Name: ______________________________ Date: ____________________ Period: __________ CHAPTER 5 TEST REVIEW 1. Give the electron configurations for the following elements. A. B. C. D. E. F. Mg 1s2 2s2 2p6 3s2 K 1s2 2s2 2p6 3s2 3p6 4s1 Ge 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p2 Fe 1s2 2s2 2p6 3s2 3p6 4s2 3d6 O 1s2 2s2 2p4 B 1s2 2s2 2p1 2. Give the orbital filling diagrams for the following elements. Mg A. 1s2 2s2 2p6 3s2 1s B. 2s C. 2s D. 1s 2p 3s 3p 4s 1s2 2s2 2p4 O 1s 3s 1s2 2s2 2p6 3s2 3p6 4s1 K 1s 2p 2s 2p 1s2 2s2 2p1 B 2s 2p 3. Write the noble gas notation for the following elements. Na: [Ne] 3s1 c) V: [Ar] 4s2 3d3 b) F: [He] 2s2 2p5 d) Mg: [Ne] 3s2 a) 4. Give the Lewis electron dot diagrams for the following elements. A. Mg Mg D. He He B. K K E. O O C. Ge Ge F. B B 5. Give the number of orbitals & maximum number of electrons in each of the sublevels: A. s sublevel 1 orbital 2 electrons B. p sublevel 3 orbitals 6 electrons C. d sublevel 5 orbitals 10 electrons D. f sublevel 7 orbitals 14 electrons 6. How many valence for each of the following elements? A. atomic number 7 Nitrogen (N) - 1s22s22p3 = 5 valence electrons B. atomic number 17 Chlorine (Cl) - 1s22s22p63s23p5 = 7 valence electrons C. atomic number 33 Arsenic (As) - 1s22s22p63s23p64s23d104p3 = 5 valence electrons D. atomic number 5 Boron (B) - 1s22s22p1 = 3 valence electrons 7. Give the name of the element for each of the following electron configurations. A. 1s2 2s2 2p3 Nitrogen B. 1s2 2s2 2p6 3s2 3p6 4s2 3d8 Nickel C. 1s2 2s2 2p6 3s2 3p5 Chlorine 8. When given an orbital filling diagram for an element, be able to determine which of the rules is violated: Example: What rule(s) are violated in the following diagram? 1s 2s 2p 3s 3p 1s orbital should be filled before filling the 2s (lower energy levels fill up first) Aufbau Principle is violated - 2p orbital has two electrons with the same spin. The two electrons should have opposite spins (one up arrow and one down arrow) Pauli Exclusion Principle violated - In 3p orbital each orbital should get one electron before a single orbital gets two Hund’s Rule is violated 9. How does light behave like a wave? How does light behave like a particle? Light behaves like a wave: with a wavelength and frequency. Electromagnetic waves have two fields: electric field and magnetic field which are perpendicular (90 degrees) to each other. Light behaves like a particle: when high frequency light encounters metal, a photon (particle of light) is released which contains a specific quantity (quantum) of energy, calculated with E = hʋ. 10. Sketch a beryllium-9 atom (Be) showing the proper number of p+, n0 and e-. Sketch what happens to the electrons when the atom is energized (i.e., by electricity or flame). Show where the photon is released. A Be atom contains 4 protons (assume 5 neutrons) and 4 electrons. When energized, electrons jump to higher energy levels. When they jump back down, they release energy in the form of a light photon. 11. Define the following terms or equations: a. wavelength, : the distance between crests (or any two equivalent points) on wave b. atomic emission spectrum: the set of frequencies of light emitted by the atoms of an element c. E = hʋ Equation used to calculate the energy of a photon developed by Planck d. Electromagnetic Spectrum The range of wavelengths of electromagnetic radiation e. c = ʋ Equation that relates the wavelength, frequency, and speed of an electromagnetic wave f. electromagnetic radiation: a form of energy with wave-like behavior as it travels through space g. photon: a particle of light energy that carries a quantum of energy h. frequency number of waves per second i. the levels and sublevels of the electron cloud: (1) Energy Level a 3-D region around the nucleus of an atom that describes an electrons probable location. There are 7 energy levels in an atom. Each energy level can be broken down into sublevels. The 4 sublevels are s, p, d, f (2) Sublevel Each sublevel contains orbitals. Each orbital can only contain 2 electrons max. (3) Orbital 12. When given an electromagnetic spectrum be able to identify which of a pair of waves has a longer wavelength and a higher frequency. a) Which waves have the longest wavelength? Radio Waves: longer wavelength but lower frequency & energy. b) Which waves have the shortest wavelength? Gamma (Rays: shorter wavelength, but higher frequency & energy. c) Do visible light waves have a higher or lower frequency compared to ultraviolet? ROYGBIV: Red has the lowest energy & frequency and longest wavelength. Visible light has lower frequency compared to ultraviolet. d) Do x-rays have a longer or shorter wavelength compared to infrared waves? X-rays have shorter wavelength compared to infrared. = wavelength;= frequency; = gamma 13. How are atomic emission spectra used to identify an element (think about how you could identify the element lamps)? Each element has its own unique emission spectra which can be used like a “fingerprint” to identify the element. 14. Problem solving: a. What is the wavelength of electromagnetic radiation having a frequency of 5.00×1012 Hz? c = λѵ Where c is speed of light (3.00×108 m/s) and ѵ is frequency (5.00×1012 Hz) λ = (3.00×108 m/s) (5.00×1012 1/s) λ = 6.00×10-5 m b. What is the frequency of electromagnetic radiation having a wavelength of 3.33×10-8 m? c = λѵ Where c is speed of light (3.00×108 m/s) and λ is wavelength (3.33×10-8 Hz) c = λѵ 8 ѵ = (3.00×10 m/s) (3.33×10-8 m) ѵ = 9.00×1015 Hz or 9.00×1015 /s c. Calculate the energy of a photon of violet light with a frequency of 6.8×1014 Hz. E=hѵ Where h is Planck’s Constant 6.626×10-34 J•s and ѵ is frequency (6.8×1014 Hz) E = (6.626×10-34 J•s) x (6.8×1014 Hz) E= 4.5×10-19 J d. Calculate the energy of a photon of ultraviolet light that has a frequency of 5.02×1020 Hz. E=hѵ Where h is Planck’s Constant 6.626×10-34 J•s and ѵ is frequency (5.02×1020 Hz) E = (6.626×10-34 J•s) x (5.02×1020 Hz) E= 3.33×10-13 J