Ionic Bonding Worksheet How create the Lewis Structure (Dot Diagram) of an atom. (Problems 1-8) Example: Draw the Lewis Structure of a Magnesium Atom. 1. Find the atomic number of that element by locating that element using the periodic table. The atomic number tells us the number of total protons, electrons, and neutrons in the atom. Mg has an atomic number of 12. Mg has 12 TOTAL electrons 2. Find the number of valence electrons. Remember that atomic masses tell us the number of electrons, but NOT the number of VALENCE electrons. Valence electrons are the electrons in the outermost energy level, that determine if the element forms a chemical bond or not. There can be 2 electrons in the innermost energy level of the atom There can be 8 electrons in each of the energy levels after the 1 st one. Magnesium Atomic Number Atomic Mass Number of Protons, electrons, and neutrons Column in the periodic table Number of valence electrons 12 24.305 amus 12 2 2 Mg has 2 valence electrons because it has 12 total electrons. 2 of those occupy the 1 st energy level, and 8 of them occupy the 2nd energy level. Therefore there are 2 electrons left over in the 3 rd energy level. Shortcut- Mg has 2 valence electrons because it is in the 2 nd column. 3. Draw the Lewis structure, by writing down the atomic symbol. Then place each valence electron around the symbol as a dot. Place one at each of the 4 sides of the symbol, then double them up. The most valence electrons that an element can have would be 8 and the least would be 1 valence electron. BAD GOOD Lewis Structures of Atoms: Draw Lewis Structures for the following elements. 1. Cl 5. S 2. H 6. Ca 3. O 7. F 4. Ar 8. Na How to Convert an atom into an ION. (Problems 9-14) Example: What does a Chlorine Ion look like? 1. 2. Draw the lewis structure of a chlorine atom. Follow the octet rule. Atoms are unstable until the have a full outer shell of electrons. For H and He, this means that they have 2 electrons. Form all other elements, this means that they have 8. For this reason, Noble Gasses do NOT form ions. Atom Ion F - Ca 2+ S 2- Ne Does not form an ion If chlorine gains just 1 electron, it will have 8 electrons in its outer shell. So add 1 electron to the chlorine atom. 3. Remember that the charge of an electron is negative. So if we gain 1 electron our atom gets a negative charge. All negatively charged ions are called anions. Write the ion’s charge in the upper right hand side of the lewis structure. 4. If an ion loses electrons to have 8 electrons in its outer shell, it loses negative charges. This makes the atom positively charged. Positively charged ion are called cations. See the steps below for making a sodium cation. Lewis Structures of Ions: Draw Lewis Structures for the following IONS. (one of them doesn’t form an ion) 1. Cl 2. H 5. S 6. Ca 3. O 4. Ar 7. F 8. Na How to draw Lewis Structures of Ionic Compounds (Problems 15-20) Example: What does a molecule would form from Sodium ions and chlorine ions? 1. Draw the lewis structure of a chlorine atom and a sodium atom. 2. Convert the atoms to ions. But… Electrons can’t just come from nowhere (that would violate the 1 st law of Thermodynamics!). So when sodium loses an ion it must be transferred to the chlorine. Draw the process of moving electrons from one atom to the other. 3. Re-draw the lewis structure of the combined molecule. Include the charge of each ion. 4. Sometimes this can be a little more difficult. Think of bonding aluminum to oxygen. Aluminum wants to get rid of 3 electrons, but oxygen can only take 2. Therefore, the last remaining electron must go to another oxygen atom. But this atom is still short 1 electron. In order to make the oxygen have a full octet lets take an electron away from a second Aluminum atom. In order to make the aluminum have a full octet, it would have to lose another 2 electrons, so lets add another oxygen atom Now all 3 oxygen atoms have full octets and both aluminum atoms have full octets. Redraw the ionic compound to make everything look neat. Add in charges. Ionic Bonding: Draw the lewis structures of the following ionic compounds. 15. Potassium and chlorine 16. oxygen and aluminum 17. magnesium and fluorine 18. Bromine and Calcium 19. Lithium and Sulfur How to write the chemical formula of an ionic compound(Problems 20-24) Example: Write the compound made from fluorine and magnesium 1. Draw the lewis structure of the compound that a fluorine atom and a magnesium atom make. Metal Compound Na Nonmetal Cl Al O Al2O3 Mg F MgF2 NaCl 2. Ionic compounds are made when metals and non-metal bond together. Identify the metal and and non-metal using the periodic table 3. Write the atomic symbols of the two elements. The metal always goes first. 4. Since there are 2 fluorine ions in one molecule of this compound, add a “2” subscript after the F. Naming ionic compounds: name the following ionic compounds 20. Potassium and chlorine Answer______________ 21. oxygen and aluminum Answer______________ 22. magnesium and fluorine Answer______________ 23. Bromine and Calcium Answer______________ 24. Lithium and Sulfur Answer______________ How to name ionic compounds(Problems 25-29) Example: Name the compound made from chlorine and sodium. 1. Draw the lewis structure of the compound that a chlorine atom and a sodium atom make. 2. Write the chemical formula of the compound that they make. NaCl 3. The first part of the name is just the metal. Sodium 4. The second part of the name is the nonmetal Sodium chlorine 5. Take away the last syllable of the non-metal and replace it with the “–ide” suffix. Sodium chloride Naming ionic compounds: name the following ionic compounds 25. Potassium and chlorine Answer______________ 26. oxygen and aluminum Answer______________ 27. magnesium and fluorine Answer______________ 28. Bromine and Calcium Answer______________ 29. Lithium and Sulfur Answer______________