Acids, Bases, and Salts: Unit 6 Outline Characteristics of Acids • Molecular substances that ______________ in water. a. ___________ difference is less that 1.8 b. It’s a non-polar covalent molecule c. Creates ___________ in solution • Acids react with ___________ metals to create hydrogen gas. a. Active metals include, ______________________. b. Cu, Ag, Au, Pt. DO NOT react with acids c. Metal + Acid ___________+ H2 (g) • Affect the color of ___________. • React with bases more neutral solution of H2O + ___________ • Edible acids have a ___________ taste<don’t try this!> Arrhenuis Acids • A solution that yields an ___________ (a ____________) as one of its components in solutions. • H + Ions are always ___________. • Strong acids have: a. 1 H+ proton = 1 ______________________ • Weak acids have more ___________ molecules for every H+ Ionization of Acids • The higher the rate of ionization, the more ___________ the acid. • Strong: HCl: nearly ___________ ionized. • sulfuric acid(H2SO4) ___________ ionized. • Weak: Hydrofluoric acid (HF): ___________ions • Hydrosulfuric acid: ___________ions. Properties of Bases • ___________ • Cause ___________ to turn colors • Neutralize acids and produce a ___________+ H2O • ___________ taste, ___________ feel • Soap in the mouth? Arrhenuis Bases • Contribute a OH- (___________) in solution. • OH-, unlike H+, does not attach to other molecules UNLESS it has a ___________ charge Ionization of Bases • Ionize similar to acids, except that Bases tend to be ___________ compounds. • The OH- ion is ___________, while the metal attached is bonded ___________ • Strong Bases: ___________ (almost 100%) a. Weak Bases: Ammonia compounds: ___________ Salts • • • • Ionic compounds that have Ions other than ___________ and ___________. SOLID=___________ Conduct ___________ when molten OR in solution Tend to have ___________ melting points The Ionization of Water • Water ionizes itself • For any sample of water: • H2O H3O+ + OH• H2O = 1 mole; H3O+ = ___________mole and OH- = ___________mole • In 10,000 L of H2O, there would be ___________of H2O- one drop from a dropper! Ionization of Water… continued • There are ___________amount of H3O+ and OH- ions. • This allows water to: a. Be perfectly neutral b. Neutralize other substances through self ionization. • - If an ___________ion pops in, the OH- can ___________ it to a certain extent. • - Most solutes are combinations of ___________and ___________, so, water dissolves and separates them. Ionization of Water… continued • Kw= OH- x H3O+ • In any sample: ___________ = 1.0x10-7 • ___________ = 1.0x10-7 • Then Multiply: ___________ = 1.0x10-14 • Soooooooooooooooooooo… for a solution to be perfectly ___________, it must have ___________ ___________ of OH- and H3O+ions. The pH Scale • A measure of the ___________ or ___________ of a solution, based on the concentration of the ___________in solution. • pH= “pouvoir Hydrogen” = Power of Hydrogen • The pH of a given solution is: equal to the ___________of the Hydrogen Ion ___________ in a given solution. a. ___________scale b. Small # = ___________ c. Large # = ___________ • The p OH scale: OPPOSITE of the pH scale. a. pH + p OH = 14; Why? • Because we want to compare pH to ___________—which always has ___________ So—[H+] [OH-] = Kw and Kw= 1.0x 0^-14 Another View of Acids and Bases • Bronsted- Lowry a. Acids: ___________ b. Bases: ___________ • NH3 + H2O NH4+ + OHa. Draw Lewis dot structures b. ___________ Acids and Bases c. Strengths of acids chart: P.565 More Acids and Bases • ___________= Ionization Constant for an acid. • Strong Acids (HCl, H2SO4, HNO3, etc.) -all of the compound will ___________. a. Weak Acids all ___________at various rates: HC2H3O2 will ionize at lower rate than the strong acids. This affects acid strength. • ___________= same thing, except for bases instead of acids. • The ionization constants tell you the number of moles of the acid (Ka, H+) or base (Kb, OH-) in ___________of a ___________ solution. • More simply, it’s the ___________of a particular ion in solution. Key Terms • ___________, ___________ (and complete…) • ALL refer to a compound breaking apart into the ions that make the compound up. • Simple Reactions: a. Adding an acid to a metal will produce? b. Adding a base to an acid will produce? • Any reaction that makes an acid or base from its constituent parts is called Acid (or base) Formation. a. H + Cl = HCl. • Neutralization- An acid + base reacts to produce a salt plus water. Net Ionic Equations • Net Ionic Equations*- In some instances, only a few certain elements are involved in a reaction. To ‘simplify’ the equation, all the inactive parts are removed from the equation. • HCl (aq) + Zn (s) H2 (g) + ZnCl (aq) • H changes from a ___________ to a ______________________. • Zinc does the opposite • But what does the chlorine do? • We write: • H+ + Zn0 H20 + Zn + • Since the Cl stays a ___________ ___________, we can leave it off for this type of equation. • Net Ionic Equations only occur in a special type of reaction, called ___________ Redox • Redox is short for ______________________reaction. • Redox Reactions are an important part of chemistry. • Redox Reactions are a result of ______________________. • In our example above, electrons are taken from the Zinc, and given to Hydrogen. This makes Zinc an ion, and Hydrogen a free element—the opposite of what they were before the reaction. • Reduction is the ___________of electrons. Why do we call it reduction? • Oxidation is the ___________of electrons. To remember this: “LEO says GER” ______________________= Oxidation; ______________________= Reduction