YOUNGSTOWN CITY SCHOOLS SCIENCE: CHEMISTRY UNIT #8: “ACIDS AND BASES” (4 WEEKS) 2013-2014 SYNOPSIS: Students will investigate the importance of acids and bases in their everyday lives. Through extensive lab work, they will learn the processes of titration, pH calculation, and neutralization. At the end of the unit students will be given a solution to calculate its concentration. ENABLERS: acids, bases, dissociation, electronegative, hydronium ion, aqueous, hydroxide ion, titration, equilibrium, Bronsted-Lowrey and Lewis STANDARDS VIII. ACIDS AND BASES A. Structural features of molecules are explored to further understand acids and bases B. Acids often result when hydrogen is covalently bonded to an electronegative element and is easily dissociated from the rest of the molecule to bind with water to form a hydronium ion (H3O+) C. The acidity of an aqueous solution can be expressed as pH, where pH can be calculated from the concentration of the hydronium ion D. Bases are likely to dissociate in water to form a hydroxide ion E. Acids can react with bases to form a salt and water F. Neutralization reactions can be studied quantitatively by performing titration experiments 1. Experimentally determine the concentration of an acid or base through titration 2. Use indicators to determine the identity of an unknown substance G. Equilibrium of acids and bases and the concept of Brønsted-Lowry and Lewis acids and bases are studied LITERACY STANDARDS RST.1 Cite specific textual evidence to support analysis of science and technical texts, attending to important distinctions the author makes and to any gaps or inconsistencies in the account WHST.9 Draw evidence from informational texts to support analysis, reflection, and research TEACHER NOTES MOTIVATION 1. Draw on past experiences with acids and bases in other units, writing compounds, etc. to see what students know. 2. Teacher demo on production of hydrogen gas / film canister to show reaction. Students observe how hydrochloric acid reacts with magnesium to produce hydrogen gas. Teacher ignites gas to create a “rocket” 3. Video of the Hindenburg Disaster; students view and then discuss what happened. 4. YouTube Video with wands filled with hydrogen gas and then ignited - - students describe reaction of acid (metals) and hydrogen; review balancing equations with students. 5. Students set personal and academic goals 6. Preview the Authentic Assessment so students know what is expected by the end of the Unit pH and pOH concentration H3O+ Kw, Ka, Kb (constants) [OH-] [H+] = [H3O+] amphoteric indicator neutral neutralization pH scale litmus buffer salts hydride VOCABULARY anhydride titration end point equivalence point buret pKa pKb Monoprotic Diprotic Polyprotic Conjugate Acids Antacids Conjugate Bases Organic Acid Magnificent Seven Inorganic Acid Swamped-out Weak Acids Buffer Capacity Weak Bases Henderson-Hasselbalch Equation 1 0712/2013 YCS Science Chemistry Unit 8: Acids and Bases 2013-2014 TEACHER NOTES TEACHING-LEARNING 1. Teacher presents definition and properties of Acids and Bases; students take notes. As part of this, the teacher presents three theories: (VIIIA; VIIIB) Arrhenius (acids produce hydrogen ions and bases produce hydroxide). Bronsted-Lowry (proton part of compounds). Lewis (electron or negative part of compound). Students compare and contrast theories and read research articles about each (RST.1) 2. Characteristics of Acids and Bases: Teacher puts a T-chart on the board and students give characteristics of Acid or Base; one student records answers for class, and students keep giving answers until they run out of descriptors. (VIIIA) T-Chart attached on page 4. After students have done descriptor list, discuss how people in ancient time classified something as an Acid or Base. Have students explore at home and make of list of acids and bases found in common substances. Students must identify at least 8-10 items from kitchen, cleaning supplies, cosmetics, car care, bathroom, etc. Students bring in lists and identify products as acid or base on the board. They explain why they classified something as an acid or base; class discusses items and if there is disagreement, they test the substance in class. 3. pH Scale: acids, neutral, and bases. Teacher discusses pH and pOH, using a number line 0-14 (pH scale) and a number line 14-0 (pOH scale). Teacher gives examples such as salt water, Coke, milk, and other common substances to see where they fit. Also, use the household item list students brought in. Include pH of blood as 7.0 – 7.8 as the ideal; if higher or lower serious things happen to the person. (VIIIB, VIIIC) Students can also do testing with various types of bottled water. 4. Teacher moves from pH to Concentrations (what to touch or not to touch!). Teacher shows students how to do the calculations with logs (try to coordinate with Math) to show how strong the acids and bases are. Make connections to real life for students by looking at things such as: if you had a salad, would you use vinegar or hydrochloric acid? If you wash your hands, do you use acid or soap? Car battery and sulfuric acid. Looking at erosion of a battery - - electrolyte and non-electrolyte. Acid in the human stomach is hydrochloric acid. If you swallowed Liquid Plumber, how do you get it out of the system? (VIIIB, VIIIC) 5. Kw = 1.0 x 10-14 = [H+] [OH-] - - Kw = hydronium concentration x hydroxide concentration; introduce and work problems with students. Students will be able to translate the concentrations back to pH and pOH scales. (VIIIB, VIIIC, VIIIG) #6 Labs are PDF Files 6. Teacher then has students do several LABS: (VIIIC, VIIID, VIIIE) a. Acid-base-neutral lab (household products) b. Properties of Strong and Weak Acids and Bases c. Comparing Acid Strengths d. Students will do a lab with an unknown substance for their Authentic Assessment 7. Acid-Base Equations - - Teacher give reactants which includes acids and bases; students predict what the products are. Review balancing equations. The teacher should then address conjugate acids and bases (the acid or base produced after reaction). Theory of Lewis introduced this. Once they know the conjugate bases, students then describe - - e.g., how to neutralize sulfuric acid; they will know how much buffer to add to get to the pH needed (HCL + NaOH →NaCl + H2O). (VIIIE) #8 Labs are PDF Files 8. Titrations: Teacher introduces Titrations and refers to definition and purpose (e.g., test 2 0712/2013 YCS Science Chemistry Unit 8: Acids and Bases 2013-2014 TEACHER NOTES TEACHING-LEARNING concentration vitamin C in juice, Salicylic acid in aspirin, water analysis). Students perform labs: a. Acid-base titration lab b. Titration of fruit juice lab c. Standard solution titration d. Determination of acetic acid in vinegar (if time) During labs, students graph the volume of titrant to pH. When finished, students know how to find concentration of any solution. Students can tell end point when given any graph; they know which indicator to use (phenolphthalein is most used indicator. (VIIIC, VIIIF, VIIIG) TEACHER NOTES TRADITIONAL ASSESSMENT 1. Unit Test: Multiple-Choice TEACHER NOTES TEACHER ASSESSMENT 1. Lab reports or practical reports, using rubrics for quality points. 2. Assignments/worksheets 3. 2- 4-point questions TEACHER NOTES AUTHENTIC ASSESSMENT 1. Students evaluate their goals for the Unit. 2. Titration: find concentration of unknown substance. Given 3 solutions, they choose solution, run titration and tell concentration of acid. Compare to another acid on the board. (IIIA2) 3 0712/2013 YCS Science Chemistry Unit 8: Acids and Bases 2013-2014 T-L #2 CHARACTERISTICS OF ACIDS AND BASES ACIDS BASES 4 0712/2013 YCS Science Chemistry Unit 8: Acids and Bases 2013-2014