Curriculum Vitae
Dr. Hideya Koizumi
Mail Address
P.O. Box 419
State University, AR 72467
Office LSW 330B
Lab LSW 508
Tel
(870) 972-2399 Office
FAX (870) 972-3089
Email hkoizumi@astate.edu
Position Held
Instructor
Chemistry
Assistant Prof. of Chemistry
Arkansas State University
Arkansas State University
2009
2009-Current
Education
B.S. in Chemistry, Oklahoma State University
-1996
(Advisor, Prof. Lionel Ruff)
B.S. in Mathematics, Oklahoma State University
-1997
Ph.D. in Chemistry, University of Utah
-2004
(Prof. Peter B. Armentrout)
Post Doctoral Study at University of North Carolina at Chapel Hill
Camille and Henry Dreyfus Postdoctoral Fellowship
-2006
(Prof. Tomas Baer)
Post Doctoral Study at Oak Ridge National Laboratory
-2008
(Dr. Peter T. A. Reilly)
PhD. Dissertation
“Collision Induced Dissociations and Association Reactions Using Guided Ion Beam
Tandem Mass Spectrometer Application of Statistical Theory” [2004]
Dissertation Summary
Kinetic energy dependence of collision induced dissociation and association
reactions are investigated using guided ion beam tandem mass spectrometer. New
thermokinetic method for large systems are developed and tested in several cases.
Award
Recipient of Camille and Henry Dreyfus Postdoctoral Fellowship 2004-2006
Research Interest
Aerosol detection; particle sizing (aerodynamic lens and DMA), trace mass analysis,
reTOF, quadrupole mass filter, quadrupole ion trap, laser ablation
Instrumentation; development of any TOF based mass spectrometer, particle analyzer,
digital quadrupole ion trap and quadrupole mass filter, aerosol inlet, circuit board design
Biological; aerosol MALDI(Matrix Assisted Laser Desorption Ionization) mass
spectrometry
Gas phase ion chemistry; including metal ligand interaction, PST and RRKM theory
Reaction dynamics; including velocity distribution of transient complex, kinetic energy
release
Photoelectron photoion coincidence; including photoionization, velocity distribution,
velocity focusing ZEKE
Quantum chemistry and theoretical chemistry; coupled cluster theory, density functional
theory, relativistic effect, CBS limit for heavy atoms, trajectory calculations, self
consistent reaction field
Modeling associated with experiments
Electrospray ionization, ion dynamics in MS, computational fluid dynamics and transport
phenomena (finite element methods, finite volume methods)
Experience
Experiment
Gas phase ion chemistry, metal ligand interaction, guided ion beam tandem mass
spectroscopy, TOF multi-pole ion guide, quadrupole mass spectrometer, time of flight
mass spectrometer, quadrupole ion trap (digital and conventional), reaction kinetics,
Photoelectron photoion coincidence technique, development of portable aerosol mass
spectrometer, light scatter cell etc.
Instrumentation
Development of reTOF, TOF based particle sizing, digital quadrupole ion trap and
quadrupole mass filter, aerosol inlet, high efficiency ion injection methods, high
resolution function generator
Biological
Aerosol MALDI(Matrix Assisted Laser Desorption Ionization) Mass Spectrometry,
Several aerosol generators including electrospray aerosol generator
Computational
Unimolecular statistical theory (CRUNCH, PST, Pepico etc)
Several quantum chemistry packages such as Gaussian, Molpro, GAMESS etc.
