Writing Balanced Chemical Equations (2): 13. Zinc metal reacts with hydrochloric acid to produce dissolved zinc chloride and gaseous hydrogen. Zn(s) + 2 HCl(aq) ZnCl2(aq) + H2(g) 15. Pure hydrogen gas burns in atmospheric oxygen to produce water vapor. 2 H2(g) + O2(g) 2 H2O(g) 17. Silver metal dissolves in concentrated nitric acid, producing brown NO2 gas, water, and dissolved silver nitrate. Ag(s) + 2 HNO3(aq) NO2(g) + H2O(g) + AgNO3(aq) 19. Elemental boron is produced by heating solid diboron trioxide with magnesium metal. Also produced in the reaction is solid magnesium oxide. B2O3(s) + 3 Mg(s) 2 B(s) + 3 MgO(s) 21. Phosphorus trichloride, a highly toxic fuming liquid, is used in the manufacture of certain pesticides. It is synthesized by direct combination of white phosphorus gas (P4) and chlorine gas. P4(g) + 6 Cl2(g) 4 PCl3(l) 23. Nitrous oxide gas (systematic name: dinitrogen monoxide) is used in dentistry as an anesthetic. Nitrous oxide (and water vapor as a by-product) can be produced in small quantities in the laboratory by careful heating of ammonium nitrate. 2 NH4NO3(s) N2O(g) + 2 H2O(g) 25. Acetylene gas (C2H2) is often used is used for welding because it burns in oxygen with an intensely hot flame. The products of the combustion are carbon dioxide gas and water vapor. 2 C2H2(g) + 5 O2(g) 4 CO2(g) + 2 H2O(g) 27. Barium can be produced in the solid elemental state by the reaction of solid barium oxide with aluminum metal at high temperatures. Solid aluminum oxide is a by-product. 3 BaO(s) + 2 Al(s) 3 Ba(s) + Al2O3(s) 29. Carbon tetrachloride is a liquid solvent widely used for many years in the dry cleaning industry until its harmful properties became well known. It is prepared by reacting natural gas (methane, CH4) and chlorine gas in the presence of ultraviolet light. Hydrogen chloride gas is a by-product. CH4(g) + 2 Cl2(g) CCl4(l) + 2 H2(g)