Mexichem Specialty Resins, Inc. TECHNICAL ASSISTANCE BRIEF NUMBER: 013 ROTARY SCREEN COATING WITH GEON™ RESINS Rotary screen-printing is a method for coating plastisol on fabric, paper, and non-wovens. In rotary screening, the doctor blade is mounted in the interior of a cylindrical screen, through which the plastisol is extruded onto the substrate. The lack of stress on the substrate, the degree of control over penetration into the subsrate, the ability to coat on an uneven surface, and the possibilities for making discontinuous coatings makes this a unique application technique. A wide variety of Geon Vinyl resins are used in this technology. Lo-Sope resins, which have the required rheological behavior are available in a range of molecular weights. Foam printing can be done on the rotary screen. Geon Vinyl foam resins are available in different molecular weights, and with rheologies suitable for thin or thick coatings. Typical applications for rotary screen coating with plastisols are: - Thin coating on paper "Spanished" artificial leather Fabric coating Printed foam Starting point formulations and operating conditions are as follows: .Thin Coating on Paper Formulation: Item Level (phr) Geon™ 179 Geon™ 215 DINP TXIB Paraplex G62 Thermal Stabilizer Atomite TiO2 Loxiol G10 Deplastol 70 30 55 10 5 2.5 20 15 0.4 1.5 209.4 Brookfield RVF Viscosity, 1 Day, (cps) Severs Viscosity 2 RPM 20 RPM 15,300 6,800 Mexichem Specialty Resins, Inc. Pressure (psi) Efflux (g) Shear Rate (sec.1 ) Viscosity (cps) 10 12.8 290 1900 30 36.8 820 1980 50 62.2 1390 1950 70 87.9 1960 1930 90 117.2 2600 1860 Conditions: Screen: Standard Stork 20 Mesh Blade Length: 28mm Blade Pressure Setting: 5 Substrate: Swift Strip J1632 Line Speed (ft/min) 28 28 49 84 Whisper Blade Used No Yes Yes Yes Film Thickness (mils) 2.0 2.0 2.0 1.7 2.54 2.59 2.94 2.39 Coating Weight, Dry (oz/yd2) 2. "Spanished" Artificial Leather Formulation A was coated onto an embossed release paper at 14 ft/min using a blade length of 25.4mm. A film thickness of 2.2mm resulted. Formulation B was then coated upon film A at 14 ft/min. The combined thickness of the two coatings was 5.5 mil. A standard Stork 60mesh screen was used for both coatings. Formulation A Item Geon™ 179 Geon™ 215 Palatinol 711P TXIB Paraplex G62 Thermal Stabilizer Mapico Brown Powder #422 Harwick Black Paste 90PC03 Cab-O-Sil M-5 Mineral Spirits Level (phr) 70 30 45 10 5 3 1 1 1 10 Mexichem Specialty Resins, Inc. TOTAL: 176 Severs Efflux, initial (g/100 sec.): 0.1560 cm orifice, 95 psi 416 Brookfield RVF Viscosity, initial (cps) 2 RPM 53,200 20 RPM 10,300 Formulation B Item Geon™ 179 Geon™ 215 Palatinol 711P TXIB Paraplex G62 Thermal Stabilizer TiO2 B123 Ruscoe Brown Paste 24475 Ruscoe Medium Chrome Yellow 17940-B TOTAL: Severs Efflux, initial (g/100 sec.): 0.1560 cm orifice, 95 psi Level (phr) 70 30 45 10 5 3 10 10 10.4 193.4 176 Mexichem Specialty Resins, Inc. 3. Fabric Coating Formulation Item Level (phr) Geon™ 179 Geon™ 215 Palatinol 711P Paraplex G62 TXIB Thermal Stabilizer TiO2 Atomite Cab-O-Sil M-5 70 30 70 3 10 2 10 30 1.5 TOTAL: 226.5 Brookfield RVF Viscosity, (cps) 2 RPM 38,800 20 RPM 8,560 Severs Viscosity Pressure (psi) Efflux (g) Shear Rate (sec.1 ) Viscosity (cps) 10 26.3 590 920 30 95.2 2120 760 50 178 3870 680 70 267 5960 640 90 355 7920 620 Conditions: Screen: Stork 20 Mesh Penta Blade Length: 25.4mm Blade Pressure Setting: 3 Substrate: 50/50 Polyester/Cotton Scrim Line Speed: 49 ft/min. Dry Coating Weight: 2.6 oz/yd2 Mexichem Specialty Resins, Inc. 4. Printable Foam Formulation Item Level (phr) Geon™ 180X5 Geon™ 215 Palatinol 711P TXIB Paraplex G62 TiO2 Celogen OT AZ3990 Actafoam R-3 Cab-O-Sil M-5 Ruscoe Chrome Green Oxide #25763 70 30 65 10 5 10 0.5 1.5 3 1.5 2.6 TOTAL: 199.1 Brookfield RVF Viscosity, (cps) Initial: 1 Day 2 RPM 29,600 2 RPM 20 RPM 6,130 20 RPM Severs Viscosity Pressure (psi) 38,600 8,780 Efflux (g) Shear Rate (sec.1 ) Viscosity (cps) 10 16.4 367 1470 30 52.8 1180 1370 50 89.4 2000 1350 70 125.4 2800 1340 90 172.6 3860 1250 Conditions: Screen: Standard Stork 14 Mesh Blade Length: 28mm Blade Pressure Setting: 6 3-mil coating printed which foams to 8 mil when heated at 390F for two minutes. Mexichem Specialty Resins, Inc. Raw Material Sources Geon™ 180X5 PVC Dispersion Resin Mexichem Specialty Resins, Inc. Geon™ 179 PVC Dispersion Resin Mexichem Specialty Resins, Inc. Geon™ 213 PVC Blending Resin Mexichem Specialty Resins, Inc. DINP Plasticizer Exxon Palatinol 711P Plasticizer BASF TXIB Plasticizer Eastman Actafoam R-3 Stabilizer/Activator Olin Paraplex G-62 Secondary Stabilizer C.P. Hall Atomite Filler ECC International TiO2 Pigment DuPont Loxiol G10 Lubricant Henkel Deplastol Viscosity Depressant Henkel Cab-O-Sil M-5 Fumed Silica Cabot Celogen OT Blowing Agent Galata Corporation Celogen 3990 Blowing Agent Galata Corporation © Mexichem Specialty Resins, Inc. 2013 The information contained herein is believed to be reliable, but no representations, guarantees or warranties of any kind are made as to its accuracy, suitability for particular applications or the results to be obtained therefrom. The information is based on laboratory work with smallscale equipment and does not necessarily indicate end product performance. Because of the variations in methods, conditions and equipment used commercially in processing these materials, no warranties or guarantees are made as to the suitability of the products for the application disclosed. Full-scale testing and end product performance are the responsibility of the user. Mexichem Specialty Resins, Inc. shall not be liable for and the customer assumes all risk and liability of any use or handling of any material beyond Mexichem Specialty Resins, Inc.’s direct control. The SELLER MAKES NO WARRANTIES, EXPRESS OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, THE IMPLIED WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE. Nothing contained herein is to be considered as permission, recommendation, nor as an inducement to practice any patented invention without permission of the patent owner. TAB-013 Mexichem Specialty Resins, Inc. JUL 2013