CV Geology GEOUNITS Ke Kucg Kush Qa Qca Qg Qls Qoa Qog Qs Qsb Tcd Tcdss Tcw Tcwsh Tjsh Tjss Tm Tma Tmash Tml Tp Tr Tsbs Tsp Tspss Tsq fc fg fs ocean water Figure 3.1: Dibblee geologic formations for the Carpinteria Valley (Diblee, 1988). Faults are in dark brown, watershed boundaries in yellow, and stream monitoring points in red. The important formations are the Matilija Sandstone (Tma), Juncal Formation (Tjsh), Coldwater sandstone (Tcw, Tcwsh, Tmash), Cozy Dell Shale (Tcd, Tcdss), Sespe Formation (Tsp and Tspss), foothill alluvial fans of silt sand and gravel (Qoa, Qog, Qca), and coastal plain fluvial sediments (Qa, Qs). 138 D C B A Figure 3.2: Hydrologic soil groups (A-D) for the Carpinteria Valley; soils with high (A), moderate (B), low (C), and limited (D) infiltration capacity. 139 Uplands Foothills Rapid runoff Coastal plain Area Upland Foothill Coastal Plain Rapid Runoff (ha) (%) (%) (%) (%) Santa Monica 981 95 2 2 1 Franklin 1112 38 15 29 17 Carpinteria 3998 78 9 10 3 Figure 3.3: Morphological unit with percentages of each category by watershed for the Carpinteria Valley. 140 SM05 SM04 SM01 FK06 FK04 FK03 FK07 FK00 CP05 GB04 CP02 CP20 CP00 CP30 Kilometers 0 0.5 1 2 3 4 Figure 3.4: Watersheds of the Carpinteria Valley (34o24’N, 119o30’W). Sampling points are shown in red. Colored polygons distinguish the contributing area for each sampled subcatchment. The Carpinteria Salt Marsh is demarked with a green stipple. 141 Figure 3.5: A close up of the urban-agricultural fringe on Santa Monica and Franklin creeks showing the detailed digitizing done for the 2002 land use classification effort. Land use boundaries are in yellow with the watershed boundaries and sampling points in red. 142 1929 1976 2002 Figure 3.6: Aerial photographs of land use in 1929, 1976 and 2002. The watershed boundaries and drainage network are included for reference. 143 1200 100 Baseflow Stormflow 1000 80 Rainfall 60 800 600 40 Rainfall (cm) Annual discharge (10 3 m 3) 1400 400 20 200 0 0 SM-WY02 FK-WY02 CP-WY02 SM-WY03 FK-WY03 CP-WY03 Figure 3.7: Baseflow and stormflow in thousands of cubic meters at the outlet sites for each watershed: Santa Monica, Franklin, and Carpinteria creek watersheds. Distributed rainfall in centimeters shows the differences between a drought year and a year with above average precipitation. 144 SM05 SM04 CP05 SM01 FK03 FK06 FK07 GB04 FK00 CP02 CP00 Figure 3.8: Inline sampling sites on Santa Monica, Franklin, and Carpinteria creeks. Reaches with intermittent flow are shown with a dashed line, concrete lined channels are shown in dark green (storm drains in dashed green), and the Carpinteria Salt Marsh is demarked with a stipple pattern. 145 1200 1000 80 Baseflow Stormflow Rainfall 70 60 50 800 40 600 30 400 Rainfall (cm) Annual discharge (10 3 m 3) 1400 20 200 10 0 0 CP00 CP02 CP05 GB04 CP00 CP02 CP05 GB04 Figure 3.9: Annual stormflow and baseflow conditions for Carpinteria Creek. Distributed rainfall amounts for each subwatershed are shown for comparison. 146 1000 NH4 NO3 DON PO4 Annual export (mol ha -1) 100 10 1 0.1 CP00 CP02 CP05 GB04 ---------------------- WY2002 ------------------- CP00 CP02 CP05 ---------------------- WY2003 ------------------- Figure 3.10: Annual nutrient export (mol ha-1) for Carpinteria Creek watershed for WY2002 and WY2003. 147 GB04 Nutrient export (mol ha -1 ) 100 NO3-Baseflow NO3-Stormflow PO4-Baseflow PO4-Stormflow 10 1 0.1 CP00 CP02 CP05 GB04 CP00 CP02 CP05 GB04 Figure 3.11: Annual baseflow and stormflow nutrient export (mol ha-1) for Carpinteria Creek for WY2002 and WY2003. 148 100 CP00 (a) CP02 Nitrate export (mol ha -1) CP05 10 GB04 1 0.1 0.01 11/7 34 12/14 1 12/16 212/19 12/28 2/11 224 6 43 12/12 2/24 11 3/15 16 4/13 25 5/2 16 10 Phosphate export (mol ha -1) (b) CP00 CP02 CP05 GB04 1 0.1 0.01 11/7 12/14 12/16 12/19 12/28 2/11 2/12 2/24 3/15 4/13 5/2 20 1000 Storm discharge (10 3 m3) (c) CP00 CP02 CP05 GB04 Rainfall 100 18 16 14 12 10 10 8 Rainfall (cm) 10000 6 1 4 2 0.1 0 11/7 12/14 12/16 12/19 12/28 2/11 2/12 2/24 3/15 4/13 5/2 Figure 3.12: Event-based flux of (a) nitrate and (b) phosphate, as well as (c) runoff-rainfall for WY2003 on Carpinteria Creek. Distributed rainfall amounts for the watershed are provided and the numbers of days since the previous storm are shown in gray between the panels (a+b). 