8.3 STRONG AND WEAK ACIDS AND BASES DEFINITIONS: ELECTROLYTE: any substance that dissolves in water to produce ___________ (and hence conduct _________________ (may be acids, bases or salts) STRONG ACIDS/BASES/ELECTROLYTES: dissociate __________________ into ions WEAK ACIDS/BASES/ELECTROLYTES: dissociate _________________into ions; (usually less than____%). SOME EXAMPLES OF STRONG & WEAK ACIDS: STRONG NAME ACIDS *H2SO4(aq) diprotic WEAK ACIDS *HCOOH(aq) *HNO3(aq) monoprotic *CH3COOH(aq) *HCl(aq) monoprotic *C2H5COOH(aq) HBr(aq) monoprotic NAME *H2CO3(aq) (diprotic) HI(aq) monoprotic H3PO4(aq) (triprotic) HClO3(aq) monoprotic H2S(aq) (diprotic) *IB requires you to memorize the entities with an ASTERISK BEFORE IT ONLY! *NOTE: There are ONLY_____ strong acids….if it’s not one of these 6, the acid is ____________. *The first 3 Weak acids listed are example of ____________________ acids. They are all monoprotic. We will study these in more detail when we get to organic chemistry. ACTIVITY: a) Illustrate the “diprotic nature” of sulfuric acid: b) Illustrate the monoprotic nature of ethanoic acid: *Use a ______________arrow to represent _____% dissociation; a _____________ acid or base. *Use _____________ arrows to represent ______________dissociation; a ___________ acid or base. VIEW THE FOLLOWING WEB ANIMATION - Weak vs. Strong Acids: http://www.mhhe.com/physsci/chemistry/essentialchemistry/flash/acid13.swf Strong Acids Weak Acids *DEMONTRATION: Conductivity (Weak versus Strong Acid) ACID CONDUCT? EXPLANATION HCl(aq) WEAK OR STRONG? CH3COOH(aq) *COMMON MISCONCEPTION: Don’t confuse _______________________ with __________________. CONCENTRATION = ______________ to _______________ ratio [can be changed by adding _____________ (i.e. diluting)] STRENGTH = “strong” and “weak” are _______________________ of acids and bases that ______________ be changed (e.g. cannot “weaken” a substance by adding water) ACID HCl(aq) CATEGORY _____ mol dm DILUTE _____ mol dm-3 _____ mol dm-3 _____ mol dm-3 CONCENTRATED -3 CH3COOH(aq) DISTINGUISHING BETWEEN STRONG AND WEAK ACIDS: TEST Add reactive metal e.g. Mg STRONG ACID __________ H2 production WEAK ACID __________ H2 production Add a carbonate, CO32- __________ CO2 production __________ CO2 production Conductivity _______ (many _______) ________ (few ______) pH of 0.1 M solution =1 =3-4 EXTENSION: Draw Lewis structures for nitric, phosphoric and sulfuric acids: SOME EXAMPLES OF STRONG & WEAK BASES: STRONG BASES *LiOH NAME WEAK BASES *NH3 *NaOH *CH3NH2 *KOH *C2H5NH2 *Ba(OH)2 *C3H7NH2 NAME *Group ___ & ____ hydroxides = _____________ bases. *The last 3 weak bases listed are examples of _______________. Again, we will study these in more detail when we get to organic chemistry. *ACTIVITY: a) Write dissociation equations for sodium hydroxide and barium hydroxide. b) Write dissociation equations for ammonia and aminomethane.