Chemistry – Study Guide for 2nd Trimester Exam (Chapters 9 – 11.1) Chapter 9 – Chemical Names and Formulas 9.1 – Naming Ions When the metals in Groups 1A, 2A, and 3A lose electrons, they form cations with positive charges equal to their group number. The charge of any ion of a Group A nonmetal is determined by subtracting 8 from the group number. The charges of cations of many transition metal ions must be determined from the number of electrons lost. When a cation can have more than one ionic charge, a Roman numeral is used in the name to indicate the charge. The names of most polyatomic anions end in –ite or –ate. 9.2 – Naming and Writing Formulas for Ionic Compounds The name of a binary ionic compound is the cation name followed by the anion name. To write the formula for a binary ionic compound, write the symbol for the cation and then the anion. Then balance the charges. To write formulas for compounds containing polyatomic ions, write the symbol for the metal ion followed by the formula for the polyatomic ion and balance the charges. To name a compound containing a polyatomic ion, state the cation first and then the anion. 9.3 – Naming and Writing Formulas for Molecular Compounds Prefixes show how many atoms of each element are present in a molecule of a binary compound. To write the formula for a binary molecular compound, write the symbols for the elements and use the prefixes to determine the subscripts. Omit mono- for a single atom. 9.4 – Naming and Writing Formulas for Acids and Bases An acid is a combination of a monatomic or polyatomic anion with sufficient hydrogen atoms to make the compound electrically neutral. Acids are names as shown in Table 9.5. A base is a combination of a cation with as many hydroxide ions as are needed to make the compound electrically neutral. Bases are named in the same way as other ionic compounds. Chemistry – Study Guide for 2nd Trimester Exam (Chapters 9 – 11.1) 9.5 – The Laws Governing Formulas and Names The ways that compounds form are summed up in two laws: the law of definite proportions and the law of multiple proportions. To name a compound or write its formula, follow the flowcharts in Figures 9.20 and 9.22 to the correct name or formula. Chapter 9 Vocabulary: Acid Base Binary Compound Law of Definite Proportions Law of Multiple Proportions Monatomic Ion Polyatomic Ion Chapter 10 – Chemical Quantities 10.1 – The Mole: A Measurement of Matter Three methods for measuring the amount of a substance are by count, by mass, and by volume. A mole of any substance always contains Avogadro’s number of representative particles, or 6.02 x 1023 representative particles. The atomic mass of an element expressed in grams is the mass of a mole of the element. To calculate the molar mass of a compound, find the number of grams of each element contained in one mole of the compound. Then add the masses of the elements in the compound. 10.2 – Mole-Mass and Mole-Volume Relationships The molar mass of an element or compound is the conversion factor for converting between the mass and the number of moles of a substance. One mole of any gas occupies a volume of 22.4L at standard temperature and pressure. One mole of any substance contains Avogadro’s number of particles, so 22.4L of any gas at STP contains 6.02 x 1023 representative particles of that gas. 10.3 – Percent Composition and Chemical Formulas To determine the percent by mass of any element in a given compound, divide the element’s mass by the mass of the compound and multiply by 100% Chemistry – Study Guide for 2nd Trimester Exam (Chapters 9 – 11.1) An empirical formula of a compound is the simplest whole-number ratio of atoms of the elements in the compound. The molecular formula of a compound is either the same as its experimentally determined empirical formula, or it is a simple whole-number multiple of it. Chapter 10 Vocabulary: Avogadro’s Hypothesis Avogadro’s Number Empirical Formula Molar Mass Mole Percent Composition Representative Particle Standard Temperature and Pressure (STP) Key Equations: 1mole 6.02 x1023 6.02 x1023 Representative Particles = moles x 1mole mass ( grams ) mass ( grams ) number of moles x 1mole 1mole Moles mass(grams) x mass ( grams ) grams grams 22.4 L x mole Liter 1mole 22.4 L Volume of Gas = mole of gas x 1mole mass of element % Mass of Element = x100% mass of compound Moles Representative Particles x Chapter 11 – Chemical Reactions 11.1 – Describing Chemical Reactions To write a word equation, write the names of the reactants to the left of the arrow separated by plus signs; write the names of the products to the right of the arrow, also separated by plus signs. To write a skeleton equation, write the formulas for the reactants to the left of the yields sign and the formulas for the products to the right. After writing the skeleton equation, use coefficients to balance the equation so that is obeys the law of conservation of mass. Chemistry – Study Guide for 2nd Trimester Exam (Chapters 9 – 11.1) Chapter 11 Vocabulary: Activity Series Balanced Equation Catalyst Chemical Equation Coefficients Combination Reaction Combustion Reaction Complete Ionic Equation Decomposition Reaction Double-Replacement Reaction Net Ionic Equation Single-Replacement Reaction Skeleton Equation Spectator Ion