149 1200 3 GB04 Outlet flow 800 3 3 -1 (a) Discharge (m s ) Nitrate concentration (µM) 1000 4 CP00 CP02 CP05 2 600 2 400 1 200 1 0 0 11/6 11/7 11/8 11/9 11/10 11/11 11/12 11/13 500 (b) CP00 CP02 400 20 CP05 GB04 300 Outlet flow CP02 flow 250 15 10 200 150 3 -1 350 Discharge (m s ) Nitrate concentration (µM) 450 5 100 50 0 3/14 0 3/15 3/16 3/17 3/18 Figure 3.13: Nitrate concentrations on Carpinteria Creek during the (a) 11/7/02 and (b) 3/15/03 storms of WY2003. Discharge at the outlet and midbasin (CP02, only for the second storm) sites are included. 150 4 (a) CP02 CP05 50 GB04 Outlet flow 40 3 2 30 2 20 1 10 1 0 0 11/6 11/7 11/8 11/9 11/10 11/11 11/12 35 Phosphate concentration (µM) 3 30 Discharge (m 3s -1) 60 CP00 11/13 25 CP00 (b) CP02 CP05 GB04 25 Outlet flow 20 20 15 CP02 flow 15 10 10 5 5 0 3/14 0 3/15 3/16 3/17 3/18 Figure 3.14: Phosphate concentrations on Carpinteria Creek during the (a) 11/7/02 and (b) 3/15/03 storms of WY2003. Discharge at the outlet and midbasin (CP02, only for the second storm) sites are included. 151 Discharge (m 3s-1) Phosphate concentration (µM) 70 10 FK00-temperature CP00-temperature FK00-discharge CP00-discharge 35 Temperature ( o C) 30 25 9 8 7 6 20 5 4 15 3 Dicharge (m 3 s-1 ) 40 10 2 5 1 0 4/18 0 4/19 4/20 4/21 4/22 Figure 3.15: Outlet stream water temperatures and corresponding discharge on an open-canopy, concrete-lined channel (FK00) and a natural bottomed stream (CP00) with an intact riparian canopy during clear skies in April, 2002. The variance of stream flow on Franklin Creek is an indication of anthropogenic releases upstream. 152 900 Annual discharge (10 Baseflow Stormflow Rainfall 60 50 600 500 40 400 30 300 20 200 10 100 0 0 FK00 FK03 FK06 FK07 FK00 FK03 FK06 FK07 Figure 3.16: Annual stormflow and baseflow conditions for Franklin Creek. Distributed rainfall for each subcatchment is provided for comparison. 153 Rainfall (cm) 700 3 m 3) 800 70 10,000 NH4 NO3 DON PO4 Annual export (mol ha -1 ) 1,000 100 10 1 0 FK00 FK03 FK06 FK07 --------------------- WY2002 ------------------ FK00 FK03 FK06 FK07 -------------------- WY2003 ------------------- Figure 3.17: Annual nutrient export (mol ha-1) for Franklin Creek watershed for WY2002 and WY2003. 154 10000 Nutrient export (mol ha -1 ) NO3-Baseflow PO4-Baseflow NO3-Stormflow PO4-Stormflow 1000 100 10 1 0.1 FK00 FK03 FK06 FK07 FK00 FK03 FK06 FK07 Figure 3.18: Annual baseflow and stormflow nutrient export (mol ha-1) for Franklin Creek for WY2002 and WY2003. 155 1000 FK00 FK03 FK06 FK07 Nitrate export (mol ha -1) (a) 100 10 1 0 11/7 12/14 12/16 224 34 1 12/19 12/28 2 6 2/11 43 2/12 1 2/24 11 3/15 16 4/13 25 5/2 16 10 FK00 Phosphate export (mol ha -1) (b) FK03 FK06 FK07 1 0.1 0.01 11/7 12/14 12/16 12/19 12/28 2/11 2/12 2/24 3/15 4/13 5/2 10000 18 1000 FK03 FK07 16 14 12 100 10 8 10 Rainfall (cm) Storm discharge (10 3 m3) (c) FK00 FK06 Rainfall 6 4 1 2 0.1 0 11/7 12/14 12/16 12/19 12/28 2/11 2/12 2/24 3/15 4/13 5/2 Figure 3.19: Event-based fluxes (a) nitrate and (b) phosphate as well as (c) runoff-rainfall for WY2003 on Franklin Creek. Distributed rainfall amounts for the watershed are provided and the numbers of days since the previous storm are shown in gray between the panels (a+b). 156 4500 (a) 8 FK06 7 3000 FK07 6 Outlet flow 2500 5 2000 4 1500 3 1000 2 500 1 0 0 11/6 11/7 11/8 11/9 11/10 11/11 3000 11/12 11/13 16 (b) FK00 14 FK03 2500 Nitrate concentrations (µM) 3 -1 3500 Discharge (m s ) FK03 FK06 12 FK07 2000 10 Outlet flow 1500 8 6 1000 Discharge (m 3 s-1 ) Nitrate concentrations (µM) 4000 9 FK00 4 500 2 0 3/14 0 3/15 3/16 3/17 3/18 Figure 3.20: Nitrate concentrations for the (a) 11/7/02 and 3/15/03 storms of the year on Franklin Creek. 