Chemistry Chapter 11 11.1 Class No.: _____ Occurrence and extraction of metals Oral Presentation (2 groups will be selected for presentation.) Search the internet (or other resources) for the occurrence of metals and the uses of metals in daily life. Websites for references: 1) Some common minerals and their uses http://www.nma.org/about_us/publications/pub_minerals_uses.asp http://www.mii.org/commonminerals.php#chrom 2) Minerals and metals for the worlds http://www.riotinto.com/library/reports_PDFs/corpPub_CorpBrochure_MineralsMetal.pdf Please summarize your classmates’ presentation: Hand in your summary at the end of the lesson. Chemistry Worksheets / HKCWCC / Chapter 11 Marks P. 1 Chemistry Chapter 11 11.2 Class No.: _____ Occurrence and extraction of metals Uses related to the properties of metals Complete the following table: Metal Iron Copper Aluminium Uses Reasons for uses For construction, building Hard, strong, malleable and ductile, & cheap bridges, and the body of vehicles Making magnet Magnetic For making electrical wire, Excellent conductor of electricity, ductile and corrosion resistant. water pipes, Non-poisonous, malleable & ductile, corrosion resistant and cooking utensils Excellent conductor of heat, Non-poisonous. For making overhead power Very good conductor of electricity, low density, cables, ductile. aircraft body, Light but strong, corrosion resistant saucepans, kitchen foils, Very good conductor of heat, non-poisonous, corrosion resistant, malleable. soft drink can, Non-poisonous, low density, corrosion resistant, and malleable. & window frames. Strong, corrosion resistant Titanium For making aircraft supersonic Light but very strong, very corrosion resistant, malleable Gold For jewellery, coins, Attractive golden yellow colour, extremely corrosion resistant, most malleable and ductile shield for heat, and radiation Excellent reflective quality Mercury For thermometers Liquid at room temperature, expands on heating Silver For jewellery, coins, Attractive silvery colour, corrosion resistant, malleable and ductile electrical and components Chemistry Worksheets / HKCWCC / Chapter 11 electronic Good conductor of electricity, ductile and corrosion resistant. P. 2 Chemistry Class No.: _____ Chapter 11 11.3 Occurrence and extraction of metals Metal ores Which metals are found free in the Earth? Why ? Unreactive metals, such as gold and platinum (at the bottom of the reactivity series), are found free in the Earth’s crust. Metals are usually found in the form of compounds. Which kinds of compounds are found in ores? Metal oxides, carbonates and sulphides are found in metal ores. Are these metal compounds soluble in water? They are insoluble in water. Name some common metal ores: Metal Aluminium Formula of the compound bauxite Aluminium oxide Al2O3 Copper pyrites Copper iron(II) sulphide CuFeS2 Iron Haematite Iron(III) oxide Fe2O3 Lead Galena Lead(II) sulphide PbS Copper 11.4 Name of the main ore Compound found in ore Extraction of metals form their ores What are the three methods for extracting a metal from its ores? 1) Heating the metal ore/oxide alone. 2) Heating the metal ore/oxide with carbon/coke. 3) Electrolysis of hot molten ores. a) Heating the metal ore / oxide alone What do you observe when zinc oxide is heated? The white solid turns yellow. What do you see when the hot zinc oxide is allowed to cool? The yellow solid turns white. Chemistry Worksheets / HKCWCC / Chapter 11 P. 3 Chemistry Chapter 11 Class No.: _____ Occurrence and extraction of metals Is there any metal formed? No, there isn’t any metal formed. Which metal oxides give metal when heated? Merucry(II) oxide and silver oxide Write chemical equations for the thermal decomposition of i) mercury(II) oxide : ii) silver oxide: 2HgO(s) 2Hg(l) + O2(g) 2Ag2O(s) 4Ag(s) + O2(g) b) Heating metal ore / oxide with carbon i) lead(II) oxide What do you see when lead(II) oxide is heated alone? The yellow solid turns orange. Is there any lead metal formed? No, there isn’t any metal formed. Heat lead(II) oxide in a charcoal block. (Heat lead(II) oxide with coke.) What do you see? Silvery beads of molten lead are formed. Write a chemical equation for the reaction involved. 2PbO(s) + C(s) 2Pb(s) + CO2(g) ii) copper(II) oxide What do you see when copper(II) oxide is heated alone? No observable change. Heat copper(II) oxide in a charcoal block. (Heat copper(II) oxide with coke.) What do you see? Reddish brown solid copper is formed. Write a chemical equation for the reaction involved. 