MATERIAL SAFETY DATA SHEET 1. Product and Company Identification Product Name: Manufacturing Number: Producer: Telephone No: Fax No: Email: Supplier: Rizowet Not Available Natrol cc P.O. Box 1137 Delmas 2210 South Africa +27 (0)82 921 8428 +27 (0) 865 476 711 jonathan@mbfi.co.za See Producer 2. Composition/Information on Ingredients Product description: Dangerous ingredients: A dispersible concentrated adjuvant wetter-spreader for use with agricultural chemicals targeted for foliar applications. None 3. Hazards Identification Important hazards: None 4. First Aid Measures Inhalation: Skin Contact: Eye Contact: Harmful if inhaled. No adverse effects expected to static vapor at room temperature. Inhalation of an aerosol of pure material in a confined space could cause breathing problems and eye damage. The spray can cause: damage to the respiratory tract, eye injury, injury to the nasal cavity, injury to blood forming system. Prolonged exposure and / or repeated exposure may cause the following effects: damage to the respiratory tract, eye injury, injury to the nasal cavity, injury to the blood system. Remove patient to fresh air. Respiration and / or artificial oxygen may be necessary. Get medical help immediately. Can cause skin irritation. Wash with soap and water. Remove contaminated clothing and shoes. See a doctor if an allergic reaction noticed. Causes eye irritation. Can have the following effects: pain, excessive blinking, tear production, excessive redness of the conjunctiva, inflammation of the conjunctiva, inflammation of the iris. These effects should be resolved in two weeks. It may be an injury to the cornea. Prolonged exposure to vapor or aerosol may cause discomfort. Steam can cause blurred vision. 1 These effects will be resolved within hours. Flush with water for at least 15 minutes. See a doctor if an allergic reaction noticed. Treatment is symptomatic and supportive. Ingestion can cause liver damage or injury to the thyroid, kidney damage, damage to blood forming system, injuries to male and female reproductive systems. Prolonged and / or repeated contact may result in: liver damage or injury to the thyroid, kidney damage, injury to blood forming system, injuries to male and female reproductive systems. : If conscious, drink plenty of water. Get medical help immediately. Ingestion: 5. Fire Fighting Measures Type of material: Flash point: Extinguishing Media: Specific control measures: Hazardous Decomposition Products: Flammable 116 ºC Water mist, foam, carbon dioxide, and dry powder Use self-contained breathing apparatus with positive pressure NIOSH / MSHA approved and mask full face and protective firefighting clothing. Carbon monoxide, carbon dioxide 6. Accidental Release Measures Environmental precautions: Personal precautions: Destruction and clean up: Avoid infiltration of large volumes into drains, surface water, groundwater and soil. Respiratory protection, safety goggles and protective gloves are recommended. Absorb with sawdust, wood chips or sand. Collect in polyethylene bags for disposal and wash area with water. 7. Handling and Storage Handling: Ensure adequate ventilation when handling. Avoid contact with skin and eyes. Keep away from children. Can generate formaldehyde at temperatures above 150 °C. Respiratory protection is recommended. Keep tightly closed. Store under cool 5 to 30 ºC (preferably 25 ºC), dry conditions. Ensure adequate ventilation. Store in its original container. Not available. Consult the manufacturer before using a pure liquid spray. Storage: Incompatible materials: Other precautions: 8. Exposure Controls/ Personal Protection TLV: Technical measures/precautions: Personal protection Respiratory Protection: Non Available Ensure adequate ventilation during use. Avoid inhalation. Gloves should be worn when mixing or handling the product Respiratory protection is necessary. When handling high concentrations, filter aspirators with independent air supply is prescribed. Use NIOSH approved respiratory protection. Hand protection: Chemically resistant imperviousgloves should be worn as a precaution. Safety goggleswith side shields are recommended. Wear appropriate protective clothing and eye protection / face. Eye Protection: Skin and body protection: 2 9. Physical and Chemical Properties Physical state: Color: Odor: Moisture %: Density: Solubilty/Misciblity in water: Partition coefficient: Steam pressure: Boiling point: Vapor density: (Air = 1): Melting point: Decomposition Temperature: Explosive properties: Auto-ignition temp: Liquid – Soluble concentrate Light yellow Moderate, a polyether N/A 1.0070 at 20 ºC. Dispersible Not applicable <1 mm Hg >150 ºC Heavier than air Not applicable Not determined Not explosive Not applicable 10. Stability and Reactivity Hazardous decomposition products: Materials to avoid: Conditions to avoid: Carbon oxides, silicon oxides and formaldehyde, carbon monoxide is highly toxic if inhaled, the carbon dioxide in sufficient concentrations can act as an asphyxiant.; acute over-exposure to combustion products may result in irritation of the respiratory tract.; This product contains methylpolysiloxanes which can generate formaldehyde at approximately 300 ° F (150 ° C) and more in oxygen containing atmospheres. Formaldehyde is a sensitizer of the skin and respiratory irritant of the eyes and throat, acute toxic potential cancer hazard. None known Not known 11. Toxicological Information LD50: Skin irritant (rat): Eye irritant (rabbit): Acute Oral: Rats: LD50 >2000 mg/kg Acute Dermal: Rats: LD50 >2000 mg/kg Acute inhalation: Rats: LC50 > 2 mg/l, Aerosol LC50: Rats: > 11.78 mg/l (5% dilution in aqueous solution) Moderate skin irritant Severely irritatating 12. Ecological Information Acute Fish: Toxicity to other organisms: Toxicity to algae: Biodegradability: Toxic to aquatic organisms. LC50: Zebra fish: Dose: 2.75 mg / l: Exposure: 96 h NOECZebra fish: Dose: 0.56 mg/l: Exposure: 96 h. Immobilisiation EC50: Daphnia similis: Dose: 22.61mg/l: Exposure: 48 h NOEC: Daphnina similis: Dose: 10 mg/l: Exposure 48 h. EC50: Green algae: Dose: 5.5 mg/l: Exposure: 96 h NOEC: Green algae: Dose: 1 mg/l: Exposure 96 h. Not readily biodegradable 3 13. Disposal Considerations Absorb with sawdust, wood chips or sand. Collect in polyethylene bags for disposal and wash area with water and detergent. Use proper protective clothing and equipment. Avoid infiltration of large volumes into drains, surface water, groundwater and soil. 14. Transport Information The product falls under DOT class 9. 15. Regulatory Information EEC Classification: Hazard Symbol / labeling: S-phrases: National Regulations: Other Regulations: None Class 9 None None None 16. Other Information The purpose of the above information is to describe the product only in terms of health and safety requirements. The information given should not, therefore, be construed as guaranteeing specific properties or as a specification. Customers should satisfy themselves as to the suitability and completeness of such information for their own particular use. Contact Person: Mr. Jonathan Etherington +27 82 921 8428 4