157 9 FK03 8 FK06 7 FK07 80 6 Outlet flow 5 60 4 40 3 2 20 1 0 0 11/6 11/7 11/8 11/9 11/10 11/11 11/12 11/13 60 16 (b) Phosphate concentrations (µM) 3 -1 (a) 100 Discharge (m s ) FK00 FK00 14 FK03 50 FK06 12 FK07 40 Outlet flow 30 10 8 6 20 4 10 2 0 3/14 0 3/15 3/16 3/17 3/18 Figure 3.21: Phosphate concentrations for the (a) 11/7/02 and (b) 3/15/03 storms of the year on Franklin Creek. 158 Discharge (m 3 s-1 ) Phosphate concentrations (µM) 120 80 5 70 Stormflow 60 Rainfall 50 3 40 2 30 20 Annual rainfall (cm) Annual discharge (cm) Baseflow 4 1 10 0 0 SM05 CP05 GB04 SM05 -------------------- WY2002 ------------------ CP05 GB04 -------------------- WY2003 ------------------ Figure 3.22: Annual baseflow, stormflow and rainfall for the three upper basin sites. Distributed rainfall amounts for each subwatershed are shown for comparison. 159 1000 WY2002 NH4 VWM concentration (µM) NO3 100 DON PO4 10 1 0.1 1000 SM05 NH4 CP05 GB04 SM01 CP05 GB04 SM01 CP00 WY2003 VWM concentration (µM) NO3 100 DON PO4 10 1 0.1 SM05 CP00 Figure 3.23: VWM concentrations (µM) for the three upper sites (SM05, CP05, GB04) plus two associated outlet sites (SM01, CP00) during WY2002 and WY2003. 160 1000 WY2002 NH4 -1 Annual flux (mol ha ) NO3 100 DON PO4 10 1 0.1 Annual flux (mol ha -1) 1000 100 SM05 NH4 NO3 DON PO4 CP05 SM05 CP05 GB04 SM01 CP00 WY2003 10 1 0.1 GB04 SM01 CP00 Figure 3.24: Nutrient flux (mol ha-1) for the three upper sites plus two associated outlet sites during WY2002 and WY2003. 161 1000 Nutrient export (mol ha -1) NO3-Baseflow WY2003 NO3-Stormflow PO4-Baseflow 100 PO4-Stormflow 10 1 0.1 SM05 CP05 GB04 SM01 CP00 Figure 3.25: Baseflow and stormflow nitrate and phosphate export (mol ha-1) for the three upper basin and outlet sites in WY2003. 162 100 20 SM05 GB04 10 Rainfall 1 10 0.1 5 0.01 1 15 Rainfall (cm) -1 Nitrate export (mol ha ) CP05 0 11/7 12/14 12/16 12/19 12/28 2/11 2/12 2/24 3/15 4/13 5/2 20 CP05 -1 GB04 15 Rainfall 0.1 10 Rainfall (cm) Phosphate export (mol ha ) SM05 5 0.01 0 11/7 12/14 12/16 12/19 12/28 2/11 2/12 2/24 3/15 4/13 5/2 Figure 3.26: Storm-to-storm nitrate and phosphate export (mol ha-1) during WY2003. Rainfall amounts at the Carpinteria Fire Station are given for storm magnitude comparison. 163 300 NO3-CP05 NO3-GB04 Q-CP00 Nitrate concentration (µM) 200 3 2 150 100 1 Discharge (m 3s-1 ) (a) 250 50 0 0 11/5 11/6 11/7 11/8 11/9 11/10 11/11 11/12 11/13 11/14 11/15 300 NO3-CP05 NO3-GB04 Q-CP00 2 150 100 1 50 0 0 12/14 12/16 12/18 12/20 12/22 12/24 300 25 (c) NO3-SM05 NO3-CP05 NO3-GB04 Q-CP00 250 Nitrate concentration (µM) 12/26 200 20 Discharge (m 3s-1 ) Nitrate concentration (µM) 200 3 Discharge (m 3s-1 ) (b) 250 15 150 10 100 5 50 0 3/14 0 3/15 3/16 3/17 3/18 Figure 3.27: Nitrate concentrations (µM) from the (a) 11/6/02, (b) 12/26/02 and (c) 3/15/03 storms at the upper sites. SM05 was not shown in the first two graphs because of limited data across each hydrograph. The discharge (Q) curve in cubic meters per second is from CP00 at the basin outlet. 164 10 (a) PO4-CP05 PO4-GB04 Q-CP00 Phosphate conc (µM) 8 7 3.0 6 2.0 5 4 3 1.0 Discharge (m 3s-1 ) 9 2 1 0 0.0 11/5 11/6 11/7 11/8 11/9 11/10 11/11 11/12 11/13 11/14 11/15 10 Phosphate conc (µM) 8 PO4-CP05 PO4-GB04 Q-CP00 (b) 7 6 3.0 2.0 5 4 3 1.0 Discharge (m 3s-1 ) 9 2 1 0 0.0 12/14 12/16 12/18 12/20 12/22 12/24 6 25 PO4-SM05 (c) PO4-CP05 20 PO4-GB04 5 Q-CP00 15 4 10 3 5 2 1 3/14 Discharge (m 3s-1 ) Phosphate concentration (µM) 7 12/26 0 3/15 3/16 3/17 3/18 Figure 3.28: Phosphate concentrations (µM) from the (a) 11/6/02, (b) 12/26/02 and (c) 3/15/03 storms at the upper sites. SM05 was not shown in the first two graphs because of limited data across each hydrograph. The discharge (Q) curve in cubic meters per second is from CP00 at the basin outlet. 