2CuO(s) + C(s) 2Cu(s) + CO2(g) Chemistry Worksheets / HKCWCC / Chapter 11 P. 4 Chemistry Class No.: _____ Chapter 11 Occurrence and extraction of metals iii) zinc oxide Heat zinc oxide in a charcoal block. What do you see? The white solid turns yellow. Why? The hot Bunsen flame does not provide high enough temperature to start the reduction of zinc oxide by carbon. N.B. Which metal is more reactive, lead or zinc? Zinc is more reactive than lead. Which metal, zinc or lead, forms a more stable oxide? Zinc forms a more stable metal oxide than that of lead. Bunsen flame is not hot enough to remove oxygen from zinc oxide. N.B. What is oxidation? Give examples of oxidation: Oxidation is the process in which oxygen is added to a substance. What is reduction? Reduction is the process in which oxygen is removed from a substance. Give examples of reduction: Lead is formed when lead oxide is heated with carbon. N.B. Name the type of reaction by which metal is extracted from its oxide by heating with carbon. Reduction of metal oxide by carbon / Redox reaction. What is the role of carbon in the reaction? Reading assignment: Reducing agent. Read 11.7 Extraction of iron from haematite in industry (P.244) Chemistry Worksheets / HKCWCC / Chapter 11 P. 5 Chemistry Chapter 11 Class No.: _____ Occurrence and extraction of metals iv) galena, lead(II) sulphide Give the chemical formula of lead(II) sulphide: How lead is extracted from galena? PbS Heat (Roast) lead(II) sulphide in air to form lead(II) oxide. Heat lead(II) oxide with carbon to form lead. Write chemical equations for the reaction involved. 2PbS(s) + 3O2(g) 2PbO(s) + C(s) c) 2PbO(s) + 2SO2(g) 2Pb(s) + CO2(g) Extraction of metals by the electrolysis of its hot molten ores Which metals are extracted by the electrolysis of molten ores? Reactive metals (metals that are above zinc in the reactivity series) are extracted by the electrolysis of molten ores. N.B. It is an expensive method. Examples: Electrolysis of hot molten bauxite, Electrolysis of molten sodium chloride. 11.5 Discovery of metals Read Table 11.2 (P. 237) What is the relationship between the year of discovery of metals and the relative reactivity of metals? The more reactive the metal, the more stable is its compounds and the more difficult is it to be extracted. Thus, these metals will a short history and was extracted by Man recently. N.B. Uncreative metals, such as gold and platinum, are found free in nature. Read Table 11.3 Different Ages in human civilization (Stone, Copper, Bronze, & Iron Age) Chemistry Worksheets / HKCWCC / Chapter 11 P. 6 Chemistry Chapter 11 Class No.: _____ Occurrence and extraction of metals 11.6 Factors affecting the discovery and use of metals 1) 2) 3) The price of metals depends mainly on: 1) 2) 3) 11.7 Conserving metals Why we need to conserve metals? Ways to conserve metals 1) 2) 3) Importance of recycling: 1) 2) 3) 4) Recycling involves ____________, ___________, ___________, and ____________ the metal, and ______________any unwanted substances. The used metals are then __________ and ____________ into other shapes, Chemistry Worksheets / HKCWCC / Chapter 11 P. 7 Chemistry Chapter 11 Class No.: _____ Occurrence and extraction of metals 11.8 Extraction of iron from haematite in industry (Blast Furnace) Raw materials: ________________________________________________________________ A mixture of ___________, __________ and _____________ is added at the top of the furnace. ________ air is blown into the furnace from the bottom. A chain of chemical reactions occur: 1) Carbon reacts with oxygen in air to form ______________. Equation: ___________________________________________________________________ 2) The hot carbon dioxide rises in the furnace and is reduced by _________ to form __________ . Equation: ___________________________________________________________________ 3) Carbon monoxide is a ____________ agent. It ___________ iron(III) oxide in haematite to form hot molten ___________. Equation: ____________________________________________________________________ The hot molten iron is then rum out from the bottom of the furnace. 4) The formula of limestone: ________________ Limestone breaks up _______________ and ________________ when heated. Equation: ____________________________________________________________________ 5) Calcium oxide helps to remove _______________ (the impurities) to form a liquid ‘_______’. Equation: _________________________________________________________________ Chemistry Worksheets / HKCWCC / Chapter 11 P. 8