SCH 3U1 ATTRACTIVE FORCES There are different types of forces that exist between molecules and particles. The strength of these particles determines the _______ of the substance. For example, if a substance is solid that means the particles are locked beside each other tightly. This is a ______ force. In the case of gases the forces are ______. The particles themselves move about _______ and when they collide they rebound off each other. Electrostatic Force: This force is referred to as an ____________ interaction or an ionic bond. It is the result of a positive and a negative charge wanting to pull closer to each other. These particles usually form ionic ______. Strong Force. Hydrogen Bonding: Definition - A hydrogen bond is an _________________ in which a hydrogen atom that is bonded to an electronegative atom (_______) is attracted to an unshared pair of _______ on another electronegative atom. This combination creates an attraction (not a bond) that is much _______ than a dipole force or London force. Hydrogen bonds are like any other attractive (intermolecular) forces because the attractions are ___________ in nature. Water is one molecule that displays hydrogen bonding. Because water is a polar molecule, individual water molecules _______ each other by _________ and hydrogen bonds. In order to boil water these numerous interactions must be broken and this requires a lot of _______. This energy needed gives water a much ______ boiling point than would be expected of a molecule of its size and bond type. .. .. .. :O--H - - - :O--H - - - :O--H H | | | | H H H - - - :O--H The hydrogen bond is not only found in water but generally in hydrogen compounds that have elements with high __________. The bonds N-H, O-H and F-H all display hydrogen bonding. Each of the compounds water, ammonia and hydrogen fluoride have a much _______ boiling point than expected. Intermediate Force. Dipole-Dipole Force: This force occurs when a polar molecule interacts with a polar molecule. A polar molecule means that the electrons are shifted ______ the more electronegative element, eg. HCl. In this molecule the electrons are pulled toward the ______, making the chlorine (slightly) negative and the hydrogen positive. The hydrogen chloride molecule is said to have a dipole. + - + - + - + - + - + - H-Cl --- H-Cl --- H-Cl --- H-Cl --- H-Cl --- H-Cl The three dashes indicate the dipole force that exists. (Analogy: a layer of butter between two oreo cookies.) Weak force. London Forces: In an atom or a non-polar molecule the electron cloud is ___________. However, the electrons have a random motion within the electron cloud. In any one instant there may be _____ electrons on one side of the cloud. This will give it a (brief and slight) charge. This can ______ a charge in a neighbouring particle. These interactions that form keep the liquid together and have to be _______ before it becomes a gas. Weak force.