165 25 300 15 200 10 100 5 0 0 3/14 3/15 3/16 3/17 3/18 40 35 Phosphate conc (µM) 20 3/19 25 (b) PO4-GB04 PO4-CP00 Q-CP00 Q-GB04 30 25 20 15 20 10 15 Discharge (m 3s-1 ) Nitrate concentration (µM) (a) NO3-GB04 NO3-CP00 Q-CP00 Q-GB04 Discharge (m 3s -1) 400 10 5 5 0 3/14 3/15 3/16 3/17 3/18 0 3/19 Figure 3.29: Contrasts in the (a) nitrate and (b) phosphate chemographs for the 3/15/03 storm at an upper basin (GB04) and outlet (CP00) sites. Discharge (Q) is given for both sites in cubic meters per second. 166 160 NO3-CP05 (a) 140 NO3-GB04 Concentration (µM) 120 100 80 60 40 20 0 0 1 10 100 3 -1 Discharge (m s ) 90 (b) 80 DON-CP05 DON-GB04 70 Concentration(µM) 60 50 40 30 20 10 0 0 1 4.5 100 PO4-CP05 (c) 4.0 Concentration (µM) 10 3 -1 Discharge (ms ) PO4-GB04 3.5 3.0 2.5 2.0 1.5 1.0 0.5 0.0 0 1 10 100 3 -1 (d) 900 Conductivity (µS cm -1 ) Discharge (m s ) SC-CP05 SC-GB04 700 500 300 100 0 1 10 100 3 -1 Discharge (m s ) Figure 3.30: (a) Nitrate, (b) phosphate, (c) dissolved organic nitrogen, and (c) conductivity concentration-discharge curves at CP05 and GB04 during the 3/15/03 storm of WY2003. 167 350 (a) Concentration (µM) 300 NO3-CP00 NO3-GB04 250 200 150 100 50 0 0 5 10 15 20 25 3 -1 Discharge (m s ) 120 (b) 100 DON-CP00 DON-GB04 Concentration (µM) 80 60 40 20 0 0 5 10 15 25 PO4-CP00 (c) Concentration (µM) 20 3 -1 Discharge (ms ) 40 PO4-GB04 30 20 10 0 0 5 10 15 20 25 3 -1 Discharge (m s ) 900 Conductivity (µS cm -1 ) (d) SC-CP00 SC-GB04 700 500 300 100 0 5 10 15 20 25 3 -1 Discharge (m s ) Figure 3.31: Upper (GB04) verses outlet (CP00) (a) nitrate, (b) dissolved organic nitrogen, (c) phosphate, and (d) conductivity concentration-discharge curves on Carpinteria Creek during the 3/15/03 storm of WY2003. 168 10000 2002 Baseflow 2002 Stormflow 2003 Baseflow 2003 Stormflow -1 Nitrate flux (mol ha ) 1000 100 10 1 0.1 Greenhouse Nursery Commercial Residential Avocado Chaparral 1000 -1 Phosphate flux (mol ha ) 2002 Baseflow 2002 Stormflow 2003 Baseflow 2003 Stormflow 100 10 1 0.1 Greenhouse Nursery Commercial Residential Avocado Chaparral Figure 3.32: Annual nitrate and phosphate fluxes (mol ha-1) by baseflow and stormflow for each of the land use classes. Flows at the avocado site were estimated. 169 Nitrate VWM concentration (µM) 10000 2002 Baseflow 2002 Stormflow 2003 Baseflow 2003 Stormflow 1000 100 10 1 0.1 Greenhouse Nursery Commercial Residential Avocado Chaparral Phosphate VWM concentration (µM) 1000 2002 Baseflow 2002 Stormflow 2003 Baseflow 2003 Stormflow 100 10 1 0.1 Greenhouse Nursery Commercial Residential Avocado Chaparral Figure 3.33: Annual land use nitrate and phosphate volume weighted mean (VWM) concentrations by baseflow and averaged stormflow values. Flows at the avocado site were estimated. 170 10000 -1 6 5 100 4 10 3 1 2 0.1 1 0.01 0.001 0 10/30 11/11 11/24 11/29 12/2 12/14 12/20 12/29 1/27 2/17 3/6 3/17 3/23 10000 20 Greenhouse Commercial Avocado Rainfall -1 Nitrate flux (mol ha ) 1000 Nursery Residential Chaparral WY2003 18 16 100 14 12 10 10 1 8 6 0.1 4 0.01 2 0.001 0 11/7 12/14 12/16 12/19 12/28 2/11 2/12 2/24 3/15 4/13 5/2 Figure 3.34: Storm-to-storm nitrate fluxes (mol ha-1) for each land use type during the two years of the project. Rainfall for the Carpinteria Creek watershed was provided for comparison of storm magnitudes. 171 Rainfall (cm) Nitrate flux (mol ha ) 1000 WY2002 Nursery Residential Chaparral Rainfall (cm) Greenhouse Commercial Avocado Rainfall 6 Greenhouse Commercial Avocado Rainfall 1000 WY2002 Nursery Residential Chaparral 5 4 10 3 1 2 0.1 1 0.01 0.001 0 10/30 11/11 11/24 11/29 12/2 12/14 12/20 12/29 1/27 2/17 3/6 3/17 3/23 10000 -1 Phosphate flux (mol ha ) Rainfall (cm) 100 20 Greenhouse Commercial Avocado Rainfall 1000 WY2003 Nursery Residential Chaparral 18 16 100 14 12 10 10 1 8 6 0.1 4 0.01 2 0.001 0 11/7 12/14 12/16 12/19 12/28 2/11 2/12 2/24 3/15 4/13 5/2 Figure 3.35: Storm-to-storm phosphate flux (mol ha-1) for each land use type during the two years of the project. Rainfall for the Carpinteria Creek watershed was provided for comparison between storm magnitudes. 