Commercial CFD package (COMSOL)
LabVIEW (virtual instrumentation), FPGA, SIMION, Java, C, Visual Basic
Mathematical Modeling
Fortran, Mathematica, Maple etc
Selected Poster Presentations
2001 Gordon research conference “Association reaction of Cu+ ion and dimethoxy
ethane”
2002 Arrowhead ion chemistry conference “TOF study of Cu+ ion and dimethoxy ethane
association reaction. Velocity distribution of long lived complex and its fragments”
2004 American chemical society national meeting selected poster session “Heats of
formation of acetyl and propionyl radical and ion threshold photoelectron photoion
coincidence”
2004 American chemical society national meeting “Quantitative study of alkyl nitates in
single aerosol particles”
2005 Gordon research conference “Heats of formation of acetyl and propionyl radical and
ion threshold photoelectron photoion coincidence”
2007 ASMS Conference on Mass Spectrometry “On Line Aerosol MALDI Mass
Spectrometer Using Digital Quadrupole Ion Trap”
2008 Arrowhead ion chemistry conference “Digital Ion Trap and Digital Quad Mass
Spectrometry”
2008 ASMS Conference on Mass Spectrometry “A New Method for Digitally Producing
Waveforms and Its Use in Digital Ion Trap Mass Spectrometry”
2010 ASMS “Probing Rapid Method of Isotope 87Sr/86Sr Analysis by ESI-QIT-MS”
2010 American chemical society national meeting “Interaction of 12c4 with Alkali Metal
Cation in Aqueous Solution: Theoretical Investigation Using Polarized Continuum
Model”
2010 INBRE Research Conference “Breaking Through Limitations: Instrumentation
Analysis for Larger Molecules: A Theoretical Study and Simulations”
Oral Presentations
1999 Arrowhead ion chemistry conference “Collision induced dissociation and
theoretical study of Cu+ and dimethyl ether”
2001 Arrowhead ion chemistry conference “Collision induced dissociation and
association reaction of Cu+ and dimethoxy ethane”
2003 Arrowhead ion chemistry conference “Association reaction of alkali metal and
dimethoxy ethane”
2006 Oak Ridge National Laboratory “Development of portable aerosol mass
spectrometer”
Co-author of several other oral presentations (not listed here)
Publications (Conference proceedings not listed here)
[1] Collision-Induced Dissociation and Theoretical Studies of Cu+-Dimethyl Ether
Complexes,
Koizumi, H.; Zhang, X.-G.; Armentrout, P. B.; J. Phys. Chem. A.; 105(11); 2001, pp.
2444-2452
[2] Collision-Induced Dissociation and Theoretical Studies of Cu+-Dimethoxyethane
Complexes,
Koizumi, H.; Armentrout, P. B.; Journal of The American Society for Mass
Spectrometry; 12(5); 2001, pp. 480-489.
[3] Bond Dissociation Energies and Structures of CuNO+ and Cu(NO)2+,
Koszinowski, K.; Schroder, D.; Schwarz, H.; Holthausen, M. C.; Sauer, J.; Koizumi, H.;
Armentrout, P. B.; Inorg. Chem; 41(22); 2002, pp. 5882-5890.
[4] Collision-Induced Dissociation and Theoretical Studies of Ag+(methanol)n, n = 1- 4,
Koizumi, H.; Larsen, M.; Armentrout, P. B.; Feller, D.; J. Phys. Chem. A.; 107(16); 2003,
pp. 2829-2838.
[5] Sequential Bond Energies of Ag+(H2O)n and Ag+(dimethyl ether)n, n = 1–4,
determined by threshold collision-induced dissociation,
Koizumi, H.; Larson, M.; Muntean F.; Armentrout P. B.; International Journal of Mass
Spectrometry; 228(2-3), 2003, pp. 221-235
[6] The Kinetic Energy Dependence of Association Reactions. A New Thermokinetic
Method for Large Systems,
Koizumi, H.; Armentrout, P. B.; The Journal of Chemical Physics; 119(24), 2003, pp.
12819-12829
[7] Reaction of Cu+ with Dimethoxyethane: Competition Between Association and
Multiple Dissociation Channels,
Koizumi, H.; Muntean F.; Armentrout P. B.; The Journal of Chemical Physics; 120(2),
2004, pp. 756-766
[8] Heats of Formation of the Acetyl Radical and Ion Obtained by Threshold
Photoelectron Photoion Coincidence,
Fogleman, E. A.; Koizumi, H.; Kercher, J. P.; Sztaray, B.; Baer, T.; J. Phys. Chem. A.;
108(24); 2004, pp. 5288-5294.
[9] The Heats of Formation of tert-Butyl Isocyanide and Other Alkyl Isocyanides by
Photoelectron Photoion Coincidence Spectroscopy,
Koizumi, H.; Baer, T.; J. Phys. Chem. A.; 108(28); 2004, pp. 5956-5961.
[10] Heats of Formation of the Propionyl Ion and Radical and 2,3-Pentanedione by
Threshold Photoelectron Photoion Coincidence Spectroscopy,
Kercher, J. P.; Fogleman, E. A.; Koizumi, H.; Sztaray, B.; Baer, T.; J. Phys. Chem.
A.;109(5); 2005, pp. 939-946.
[11] Sequential Bond Energies of Fe+(CO2)n, n = 1-5, Determined by Threshold
Collision-Induced Dissociation and ab Initio Theory,
Armentrout, P. B.; Koizumi, H.; MacKenna, M.; J. Phys. Chem. A.; 2005; 109(50) pp.
