Large Seafloor Volcanic-hosted Massive Sulfide Deposits: Discovered and Undiscovered Peter A. Rona, Institute of Marine and Coastal Sciences and Department of Geological Sciences, Rutgers University, 71 Dudley Road, New Brunswick, NJ 08901-8521 (rona@marine.rutgers.edu) Some hundreds of sites of massive sulfides have been found hosted in volcanic rocks at global spreading axes and submarine volcanoes on ocean ridges and in volcanic island arcs (fore- and back-arc settings; Rona and Scott, 1993; Hannington et al., 2004). However, relatively few of these deposits are in the 5 million tonne class, the size that a leading marine mining company identifies as prospective. A large gap exists between these seafloor massive sulfides and the largest volcanic-hosted massive sulfide deposits on land in the 100 million tonne range like the Kidd Creek deposit of eastern Canada, interpreted as an analog of modern seafloor volcanic-hosted massive sulfide deposits (Hannington et al., 1999). This size gap is largely an artifact of the present early stage of ocean exploration. If such giant massive deposits exist on the seafloor, where are they likely to be found? Spreading axes and submarine fore-arc volcanoes remain prospective for discovery of giant massive sulfide deposits. However, even more likely are relict deposits at sites in oceanic and transitional lithosphere generated in these tectonic settings and now underlying ocean and back-arc basins (Rona, 2008). Challenges are to advance understanding of how massive sulfide deposits evolve as they move away from active sites of formation with the aging lithosphere by drilling (e.g., the assemblage of large massive sulfide mounds spanning over 100,000 years at the TAG hydrothermal field on the Mid-Atlantic Ridge) and to develop appropriate exploration methods to detect properties that reside with the deposits as they age, such as a magnetic signature of crustal alteration by hydrothermal processes (Rona, 1978; Tivey et al., 1996). Hannington, M.D., Barrie, C.T., Bleeker, W., 1999. The giant Kidd Creek volcanogenic massive sulfide deposit, Western Abitibi subprovince, Canada, In Hannington, and M.D., Barrie, C.T., eds., The Giant Kidd Creek Volcanogenic Massive Sulfide Deposit, Western Abitibi Subprovince, Canada:, Economic Geology, Monograph 10, Preface and introduction, 1-28. Hannington, M.D., Petersen, S., Herzig, P.M.,Jonasson, I.R., 2004. A Global Data Base of Seafloor Hydrothermal Systems Includinga Digital Data Base of Geochemical Anlayses of Sefloor Polymetallic Sulfides, Gelogical Survey ofCanada, Open File 4598, CD-ROM. Rona, P.A., 1978. Magnetic signature of hydrothermal alteration and volcanogenic mineral deposits in oceanic crust, Journal of Volcanological and Geothermal Research 3, 219-225. Rona, P.A., 2008. The changing vision of marine minerals, Ore Geology Reviews 33, 618-666, doi:10.1016/j.oregeorev.2007.03.006 Rona, P.A. and Scott, S.D. (Eds.), 1993. A Special Issue on Sea-floor Hydrothermal Mineralization: New Perspectives, Economic Geology 88, 1935-1975. Tivey, M.A., Rona, P.A., Kleinrock, M.C., 1996. Reduced crustal magnetization beneath relict hydrothermal mounds, TAG hydrothermal field, Mid-Atlantic Ridge, 26oN, Geophysical Research Letters 23, 3511-3514.