172 Rainfall (cm) -1 Phosphate flux (mol ha ) 10000 6 1000 Nursery Residential Chaparral WY2002 5 4 100 3 2 10 1 1 0 10/30 11/11 11/24 11/29 12/2 12/14 12/20 12/29 1/27 2/17 3/6 3/17 3/23 10000 Nitrate VWM concentration (µM) Rainfall (cm) Greenhouse Commercial Avocado Rainfall 20 Greenhouse Commercial Avocado Rainfall Nursery Residential Chaparral WY2003 18 16 1000 14 12 100 10 8 6 10 4 2 1 0 11/7 12/14 12/16 12/19 12/28 2/11 2/12 2/24 3/15 4/13 5/2 Figure 3.36: Storm-to-storm nitrate volume weighted mean (VWM) concentrations for each land use type during the two years of the project. Rainfall for the Carpinteria Creek watershed was provided for comparison between storm magnitudes. 173 Rainfall (cm) Nitrate VWM concentration (µM) 10000 6 Nursery Residential Chaparral WY2002 5 100 4 3 10 2 1 1 0 10/30 11/11 11/24 11/29 12/2 12/14 12/20 12/29 1/27 2/17 3/6 3/17 3/23 1000 Phosphate VWM concentration (µM) Rainfall (cm) Greenhouse Commercial Avocado Rainfall 20 Greenhouse Commercial Avocado Rainfall WY2003 Nursery Residential Chaparral 18 16 14 100 12 10 8 10 6 4 2 1 0 11/7 12/14 12/16 12/19 12/28 2/11 2/12 2/24 3/15 4/13 5/2 Figure 3.37: Storm-to-storm phosphate volume weighted mean (VWM) concentrations for each land use type during the two years of the project. Rainfall for the Carpinteria Creek watershed was provided for comparison between storm magnitudes. 174 Rainfall (cm) Phosphate VWM concentration (µM) 1000 Table 3.1: Physical and land use characteristics for Santa Monica, Franklin and Carpinteria creek watersheds for 2002. Percent agriculture includes greenhouses. Watersheds Santa Monica Franklin Carpinteria Area (km2) 9.8 11.1 40.0 Ave-Slope Max-Elev (%) (m) 45 20 38 1192 533 1424 Land Use: Chaparral Riparian Agriculture (%) (%) (%) 92 41 79 2 2 2 175 4 36 14 Greenhouse Urban (%) (%) 0.4 7 0.5 2 21 5 Impervious (%) 2 18 4 Table 3.2: Land use percentages for each sampling area. “Only” refers to the contributing area between the above (Figure 3.4) and below sampling points and “ws” indicates the entire watershed from the ocean or estuary upward. Missing percentages are concrete-lined channels, Highway 101 and water (reservoirs). SUB_WSS Area (ha) Chaparral (%) Riparian (%) Rangeland (%) Avocado (%) Nursery (%) Greenhouse (%) Other Agriculture (%) Commercial (%) Residential (%) SM-ws SM-ws-only SM01-only SM01 SM04-only SM04 SM05 981 7 38 973 34 935 902 92 0 3 93 46 96 98 2 0 0 2 22 2 1 0 0 0 0 12 0 0 2 0 29 2 16 1 0 0 0 9 0 0 0 0 0 0 10 0 0 0 0 1 0 13 1 2 0 0 0 19 2 0 0 0 0 2 64 25 1 2 0 0 FK-ws FK-ws-only FK00-only FK00 FK03-only FK03 FK04 FK06-only FK06 FK07 1112 39 214 1073 468 859 21 79 370 291 41 0 0 42 61 53 0 9 45 55 2 0 0 2 4 2 0 0 0 0 1 0 0 1 0 1 0 0 1 1 15 0 18 16 14 15 6 27 18 15 5 0 8 6 1 5 2 35 11 4 7 0 5 7 5 8 92 7 7 7 8 0 0 9 8 11 0 15 15 15 4 44 6 3 3 2 0 1 0 0 15 51 57 14 3 3 0 5 3 3 CP-ws CP-ws-only CP20 CP00-only CP00 CP30 CP02-only CP02 CP05 GB04 3998 22 40 101 3935 7 721 3827 1232 1874 79 0 0 0 80 0 15 82 97 98 2 15 0 9 2 0 4 2 2 2 1 0 0 0 1 0 6 1 1 0 9 0 0 17 9 0 49 9 0 0 0 0 0 10 0 0 0 0 0 0 0 0 0 7 1 0 2 0 0 0 2 5 0 8 2 1 12 2 0 0 2 28 73 11 1 0 2 0 0 0 3 52 27 31 3 99 9 2 0 0 176 Table 3.3: Historic land use percentages by broad categories with impervious surface extent for the three principal watersheds of the Carpinteria Valley from 1929, 1976, and 2002. Percent agriculture includes greenhouses. Watersheds Santa Monica Franklin Carpinteria Drainage Land Use: Area Chaparral (km2) Year (%) 1929 9.8 93 1976 92 2002 92 1929 11.1 48 1976 39 2002 41 1929 40.0 85 1976 81 2002 79 Riparian (%) 3 2 2 2 1 2 4 3 2 177 Agriculture (%) 4 5 4 48 42 36 10 14 14 Greenhouse Urban Impervious (%) (%) (%) 0.0 0.2 0.2 1 2 1 0.4 2 2 0.0 2 3 3 17 9 7 21 18 0.0 1 1 0.1 3 2 0.5 5 4 Table 3.4: Distributed precipitation totals in cm for each year and by storm according to the isohyetal method; storms were defined as having cumulative rainfall greater than 0.25 cm on the coastal plain. In 2001 and 2002 three gauging stations were used; five were used in 2003. Differences between annual totals and summation of storm precipitation were events with less than 0.25 cm of