 1. KOH + SO2 --> K2SO3 + H2O 2. Al4C3 + H2O --> Al(OH)3 + CH4 3. Na2CO3 + H3PO4 --> Na3PO4 + H2O + CO2 Worksheets on Balancing: matter12balancingwsht matter12balancingwsht2 matter12balancingwsht3 matter12balancingwshtpolyat 4. CaC2 + H2O --> Ca(OH)2 + C2H2 5. Al + NaOH --> Na2AlO3 + H2 6. KNO3 --> KNO2 + O2 UNIT 1 PORTFOLIO Write a BALANCED chemical equation for each of these chemical reaction statements. 1) sulphur trioxide gas and water combine to form sulphuric acid 2) when dissolved in water, lead II nitrate and sodium iodide react to make aqueous lead iodide and sodium nitrate 3) when dissolved beryllium chloride reacts with dissolved silver nitrate in water, aqueous beryllium nitrate and silver chloride powder are made. 4) solid zinc and aqueous copper II sulphate yield aqueous zinc sulphate and copper metal 5) aluminum metal reacts violently with chlorine gas to produce a white solid