Worksheet 4D: Solution Calculations Leader: Course: Instructor: Date: Sara Chem177 Bonaccorsi 2/19/14 Supplemental Instruction Iowa State University Dilution 1) In lab you mix 23.5 grams of copper (II) Nitrate (molar mass = 187.6) into 193 mL of water. a. What is the morality of the solution? 23.5 g Cu(NO3)2 * (1mol/187g) = .649 M1 .193L H2O b. You then dilute it to .500 L, at which point the concentration of the solution is what? M2=.649*.193/.500= .251 M Limiting Reagent/ Solution Stoichiometry 2) 3Au(NO3)2 (aq) + 2Li3PO4 (aq) 6LiNO3 (aq) + Au3(PO4)2 (s) a. What is the net ionic equation for the reaction? Au2+ (aq) + 2NO3- (aq) + 3Li+ (aq) + PO43- (aq) 6Li+(aq) + 6NO3- (aq) + Au3(PO4)2 (s) b. If you start with 10.0 mL of 6.00 M Gold (II) Nitrate and you add 113 mL of water what is the new concentration? 10.0 mL * 6.00 mol/L = (113 mL+10.0) * M2 M2 = .488 M c. You react it with .0500 moles of Lithium phosphate. How many moles of solid is produced? (.488 mol gold/L * .123L) * (1 mole solid/3 moles gold) = .0200 mol solid .0500 mol Li * ( 1 moles solid/2 moles Li) = .0250 moles solid Gold limiting 3) In lab you are performing a titration to find the concentration of a 25.6 mL solution of H2SO4. You start by dissolving 8.56 g solid KOH (molar mass = 56.1 g/mol) in 50.0 mL water. You then use 11.7 mL of that solution to titrate the H2SO4(aq). a. Write out the molecular and net ionic reaction? 2KOH (aq) + H2SO4(aq) 2H2O (l) + K2SO4 (aq) b. What is the concentration of the basic solution you made? 8.56 g KOH (1 mol KOH / 56.1 g KOH) = 3.05 M .0500 L H2O c. What is the unknown concentration of the acid solution? .0117 L base * 3.05 moles base * 1 mole acid * 1 1 L base 2 moles base .0256 L base = .697 M 1060 Hixson-Lied Student Success Center 515-294-6624 sistaff@iastate.edu http://www.si.iastate.edu