Unit 2 – Atomic Theory and Periodicity Review Section I: History In each box, write the name of the scientist(s) associated with the statement. Choose from among the following: Democritus Dalton Bohr Rutherford Thomson Schroedinger and Heisenberg There are small negatively charged particles inside an atom Thomson His discovery was made after conducting an experiment with gold foil Rutherford There is a small, dense, positively charged nucleus Rutherford Atoms are small, hard spheres Dalton and Democritus Most of an atoms mass is in the nucleus Rutherford Electrons are found in electron clouds, not in defined paths Schroedinger and Heisenberg Electrons follow a definite path but can jump from one path to another Bohr Elements combine is specific proportions to make compounds Dalton Atoms are mostly empty space Rutherford Atoms are uncuttable Democritus Atoms of one element are all the same, but atoms of different elements are different Dalton His theory of atomic structure led to the “plum pudding” model of atoms Thomson Electron paths cannot be defined for certain Schroedinger and Heisenberg All substances are made of atoms Dalton Section II: Atomic Vocabulary (unscramble) 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. Weighted average of all naturally occurring isotopes of the same element. (mictoa sams) atomic mass The building blocks of matter (moats) atoms Positively charged particle in an atom (torpno) proton Made up of protons and neutrons (ucselun) nucleus Particle in an atom that has no charge (tronune) neutron Atoms with the same number of protons but a different number of neutrons (sootpies) isotopes Negatively charged particle in an atom (cleenrot) electron Number of protons in a nucleus (mictoa brumen) atomic number Regions where electrons are likely to be found (renectol scudlo) electron clouds Sum of protons and neutrons (sams brumen) mass number Section III: Isotopes Practice Complete the table below. Complete atomic symbol 14 C 6 𝟕𝟖 I 𝟓𝟑 Atomic # Mass # # of protons # of neutrons # of electrons 6 14 6 8 6 53 78 53 25 53 𝟑𝟓 Cl 𝟏𝟕 17 35 17 18 17 54 Fe 26 𝟒 He 𝟐 26 54 26 28 26 2 4 2 2 2 238 U 92 92 238 92 146 92 11. Name the element which has the following number of particles: a. 82 electrons, 125 neutrons, 82 protons Lead-207 b. 53 protons, 53 electrons, 74 neutrons Iodine-127 12. Naturally occurring europium consists of two isotopes with masses of 151 and 153 amu. The respective abundances are 48.03% and 51.97%. What is the atomic mass of europium? 152 amu (or 152 g/mol) 13. Strontium consists of four isotopes. There masses and abundances are listed below. Use this data to calculate the atomic mass of strontium. Mass Abundance 84 0.50% 86 9.9% 88 amu (or 88 g/mol) 87 7.0% 88 82.6% NOTE: On the test you will need to round average atomic masses to the correct number of significant figures, based on the data given. Section IV: Unit Conversions (Mass-Moles-Atoms) 14. How many moles are in 4.14x1022 atoms of boron? 0.0687 mol 15. Determine the mass in grams of 6.8 moles of iron. 380 g 16. What is the mass of 1.62 x 1023atoms of carbon? 3.23 g 17. How many atoms are in 2.17 grams of zinc? 2.00 x 1022 atoms Section V: Regions of the periodic table 18. Name the following regions of the periodic table. a. Group IA alkali metals e. Groups IB – VIIIB transition metals b. Group IIA alkaline earth metals f. The top row of the f block lanthanides c. Group VIIA halogens g. The bottom row of the f block actinides d. Group VIIIA noble gases 19. List the six metalloids (aka semimetals). Boron, silicon, germanium, arsenic, antimony, & tellurium 20. List the seven diatomic elements. hydrogen, nitrogen, oxygen, fluorine, chlorine, bromine, iodine Section VI: Electron configurations and Orbital diagrams Write the electron configurations and draw the corresponding orbital diagrams and the Lewis dot diagram for the elements below. 21. 22. 23. 24. 25. 26. 27. 28. 29. 30. 31. Hydrogen Boron Sodium Krypton Chromium Phosphorus Carbon Oxygen Potassium Cobalt Platinum 1s1 See the additional pages at the end of this 1s2 2s2 2p1 document for orbital diagrams 1s2 2s2 2p6 3s1 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 1s2 2s2 2p6 3s2 3p6 4s2 3d4 1s2 2s2 2p6 3s2 3p3 1s2 2s2 2p2 1s2 2s2 2p4 1s2 2s2 2p6 3s2 3p6 4s1 1s2 2s2 2p6 3s2 3p6 4s2 3d7 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f14 5d8 Write the abbreviated electron configurations and orbital diagrams for the elements below. 32. 33. 34. 35. 36. Platinum Plutonium Neodymium Lead Cesium [Xe] 6s2 4f14 5d8 [Rn]7s2 5f6 [Xe]6s2 4f4 [Xe] 6s2 4f14 5d10 6p2 [Xe]6s1 Describe each of the following rules for electrons filling orbitals in an electron cloud. 37. Aufbau rule – each electron occupies the lowest energy orbital available 38. Pauli exclusion principle – a max of two electrons may occupy one orbital but the must have opposite spins 39. Hund’s rule – single electrons must occupy each equal-energy orbital before an opposite spin electron is added 40. Heisenberg uncertainty principle – it is impossible to know both the velocity and position of an electron at the same time Section VIII: Periodic Trends 41. Rank the following elements by increasing atomic radius: carbon, aluminum, oxygen, potassium. O, C, Al, K 42. Rank the following elements by increasing electronegativity: sulfur, oxygen, neon, aluminum. Ne, Al, S, O 43. Rank the following elements by increasing first ionization energy: bromine, strontium, arsenic, calcium Sr, Ca, As, Br 44. Why does fluorine have a higher first ionization energy than iodine? Fluorine’s valence shell is closer to the nucleus that iodine’s (fluorine has fewer shielding electrons). Thus, the nucleus has a stronger attraction for fluorine’s valence electrons, making them harder to remove.