rainfall on the coastal plain. SITE TOTALS SM01 SM04 WY2001 Total (cm) 79.7 80.5 Storm totals (cm) 10/10/00 2.0 2.1 10/26/00 3.4 3.4 10/29/00 3.4 3.5 1/8/01 0.7 0.7 1/10/01 15.2 15.2 1/24/01 3.7 3.7 1/26/01 2.4 2.4 2/10/01 12.8 12.9 2/19/01 2.1 2.2 2/26/01 6.4 6.5 3/5/01 18.7 18.9 4/7/01 4.5 4.6 4/20/01 1.9 2.0 5/26/01 0.8 0.8 Storm sums: 78.0 78.8 WY2002 Total (cm) 28.0 28.3 Storm totals (cm) 10/30/01 1.4 1.4 11/11/01 5.4 5.4 11/24/01 3.8 3.8 11/29/01 1.6 1.6 12/2/01 1.4 1.4 12/14/01 0.4 0.4 12/20/01 2.0 2.0 12/29/01 2.9 2.9 1/27/02 2.2 2.2 2/17/02 1.3 1.4 3/6/02 2.1 2.2 3/17/02 1.1 1.1 3/23/02 1.2 1.2 Storm sums: 26.7 27.0 WY2003 Total (cm) 70.6 71.1 Storm totals (cm) 11/7/02 17.6 17.7 12/14/02 0.5 0.5 12/16/02 5.6 5.6 12/19/02 5.9 5.8 12/28/02 1.2 1.2 2/11/03 1.5 1.5 2/12/03 7.9 8.0 2/24/03 1.4 1.4 3/15/03 13.8 13.9 4/13/03 8.7 8.8 5/2/03 5.8 5.8 Storm sums: 69.9 70.4 SM05 FK00 FK03 FK04 FK06 FK07 CP00 CP20 CP30 CP02 CP05 GB04 81.1 61.1 61.6 59.2 59.9 60.0 79.2 56.8 55.7 80.2 80.0 87.6 2.2 3.4 3.5 0.7 15.3 3.8 2.4 13.1 2.2 6.5 19.0 4.6 2.0 0.9 79.5 0.1 3.8 2.0 0.7 13.2 2.4 1.8 9.1 1.7 4.8 15.7 3.6 1.1 0.4 60.3 0.2 3.8 2.0 0.7 13.3 2.5 1.8 9.2 1.7 4.8 15.8 3.6 1.1 0.4 60.8 0.1 3.7 1.9 0.7 12.8 2.3 1.7 8.8 1.6 4.6 15.3 3.5 1.0 0.3 58.4 0.1 3.7 1.9 0.7 13.0 2.4 1.7 8.9 1.6 4.7 15.5 3.5 1.0 0.3 59.1 0.1 3.8 1.9 0.7 13.0 2.4 1.7 8.9 1.6 4.7 15.5 3.5 1.0 0.3 59.2 1.8 3.6 3.3 0.8 15.3 3.6 2.3 12.6 2.1 6.4 18.9 4.5 1.8 0.8 77.7 0.1 3.5 1.8 0.7 12.3 2.3 1.6 8.4 1.6 4.5 14.7 3.3 1.0 0.3 56.0 0.1 3.5 1.8 0.7 12.1 2.2 1.6 8.3 1.5 4.4 14.4 3.3 1.0 0.3 54.9 1.8 3.6 3.3 0.8 15.5 3.7 2.4 12.7 2.2 6.4 19.1 4.6 1.9 0.8 78.7 2.1 3.4 3.4 0.7 15.2 3.7 2.4 12.8 2.1 6.4 18.8 4.5 1.9 0.8 78.4 2.3 3.6 3.8 0.8 16.5 4.1 2.6 14.1 2.3 7.1 20.5 5.0 2.1 0.9 85.8 28.6 21.3 21.5 20.6 20.9 20.9 27.8 19.8 19.4 28.2 28.2 30.8 1.4 5.4 3.8 1.6 1.4 0.4 2.1 2.9 2.2 1.4 2.3 1.2 1.2 27.2 1.3 4.9 4.3 1.1 1.0 0.4 1.3 2.3 1.5 0.9 0.7 0.3 0.2 20.1 1.4 4.9 4.3 1.1 1.0 0.4 1.3 2.3 1.5 0.9 0.7 0.3 0.2 20.3 1.3 4.7 4.3 1.1 0.9 0.4 1.3 2.2 1.4 0.8 0.6 0.3 0.1 19.4 1.3 4.8 4.3 1.1 1.0 0.4 1.3 2.2 1.4 0.8 0.6 0.3 0.1 19.7 1.3 4.8 4.3 1.1 1.0 0.4 1.3 2.2 1.4 0.8 0.6 0.3 0.1 19.7 1.4 5.5 4.0 1.5 1.4 0.4 2.0 2.9 2.1 1.3 2.0 1.0 1.0 26.5 1.3 4.6 4.1 1.0 0.9 0.4 1.2 2.1 1.3 0.8 0.6 0.3 0.1 18.7 1.2 4.5 4.0 1.0 0.9 0.4 1.2 2.1 1.3 0.8 0.6 0.3 0.1 18.3 1.4 5.5 4.0 1.6 1.4 0.5 2.0 2.9 2.1 1.3 2.0 1.0 1.1 26.8 1.4 5.4 3.8 1.6 1.4 0.4 2.0 2.9 2.2 1.4 2.2 1.1 1.2 26.8 1.5 5.8 4.1 1.7 1.5 0.5 2.2 3.2 2.4 1.5 2.4 1.3 1.3 29.4 71.5 59.7 60.0 58.5 58.9 59.0 70.1 56.1 55.0 70.9 70.8 74.9 17.7 0.5 5.6 5.8 1.3 1.5 8.1 1.4 14.0 9.0 5.8 70.8 16.0 0.2 5.2 6.1 0.9 1.3 5.6 1.2 12.0 5.0 4.8 58.3 16.1 0.2 5.2 6.0 0.9 1.3 5.8 1.2 12.1 5.0 4.9 58.7 15.8 0.2 4.9 6.3 0.8 1.2 5.1 1.1 11.8 4.9 4.6 56.8 15.9 0.2 5.0 6.3 0.8 1.2 5.3 1.1 11.9 5.0 4.7 57.4 15.9 0.2 5.1 6.2 0.8 1.2 5.3 1.1 11.9 5.0 4.7 57.5 17.7 0.5 5.6 6.1 1.2 1.5 7.6 1.4 13.7 8.4 5.7 69.2 15.2 0.2 4.7 6.1 0.8 1.2 4.9 1.1 11.3 4.7 4.4 54.6 14.9 0.2 4.6 6.0 0.8 1.1 4.8 1.0 11.1 4.6 4.3 53.5 17.8 0.5 5.6 6.1 1.2 1.5 7.7 1.4 13.9 8.5 5.7 70.0 17.6 0.5 5.6 5.8 1.2 1.5 8.0 1.4 13.9 8.7 5.8 70.1 18.5 0.6 5.8 6.2 1.4 1.6 8.4 1.4 14.5 9.7 6.0 74.2 178 Table 3.5: Stream discharge, basin rainfall, and runoff/rainfall ratios for Santa Monica (SM), Franklin (FK), and Carpinteria (CP) creek watersheds during the three years of the study. The number of storms and number of stream samples taken each year are also included. Annual Rainfall3 Number of 2 Samples (cm) SM FK CP SM FK CP 14 70 71 71 80 61 79 13 105 397 287 28 21 28 11 291 738 859 71 60 70 11 157 208 185 36 26 36 1. Storm was defined as > 0.25 cm of rainfall. 2. Total number of samples: 3439. 