Group Members ______________________________________ Period ____ Date ___________ Molecular Modeling of Carbon Compounds Adapted from an original work by John Banister-Marx, Wright Center for Science Education, Tufts University, Medford, MA Introduction: Atoms in the universe share a fundamental architecture. Formed in the birth of stars since the Big Bang many billions of years ago, groups of atoms called molecules compose all of matter, including living things. Life’s atomic structure is not fundamentally different. By creating 3-dimensional models of organic and inorganic compounds using molecular modeling kits, you will recognize that the types of atoms that bond together and their arrangement is a result of each individual atom’s arrangement of subatomic particles. Furthermore, it is the number, type, and arrangement of atoms that gives each compound its unique set of physical and chemical properties. Life is merely the most splendid of all atomic creations. Atoms bond with each other in order to fill their outermost electron shell. This is generally true for all atoms except the noble gases which have outermost, or valence, electron shells that are already full. The number of electrons needed to fill this outer shell is equal to the number of bonds (shared pairs of electrons) formed between atoms. The biochemical magic of carbon, so essential to life on Earth and probably elsewhere in the universe, lies in the four electrons of its outer shell. Needing four electrons to fill its outer shell, carbon can form four bonds. Carbon forms covalent bonds by sharing its four electrons with up to four other atoms. In some cases carbon forms four single covalent bonds: as in methane CH4. It can also form double bonds (each with two shared pairs of electrons) as in carbon dioxide, with carbon in the middle and an oxygen atom on each side: O=C=O. Carbon can even form triple bonds as in acetylene gas: H-C=C-H; and in hydrogen cyanide H-C=N. It is this extremely flexible molecular architecture that produces the multitude of different organic compounds. methane cyanide acetylene gas Purpose: To discover how the valence arrangement of an atom’s electrons contributes to its tendency to form covalent bonds. To create three-dimensional models of simple inorganic molecules and more complex organic molecules. To relate the chemistry of organic molecules to the stability of living systems on the Earth. Materials: (per team) molecular model kit student lab sheet print or web-based resources Procedure: 1. First let’s examine the periodic table using a new concept – ionization energy. An atom’s ionization energy is simply the amount of energy required to remove an electron from atom when the atom is in the gaseous state. The periodic table below shows the ionization energy tendencies of the elements. In general, ionization energy increases as you travel from left to right on the periodic table. This stands to reason because as you move from left to right the number of electrons in the valence energy level of an atom increases. Therefore, the closer an atom is to having a full valence energy level and thus being stable, the harder it will be to remove one of its electrons. Likewise, ionization energy decreases as you travel down a particular group on the periodic table. This is because as atoms become larger, electrons on the outermost or valence energy level are farther from the attractive forces of the nucleus, therefore they can be more easily removed. 2. Recall the seven elements that make up over 99% of the human body. List them. ________________ Circle these elements on the periodic table above. What generalization can you make about the ionization energies of these seven elements? Is it higher or lower than most other atoms? _________________________________________________________________________________ Based on this generalization, hypothesize what kind of chemical bonds these elements prefer to form. Ionic or covalent? Explain why. _______________________________________________________ _________________________________________________________________________________ _________________________________________________________________________________ _________________________________________________________________________________ 3. Examine the contents of your molecular model kit. Complete the chart on the next page. Use the periodic table above to help you. Element Bead Color Carbon black Hydrogen white Nitrogen blue Oxygen red Sulfur yellow Halogens (i.e. Cl, F, Br, I) green Group Number (Roman numeral above each column in periodic table) # of valence electrons # of electrons needed in order to fill valence level What do you notice about the relationship between the number of electrons needed in order for each element to become stable and the number of holes on the bead representing that element? _________________________________________________________________________________ _________________________________________________________________________________ 4. Using one molecular model kit per team, make the following molecules. Draw the shapes of your verified molecules in the appropriate space in the table. Represent each atom with its chemical symbol. A line drawn between two chemical symbols represents a single pair of shared electrons (a single covalent bond). See the drawings on the front page as examples. You may have to conduct extra research for some of these. Molecule (Chemical formula) water (H20) carbon dioxide (CO2) hydrogen peroxide (H2O2) ammonia (NH3) Description the most important molecule on planet Earth. Universal solvent colorless gas consumed during photosynthesis and produced during aerobic respiration and combustion. greenhouse gas a bleach blonde’s favorite recipe. Also a natural but poisonous by-product of cellular metabolism that is constantly being broken down in your body by the enzyme catalase a base used in cleaning, and possibly one of the gases in Earth’s early atmosphere Drawing ethanol (C2H5OH) the “active” ingredient in alcohol lactic acid (C3H6O3) the substance that makes your muscles ache after heavy exercise glucose (C6H12O6) the most important energy source in living things DISCUSSION: (answer on a separate piece of paper and attach to this lab sheet) 1. Of what kinds of atoms do most of the molecules that you constructed seem to be made? 2. What kind of bond do these atoms tend to form? Is this type of bond relatively strong or relatively weak? 3. How might ionization energy be used to predict which elements will form bonds? 4. How might ionization energy be used to predict what type of bonds elements prefer to form? 5. All molecules that contain carbon (except carbon monoxide (CO) and carbon dioxide (CO2)) are considered to be organic molecules. All other molecules are inorganic. Based on the molecules that you made and the descriptions of various molecules in this lab would you say that organic molecules or inorganic molecules are more important to life? Defend your answer with evidence from the lab. 6. Review your answers to the previous questions. What might this information tell us about how life seems to be able to remain organized (put together) even though the laws of thermodynamics would suggest that it should fall apart. 7. List two other things that your team learned about molecules from doing this activity. Work Cited Banister-Marx, John. "Molecular Models and The Origin of Life." eThemes. University of Missouri, 17 Feb. 2005. Web. 14 Oct. 2010. Grandinetti, Philip J. "General-Chemistry-Ionization-Energy-Trends." 2010. Web. 15 Oct. 2010.