11365-11375
[12] Heats of Formation of GeH4, GeF4 and Ge(CH3)4,
Koizumi, H.; Davalos, J. Z.; Baer, T.; Chemical Physics ; 2006; 324(2-3) pp. 385-392
[13] Heat of Formation of Ge (CH3)3X X = Cl, Br, CH3,
Davalos, J. Z.; Koizumi, H.; Baer, T. J. Phys. Chem. A.; 2006; 110(15) pp. 5032-5037
[14] Trapping of Intact, Singly-Charged, Bovine Serum Albumin Ions
Injected from the Atmosphere with a 10-cm Diameter, Frequency-Adjusted, Linear
Quadrupole Ion Trap,
Koizumi, H.; Whitten, W.B; Reilly P.T., Journal of The American Society for Mass
Spectrometry; Volume: 281 Issue: 3 Pages: 108-114
[15] The Effect of Endcap Electrode Holes on the Resonant Ejection from an Ion Trap,
Koizumi, H.; Whitten, W.B; Reilly P.T., Koizumi, E., International Journal of Mass
Spectrometry Volume: 281 Issue: 3 Pages: 108-114
[16] Derivation of mathematical expressions to define resonant ejection from square and
sinusoidal wave ion traps,
Koizumi, H.; Whitten, W.B; Reilly P.T., Koizumi, E
International Journal of Mass Spectrometry Volume: 286 Issue: 2-3 Pages: 64-69
[17] Controlling the Expansion into Vacuum-the Enabling Technology for Trapping
Atmosphere-Sampled Particulate Ions
Koizumi H, Wang XL, Whitten WB, Reilly P.T.,
Journal of The American Society for Mass Spectrometry Volume: 21 Issue: 2 Pages:
242-248
[18] A novel phase-coherent programmable clock for high-precision arbitrary waveform
generation applied to digital ion trap mass spectrometry
Koizumi H, Jatko B, Andrews WH, Whitten WB, Reilly P.T. International Journal of
Mass Spectrometry
Volume: 292 Issue: 1-3 Pages: 23-31
[19] Theoretical and ATR-FTIR Study of Free 12-Crown-4 in Aqueous Solution
Tanika Arora, Hashim Ali, W. A. Burns, E. Koizumi, H. Koizumi
Chemical Physics Letters
Volume. 502, Issue: 4-6, Pages: 253-258
[20] Simulation of duty cycle-based trapping and ejection of massive ions using linear
digital quadrupoles: The enabling technology for high resolution time-of-flight mass
spectrometry in the ultra high mass range
J. Lee, M A. Marino, Koizumi H, Reilly P.T. International Journal of Mass
Spectrometry
Volume: 304 Issue: 1, Pages: 36-40
[21] An Investigation of aqueous Sr, Rb, and Crown Ether Mixture Solutions by ESIQITMS by Post Column Addition
Sheng Song, Rohana Liyanage, Jackson Lay, Richard Warby, Koizumi H, Analytical
letters Volume. 44, Issue: 12, Pages 2170-2181
[22] A hybrid approach to calculating Coulombic interactions: An effective and efficient
method for optimization of simulations of many ions in quadrupole ion storage device
with SIMION
Saito K., Reilly P. T. A., Koizumi E., Koizumi H., International Journal of Mass
Spectrometry Volume: 315 Issue: 1, Pages: 74-80
[22] Application of Parallel Hybrid Algorithm in Massively Parallel GPGPU—The
Improved Effective and Efficient Method for Calculating Coulombic Interactions in
Simulations of Many Ions with SIMION
Saito K., Koizumi E., Koizumi H., Journal of The American Society for Mass
Spectrometry {Accepted for publication}Volume: X Issue: X Pages: X-X
Patents Awarded
[1] US Patent
20090256640 AGILE HIGH RESOLUTION ARBITRARY WAVEFORM
GENERATOR WITH JITTERLESS FREQUENCY STEPPING 10-15-2009
Teaching
General Chemistry (Lecture)
Computer for Chemistry (Lecture)
Quantitative Analysis (Lecture & Lab)
Instrumentation (Lecture & Lab)
Special Topics
Research in Chemistry
Advisee
Master of Science
Graduated
Sheng Song M.S. 2010 Spring Arkansas State University
Tanika Arora M.S. Summer 2010 Arkansas State University
Yi She M.S. 2010 Fall Arkansas State University
Bachelor of Science
Blake Shands 2010
Jacquelyn Thomas 2010
Larry Neighbors 2011
Current
Chen Xi Zhu M.S.
Kenichiro Saito B.S.
Professional affiliations
American Society for Mass Spectrometry
American Chemical Society
American Association for Aerosol Research