3. Distributed rainfall. Number of Storms1 WY2001 WY2002 WY2003 WY2004 179 Annual Rainfall (cm) SM FK CP 18 16 19 2 7 1 7 14 4 2 6 1 Runoff/Rainfall (%) SM FK CP 0.2 0.3 0.2 0.1 0.3 0.04 0.1 0.2 0.1 0.05 0.2 0.04 Table 3.6: Percentages of dominant land use classes with impervious surface extent and distance down stream to the basin outlet (DTO) for the inline subwatershed sampling sites (SUB-WSs) on Santa Monica, Franklin, and Carpinteria creeks. SUB_WSs SM01 SM04 SM05 Area DTO (ha) (km) 973 0.4 935 2.0 902 2.6 Chaparral (%) 92.5 96.1 98.0 Riparian (%) 2.1 2.2 1.4 Avocado (%) 2.0 0.9 0.4 Nursery (%) 0.3 0.0 0.0 FK00 FK03 FK06 FK07 1073 859 370 291 0.5 1.2 1.9 2.3 42.1 52.7 45.0 54.7 1.7 2.2 0.0 0.0 15.6 15.2 17.8 15.2 5.6 5.1 10.5 4.0 7.2 7.9 6.6 6.5 2.8 1.9 0.1 0.0 13.8 3.1 3.3 2.7 16.9 12.4 11.3 9.7 CP00 CP02 CP05 GB04 3935 3827 1232 1874 0.5 2.0 5.5 6.0 80.0 82.2 97.0 98.3 2.4 2.2 2.1 1.5 9.5 9.3 0.4 0.0 0.3 0.0 0.0 0.0 0.5 0.3 0.0 0.0 0.7 0.4 0.0 0.0 2.6 1.7 0.0 0.0 2.9 2.0 0.0 0.0 180 Greenhouse Commercial (%) (%) 0.4 0.1 0.0 0.0 0.0 0.0 Residential (%) 1.2 0.2 0.2 Impervious (%) 1.3 0.2 0.1 Table 3.7: Stream nutrient characteristics for the Carpinteria Creek catchment as mass loading (kmol), volume weighted mean concentration (µM), and flux (mol ha-1). Carpinteria Creek: Year 2002 " " " 2003 " " " Site CP00 CP02 CP05 GB04 CP00 CP02 CP05 GB04 Year 2002 " " " 2003 " " " CP00 CP02 CP05 GB04 CP00 CP02 CP05 GB04 Year 2002 " " " 2003 " " " CP00 CP02 CP05 GB04 CP00 CP02 CP05 GB04 NH4 NO3 DON PO4 Loading (kmol) (kmol) (kmol) (kmol) 5.5 185.9 25.6 3.1 0.1 2.6 1.1 0.4 0.3 3.5 2.2 0.8 0.2 0.9 3.3 0.9 6.2 350.4 132.3 13.6 0.3 96.6 58.1 6.2 0.3 26.3 20.0 1.3 0.6 38.9 32.5 2.5 Volume weighted mean (µM) (µM) (µM) (µM) 13.6 455.2 62.6 7.7 4.0 98.2 41.5 15.1 1.2 15.9 9.8 3.4 0.4 1.8 6.6 1.7 3.9 220.9 83.4 8.6 0.4 110.4 66.4 7.1 0.7 50.7 38.5 2.4 0.4 29.4 24.6 1.9 Flux (mol ha-1) (mol ha-1) (mol ha-1) (mol ha-1) 1.4 47.2 6.5 0.8 0.0 0.7 0.3 0.1 0.2 2.9 1.8 0.6 0.1 0.5 1.7 0.5 1.6 89.0 33.6 3.4 0.1 25.2 15.2 1.6 0.3 21.4 16.2 1.0 0.3 20.8 17.4 1.3 181 Table 3.8: Nutrient stream characteristics for the Franklin Creek catchment as mass loading (kmol), volume weighted mean (µM), and flux (mol ha-1). Franklin Creek: Year 2002 " " " 2003 " " " Site FK00 FK03 FK06 FK07 FK00 FK03 FK06 FK07 Year 2002 " " " 2003 " " " FK00 FK03 FK06 FK07 FK00 FK03 FK06 FK07 Year 2002 " " " 2003 " " " FK00 FK03 FK06 FK07 FK00 FK03 FK06 FK07 NH4 NO3 DON PO4 Loading (kmol) (kmol) (kmol) (kmol) 5.5 1257.8 118.9 10.8 6.6 689.0 49.6 13.3 1.6 319.9 28.3 2.0 1.0 16.2 5.2 0.8 7.8 1436.3 240.0 22.5 8.6 903.3 172.6 17.2 6.1 501.8 200.1 8.8 6.5 51.9 25.2 3.2 Volume weighted mean (µM) (µM) (µM) (µM) 7.3 1678.0 158.6 14.4 16.5 1723.0 124.0 33.4 9.4 1926.9 170.3 11.8 22.8 367.3 117.2 18.2 5.2 971.6 162.4 15.2 9.2 963.5 184.1 18.3 13.2 1081.5 431.2 18.9 59.0 471.3 228.9 29.0 Flux (mol ha-1) (mol ha-1) (mol ha-1) (mol ha-1) 5.1 1171.9 110.8 10.1 7.7 802.3 57.7 15.5 4.2 865.1 76.5 5.3 3.5 55.6 17.7 2.7 7.2 1338.3 223.7 21.0 10.0 1051.9 201.0 20.0 16.5 1357.0 541.0 23.7 22.3 178.2 86.5 11.0 182 Table 3.9: Influence of debris basins on nutrient concentrations on upper Santa Monica and Gobernador creeks. Above Below Above Below SM05 (µM) SM04 (µM) GB05 (µM) GB04 (µM) Min: 0* 0* 0* 0* Max: 0.6 1.3 1.1 1.5 Mean: 0.2 0.4 0.4 0.3 Median: 0.1 0.1 0.2 0.1 Min: 0* 0* 0* 0* Max: 2.0 14.9 26.9 28.3 Mean: 0.5 2.7 4.5 3.1 Median: 0.1 0.2 1.3 0.8 Min: 0* 6.9 1.0 0.8 NH4 NO3 DON Max: 13.9 24.3 27.5 27.1 Mean: 7.7 11.2 12.8 11.1 Median: 8.4 7.0 13.6 9.2 Min: 0.6 0.8 0.3 0.3 Max: 8.6 8.6 7.4 7.2 Mean: 3.8 4.2 4.0 3.0 Median: 3.5 3.6 4.4 1.4 PO4 * At or below the detection limit. 183 Table 3.10: Annual loading (kmol), volume weighted mean concentrations (µM), and fluxes (mol ha-1) for the three upper basin sites (SM05, CP05 and GB04) and associated outlet sites (SM01 and CP00) during WY2002 and WY2003. The annual mean and standard deviation nutrient values are given for VWM concentrations and fluxes only; loading is biased by contributing area and is only included for reference. WY Site Area 2002 " " " " 2003 " " " " SM05 CP05 GB04 SM01 CP00 SM05 CP05 GB04 SM01 CP00 (ha) 902 1232 1874 973 3935 902 1232 1874 973 3935 2002 " " " " " " 2003 " " " " " " SM05 CP05 GB04 (ha) 902 1232 1874 Mean upper Std-Dev upper - 