Fall 2010 CHML212 All Sections COURSE WEBSITE: http://www.uncw.edu/chem/courses/chmL212/ REQUIRED TEXTS: Organic Chemistry: Chemistry 211-212 Laboratory Manual (Fall 2009 Edition—Blue cover) Organic Chemistry Laboratory Notebook PREREQUISITE: CHML211 Day: EXP# 8/26 13 Introduction, 9/2 Safety, 14 9/9 15 9/16 9/23 9/30 10/7 10/14 10/21 10/28 11/4 11/11 11/18 16 17 17(cont.) 18 19 20 21 22 23 24 TENTATIVE SCHEDULE EXPERIMENT TITLE Calculation, Chromatographic, and Spectral Applications IR and NMR Identification of an Unknown Substituent Effects on the Rate of Electrophilic Aromatic Substitution (QUIZ 1: Exp. 13,14) Synthesis of p-methylacetanilide Nitration of p-methylacetanilide (Synthesis and Purification) Nitration of p-methylacetanilide (Product Analysis) (QUIZ 2: Exp. 15,16,17) The Grignard Reaction Oxidation of 9-Fluorenol Sodium Borohydride Reduction of a Ketone Ester Synthesis: Flavors and Fragrances (QUIZ 3: Exp. 18,19,20) The Solventless Aldol-Type Condensation Theory of Color in Organic Compounds: Preparation of Organic Dyes Synthesis and GC Analysis of Fatty Acid Methyl Esters (QUIZ 4: Exp. 21,22,23,24) Course Grading and Policies 93-100 = A, 90-92 = A-, 87-89 = B+, 83-86 = B, 80-82 = B-, 77-79 = C+, 73-76 = C, 70-72 = C-, 67-69 = D+, 63-66 = D, 60-62 = D-, <60 = F. Attendance and Safety: No one is admitted to lab after the first 10 minutes or without closed toe shoes, lab manual or safety glasses. You must attend your scheduled lab. There are no make-up labs. If you miss a lab, you will receive a score of 0 for that day. At the end of the semester, your lowest lab grade will be dropped. If you miss three or more labs (including those for which you were more than 10 minutes late) you will receive a grade of “F” for the entire course. Any student who does has not taken and received a passing grade for CHML211 will be administratively withdrawn from the course. Lab Quizzes (50%): 4 short lab quizzes will be given, testing on 2-4 experiments each. Study guides will be provided on the course website. There will be a full lab experiment after every lab quiz. There are no make-up quizzes; however the lowest lab quiz score will be dropped. Laboratory Notebook (~10%) Your notebook will consist of pre-lab and in-lab entries as described in class, in Appendix C in the lab manual, and on the course website. Each student will submit yellow carbon pages containing pre-lab notebook entries at the beginning of the lab period, and yellow carbon pages containing in-lab entries attached to the final lab report when submitted. Laboratory Reports (~30%) Due dates will be announced by lab instructor. Late lab reports will receive a penalty of 5% of total grade per day. Unless previously arranged with instructor, once graded lab reports are returned to students, no more lab reports will be accepted. Lab Technique (~10%) Up to 10% of the final grade for each experiment will be based on technique. In order to receive the maximum score on the technique portion of your grade, you must do the following: Keep up with the glassware from your lab drawer. Return it to the lab drawer clean and dry, as well as to the drawer from which it came. Keep your work area clean and clean up after yourself. Equipment cords must be unplugged, wrapped, and the equipment pushed to the back of the hood before leaving. Bring your own safety goggles and wear them at all times while in the lab. Come to lab prepared to do an experiment, having prelab completed, and ready to participate in the experiment. Write things down in your lab notebook as you do the experiment. Be sure to submit samples to instructor when required. This applies to samples for instrumental analysis and samples for storage. If you throw out your samples too early, you will not have all of the results needed to complete an assignment. Turn in materials on time. Be safe! Be familiar with the hazards of the chemicals to be used during an experiment. Obey your safety contract at all times! *** At the end of the semester, each student will be responsible for the contents and cleanliness of their lab drawers. Any student leaving their assigned lab drawer missing glassware, or with dirty glassware, will be penalized on their technique grade, resulting in a lower lab grade. *** Use of Personal Electronics Cell phone use will not be tolerated in this class. Turn off your cell phones prior to class. If your cell phone rings, you will be asked to leave the class. Refusal to identify the source of the ringing will result in dismissal for the entire class, with the entire class receiving a zero for the lab. Laptops and desktop computer use is allowed for lab related materials ONLY. Any student seen engaging in non-laboratory related activity will be asked to leave the class, and will receive a zero for the lab. Learning Outcomes A student taking this course in the Department of Chemistry and Biochemistry at UNCW will demonstrate the ability to perform laboratory-based experiments, utilizing appropriate equipment, applying proper procedures and adhering to safety guidelines Academic Integrity All members of UNCW’s community are expected to follow the academic Honor Code. Please read the UNCW Honor Code carefully (as covered in the UNCW Student Handbook). Academic dishonesty in any form will not be tolerated in this class. Please be especially familiar with UNCW’s position on plagiarism as outlined in the UNCW Student Handbook. Plagiarism is a form of academic dishonesty in which you take someone else’s ideas and represent them as your own. Students with Disabilities Students with diagnosed disabilities should contact the Office of Disability Services (962-7555). Please submit a copy of the letter you receive from Office of Disability Services detailing class accommodations you may need. If you require accommodation for test-taking, please be sure to have referral letter submitted no less than 3 days before the test. Violence and Harassment UNCW practices a zero tolerance policy for any kind of violent or harassing behavior. If you are experiencing an emergency of this type contact the police at 911 or UNCW CARE at 962-2273. Resources for individuals concerned with a violent or harassing situation can be located at http://www.uncw.edu/wsrc/crisis.html.