ORGANIZATION OF THE PERIODIC TABLE Period Table Overview The periodic table organizes the different types of atoms, or chemical elements. The elements are arranged by atomic number in rows and columns, from left to right and top to bottom. Vertical columns are called groups or families of elements while periods of elements consist of horizontal rows. Periodic table: Groups similar elements together; represents elements by their symbols; orders elements based on increasing number of protons. Periodic Law – Properties of elements tend to change in a regular pattern when elements are arranged in order of increasing atomic number, or number of protons in their atoms. Using the periodic table to determine electronic arrangement Period – a horizontal row of elements in the periodic table. The period number gives you the highest energy level that contains electrons. Just as the number of protons an atom has increases by one as you move from left to right across a period, so does its number of electrons. Group (family) – a vertical column of elements in the periodic table Atoms of elements in the same group have the same number of valence electrons, so these elements have similar, but not exactly alike, properties. For groups 1 and 2, the number of the group is the number of valence electrons. For groups 13 through 18, subtract 10 to get number of valence electrons. Elements in the same group have similar properties Group 1 16 17 18 Lithium Oxygen Fluorine Neon Sodium Electron Configurations for Selected Elements SOME ATOMS FORM IONS All atoms will be stable with a full outermost energy level; if atoms do not have a full outermost energy level, they will react with other atoms to achieve a full outermost energy level. All energy levels are considered full with eight electrons except the first level, which is full with two electrons. Atoms of Group 1 elements have one valence electron, so they are reactive. Atoms without an octet may undergo ionization – the process of adding electrons to or removing electrons from an atom or group of atoms. Atoms can either gain electrons to achieve an octet or lose electrons to reveal the full outermost energy level. Ionization Atoms are electrically neutral; the number of negatively charged electrons is equal to the number of positively charged protons. An ion is an atom that has an electrical charge, either positive or negative. Ionization is the process whereby gaseous atoms become electrically charged. If an atom undergoes ionization, it no longer has the same number of electrons as it does protons. Thus, the charges don’t cancel. The result is an ion – an atom or group of atoms that has lost or gained one or more electrons and therefore has a net electric charge. Ion An ion is an atom, radical, or molecule that has gained or lost one or more electrons and has a negative or positive charge. Cations are ions that have a positive charge. Anions are ions that have a negative charge. Example: The element sodium has one electron in its third and outermost energy level. The third energy level can hold up to eight electrons. Since energy is required to gain or lose electrons, it requires less energy for the sodium atom to remove one electron from the outer energy level than to add seven electrons. If sodium loses its one outer electron, it would then drop from three to only having two energy levels, and its outermost energy level would be filled. The removal of one electron forms a positively charged sodium ion, Na+. A lithium atom loses one electron to form a 1+ charged ion Example: Lithium is in Group 1, so it has one valence electron. It is in the second period, so it has two levels with electrons. Two fill the first level, and one is in the outer level, which takes eight to be full. What will take less energy to make Lithium stable: gain seven to complete an octet in the second level, or lose one electron to reveal the full first level? Removing this electron is easier, and it forms a cation – an ion with a positive charge. The lithium cation is written Li+. It’s very stable. Hydrogen Ion Simulation A fluoride atom gains one electron Example: Fluorine is in Group 17, so it has seven electrons. It is in the second period, so it has two levels with electrons. Two fill the first level, and seven are in the outer level, which takes eight to be full. What will take less energy to make Fluorine stable: gain one to complete an octet in the second level, or lose seven electrons to reveal the full first level? Adding this electron is easier, and it forms an anion – an ion with a negative charge. The fluorine anion is written F-. It’s very stable. HOW DO THE STRUCTURES OF ATOMS DIFFER? Atomic structure animation table How Do the Structures of Atoms Differ? Atomic number (Z) equals the number of protons. Atoms are always neutral because they have an equal number of protons and electrons. The atomic number also equals the number of electrons. Each element has a different atomic number, which never changes. Mass number (A) equals the number of protons plus the number of neutrons. Isotopes of an element have different numbers of neutrons Isotopes and Nuclides Isotopes are atoms of the same element that have different masses. Nuclide is the general term for any isotope of any element, based on the number of protons and neutrons in its nucleus. Many elements have only one stable form, while other elements have different “versions” of their atoms. These isotopes, or “versions” have the same number of protons and electrons as all other isotopes but have a different number of neutrons. Isotope – any atoms having the same number of protons but different numbers of neutrons. What will vary in isotopes of an element, A or Z? Simulated hydrogen and helium atoms Hydrogen Isotope Simulation Some isotopes are more common than others Calculating the number of neutrons in an atom. The mass of an atom Average Atomic Mass The average atomic mass is the weighted average of the atomic masses of the naturally occurring isotopes of an element.