1.3 0.9 SM01 CP00 SM05 CP05 GB04 973 3935 902 1232 1874 2002 " " " " " " 2003 " " " " " " NH4 NO3 Loading (kmol) (kmol) 0.3 1.3 0.3 3.5 0.2 0.9 0.9 59.5 5.5 185.9 0.7 33.0 0.3 26.3 0.6 38.9 0.5 102.6 6.2 350.4 Volume weighted mean (µM) (µM) 2.2 8.8 1.2 15.9 0.4 1.8 DON PO4 (kmol) 1.9 2.2 3.3 11.7 25.6 22.3 20.0 32.5 55.1 132.3 (kmol) 0.5 0.8 0.9 3.7 3.1 1.8 1.3 2.5 4.7 13.6 (µM) 13.3 9.8 6.6 (µM) 3.6 3.4 1.7 8.9 7.0 9.9 3.3 2.9 1.0 5.6 13.6 1.0 0.7 0.4 365.2 455.2 51.7 50.7 29.4 71.8 62.6 34.9 38.5 24.6 22.8 7.7 2.9 2.4 1.9 Mean upper - 0.7 43.9 32.7 2.4 Std-Dev upper - 0.3 12.6 7.2 0.5 SM01 CP00 973 3935 0.7 3.9 155.9 220.9 83.7 83.4 7.1 8.6 SM05 CP05 GB04 (ha) 902 1232 1874 (mol ha-1) 1.4 2.9 0.5 (mol ha-1) 2.1 1.8 1.7 (mol ha-1) 0.6 0.6 0.5 Mean upper Std-Dev upper - 0.2 0.1 1.6 1.2 1.9 0.2 0.5 0.1 SM01 CP00 SM05 CP05 GB04 973 3935 902 1232 1874 0.9 1.4 0.7 0.3 0.3 61.1 47.2 36.6 21.4 20.8 12.0 6.5 24.7 16.2 17.4 3.8 0.8 2.0 1.0 1.3 Mean upper Std-Dev upper - 0.4 0.3 26.3 9.0 19.4 4.6 1.5 0.5 SM01 CP00 973 3935 0.5 1.6 105.4 89.0 56.6 33.6 4.8 3.4 Flux (mol ha-1) 0.3 0.2 0.1 184 Table 3.11: Land use distribution by percentage for each sampled subcatchment. Secondary and tertiary land uses were shown for reference. There were three upper basin (chaparral) sites, one on Santa Monica Creek (SM) and two on Carpinteria Creek (CP1 and CP2). Land Use Chaparral-SM Chaparral-CP1 Chaparral-CP2 Avocado Greenhouse Nursery Residential Commercial Area (ha) 902 1232 1874 721 21 79 7 40 Target land use (%) 98 97 98 49 92 35 99 73 Secondary land use (%) 1 (riparian) 2 (riparian) 2 (riparian) 12 (other agriculture) 6 (avocado) 27 (avocado) 1 (other agriculture) 27 (residential) 185 Tertiary land use (%) Impervious (%) 0 0 0 0 0 0 9 (residential) 11 2 (nursery) 79 15 (other agriculture) 17 0 30 0 70 Table 3.12: Annual land use nutrient fluxes (mol ha-1) and volume weighted mean concentrations (µM). Year Land use 2002 " " " " " 2003 " " " " " Greenhouse Nursery Commercial Residential Avocado Chaparral Greenhouse Nursery Commercial Residential Avocado Chaparral 2002 " " " " " 2003 " " " " " Greenhouse Nursery Commercial Residential Avocado Chaparral Greenhouse Nursery Commercial Residential Avocado Chaparral NH4 NO3 Flux (mol ha-1) 292 3404 7 3869 28 238 29 54 1 21 <1 1 708 5684 <1 5731 6 179 44 49 1 146 <1 21 Volume weighted mean (µM) (µM) 132 1542 5 2490 21 181 22 41 9 233 1 6 130 1045 <1 1271 4 108 18 21 <1 139 <1 35 186 DON PO4 239 294 78 172 10 2 963 2235 78 206 82 17 298 15 14 42 3 1 511 71 9 68 11 1 (µM) 108 189 59 130 91 8 177 494 47 86 81 29 (µM) 135 10 10 32 34 2 94 16 5 28 9 2 Table 3.13: Annual nitrate and phosphate fluxes and VWM concentrations by land use class for a dry year (WY2002) and a wet year (WY2003). Ammonium and dissolve organic nitrogen were not included given their relatively small contribution. Land use Nutrient Greenhouse Nursery Commercial Residential Avocado Chaparral Nitrate Nitrate Nitrate Nitrate Nitrate Nitrate Greenhouse Nursery Commercial Residential Avocado Chaparral Phosphate Phosphate Phosphate Phosphate Phosphate Phosphate Greenhouse Nursery Commercial Residential Avocado Chaparral Nitrate Nitrate Nitrate Nitrate Nitrate Nitrate Greenhouse Nursery Commercial Residential Avocado Chaparral Phosphate Phosphate Phosphate Phosphate Phosphate Phosphate Flux (mol ha-1) Dry year (WY2002) Wet year (WY2003) Baseflow Stormflow Annual Baseflow Stormflow Annual 2563 841 3404 3930 1755 5684 3325 544 3869 3802 1929 5731 97 140 238 85 94 179 22 32 54 23 27 49 0 21 21 0 146 146 1 1 1 1 20 21 167 2 2 19 0 0 131 13 12 23 3 0 298 15 14 42 3 1 322 0 2 41 0 0 189 71 7 26 11 1 511 71 9 68 11 1 VWM concentration (µM) Dry year (WY2002) Wet year (WY2003) Baseflow Stormflow Annual Baseflow Stormflow Annual 1839 841 1542 1931 1755 1045 3305 994 2490 2242 686 1271 285 140 181 299 94 108 35 32 41 28 27 21 0 272 233 0 401 139 5 8 6 3 56 35 120 2 5 31 0 2 131 23 12 23 37 3 187 135 10 10 32 34 2 158 0 5 50 0 2 189 25 7 26 31 2 94 16 5 28 9 2