Lesson 3 What happens when acids react with metal carbonates? ILO's to be able to describe that acids react with metal carbonates to form salts and identify the gas produced as carbon dioxide. to be able to identify evidence for a chemical reaction. to be able to represent reactions by word equations. to be able to identify the pattern in word equations to produce a general equation. Activities 1) Recap the reaction of metals with acids and the pattern of the reactions, hydrogen gas formed etc. Display the formula of a metal carbonate, eg ZnCO 3. Ask (i) what gas the pupils think might be produced from the reaction of a carbonate with an acid and (ii) how to test that it is carbon dioxide (using lime water). Then demonstrate, in a boiling tube, the reaction of zinc carbonate with sulphuric acid and prove that the gas is CO 2. 2) Practical: Pupils measure out 25cm3 of 0.5M nitric acid in a 100 cm3 beaker. Add a spatula measure of copper carbonate. Keep adding the copper carbonate until all the fizzing (or effervescence) stops. Add no more, there is no point as it is now in excess and no further reaction will take place. Filter the solution and transfer to an evaporating basin. Slowly evaporate the water until the crystals of copper nitrate form. Pupils draw a conclusion to the experiment, stating how they knew a reaction had occurred and highlighting the colour of the crystals formed. Pupils should then attempt to write a word equation for the reaction and devise a general equation for the reaction of metal carbonates and acids 3) Pupils should attempt to complete equations of the following reactions. Higher pupils could attempt the symbol equations and then balance them. Try to complete these for homework sodium carbonate + hydrochloric acid dioxide Na2CO3 + HCl sodium chloride + water + carbon NaCl + H 2O + CO2 sodium carbonate + sulphuric acid dioxide Na2CO3 + H2SO4 Na2SO4 + H2O + CO2 sodium sulphate + water + carbon sodium carbonate + nitric acid dioxide Na2CO3 + HNO3 sodium nitrate + water + carbon NaNO3 + H2O + CO2 calcium carbonate + hydrochloric acid dioxide CaCO3 + HCl CaCl2 + H2O + CO2 calcium carbonate + sulphuric acid dioxide CaCO3 + H2SO4 calcium nitrate + water + carbon Ca(NO3)2 + H2O + CO2 copper carbonate + hydrochloric acid dioxide CuCO3 + HCl copper chloride + water + carbon CuCl2 + H2O + CO2 copper carbonate + sulphuric acid dioxide CuCO3 + H2SO4 calcium sulphate + water + carbon CaSO4 + H2O + CO2 calcium carbonate + nitric acid dioxide CaCO3 + HNO3 calcium chloride + water + carbon copper sulphate + water + carbon CuSO4 + H2O + CO2 Resources Activity 1 2 Resources: lesson 3 Demo Zinc carbonate powder 1M sulphuric acid Lime-water Delivery tube for a boiling tube (1 off) Class set Copper carbonate powder, 4 jars 0.5M Nitric acid( 6 bottles) Filter paper Matches